Search

In this study, a smart strain sensor based on gluten/guar gum (GG) copolymer containing a combination of additives was developed. The mix proportions of strain sensors were designed using Taguchi method coupled with Grey relational analysis. L16 orthogonal array with three factors, viz. tannic acid (TA), glycerol and sodium chloride (NaCl) at four-levels each was optimized. The addition of TA substantially enhanced tensile strength, self-adhesion ability and conductivity. The self-adhesion ability could also be improved by adding NaCl in range of 0-5 wt%. The presence of glycerol in strain sensors could reduce the self-healing time which was found in the range of 28.75-150 s. In addition, the incorporation of glycerol into gel also improved stretchability of strain sensors. The best mix proportion of strain sensor was found to be 3.75 wt% TA, 30 vol% glycerol and 5 wt% NaCl. The best mixture of stain sensor showed the highest gauge factor (GF) of 0.61 % at a stretchability of 665 % and rapid self-healing at 70 s. This strain sensor could be applied to monitor human limb movements in a wide temperature range from -20 °C to 50 °C. Furthermore, the obtained gel was successfully used as electronic devices and self-powered sensors., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Bacterial wound infections remain a significant health issue of great concern. Hence, there is a need to develop a novel material with antibacterial properties and smart functions. In this study, the effects of silver nanoparticles content (AgNPs) on properties of photothermal and pH-responsive nanocomposite hydrogels were investigated. The nanocomposite hydrogel samples were prepared using cassava starch waste modified by carboxymethylation (CMS), and mixed with poly vinly alcohol (PVA) and tannic acid (TA). The presence of AgNPs in the hydrogel samples enhanced antibacterial activities and photothermal conversion ability. The use of as-prepared hydrogel using 200 mM silver nitrate (H-AgNPs-200) combined with near infrared (NIR) radiation produced 100 % antibacterial efficiency for Escherichia coli (E.coli) and 98.2 % for Staphylococcus aureus (S.aureus). Furthermore, the H-AgNPs-200 also provided the highest storage modulus at 8.78 kPa. The obtained nanocomposite hydrogel was shown to exhibit pH-responsive release of TA. Under NIR radiation, higher release of TA at different pH was observed. The cytotoxicity study indicated that the nanocomposite hydrogels had good biocompatibility. Hence, the development of nanocomposite hydrogel-based CMS from cassava starch waste/PVA/AgNPs is a promising and sustainable approach where agro-waste product is used as the base material for medical application in wound dressing., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: This research project is supported by National Research Council of Thailand (NRCT): NRCT5-RGJ63003–049, Research and Graduate Studies, Khon Kaen University, Thailand, BCG Economy and Sustainable Development Network through Center of Excellence Consortium, Thailand and the Natural Sciences and Engineering Council of Canada., (Copyright © 2023. Published by Elsevier B.V.)