Search

This study was supported by the Leverhulme Trust grant 2016–21 (Nature and impacts of Middle Pleistocene volcanism in the Ethiopian Rift). KF was supported by the UK's Natural Environment Research Council (NERC) grant NE/L013932/1 (RiftVolc: The Past, Present and Future of Rift Volcanism in the Main Ethiopian Rift), a Boise Fund grant from the Department of Zoology, University of Oxford, and acknowledges Fonds de Recherche Scientifique – FNRS MIS grant F.4515.20. Tephra work on the Chew Bahir cores in the Cambridge Tephra Lab by AA, AP and CL was made possible by NERC grant NE/K014560/1. Ar–Ar dating was supported by grants NIGFSC IP-1683-1116 and IP-1680-1116. The iCRAG lab is supported by SFI 13/RC/2092. The Main Ethiopian Rift (MER) is renowned as a focus of investigations into human origins. It is also the site of many large volcanic calderas, whose eruptions have spanned the timeframe of speciation, cultural innovation, and dispersal of our species. Yet, despite their significance for dating human fossils and cultural materials, the timing and geochemical signatures of some of the largest eruptions have remained poorly constrained at best. Here, through a programme of field surveys, geochemical analysis and 40Ar/39Ar dating, we report the ages of MER ignimbrites and link them to widespread tephra layers found in sequences of archaeological and paleoenvironmental significance. We date major eruptions of Fentale (76 ± 18 ka), Shala (ca. 145–155 ka), Kone (184 ± 42 ka and ca. 200 ± 12 ka) and Gedemsa (251 ± 47 ka) volcanoes, and correlate a suite of regionally important tephra horizons. Geochemical analysis highlights the predominantly peralkaline rhyolitic melt compositions (7.5–12 wt% Na2O + K2O, 70–76 wt% SiO2) across the central MER and remarkable similarity in incompatible trace element ratios, limiting the correlation of deposits via glass composition alone. However, by integrating stratigraphic and geochronological evidence from proximal deposits, lake sediment cores and distal outcrops at archaeological sites, we have traced ash layers associated with the ca. 177 ka Corbetti, ca. 145–155 ka Shala and ca. 108 ka Bora-Baricha-Tullu-Moye eruptions across southern Ethiopia. In addition to strengthening the tephrochronological framework that supports paleoenvironmental and archaeological work in the region, our findings have wider implications for evaluating the hypothesis of a middle Pleistocene ‘ignimbrite flare-up’ in the MER, and for evaluating the impacts of these great eruptions on landscapes, hydrology, and human ecology. Publisher PDF

Explosive, caldera-forming eruptions are exceptional and hazardous volcanic phenomena. The 1883 eruption of Krakatau is the largest such event for which there are detailed contemporary written accounts, allowing information on the eruptive progression to be integrated with the stratigraphy and geochemistry of its products. Freshly exposed sequences of the 1883 eruptive deposits of Krakatau, stripped of vegetation by a tsunami generated by the flank collapse of Anak Krakatau in 2018, shed new light on the eruptive sequence. Matrix glass from the base of the stratigraphy is chemically distinct and more evolved than the overlying sequence indicating the presence of a shallow, silicic, melt-rich region that was evacuated during the early eruptive activity from May 1883 onwards. Disruption of the shallow, silicic magma may have led to the coalescence and mixing of chemically similar melts representative of a range of magmatic conditions, as evidenced by complex and varied plagioclase phenocryst zoning profiles. This mixing, over a period of two to three months, culminated in the onset of the climactic phase of the eruption on 26th August 1883. Pyroclastic density currents (PDCs) emplaced during this phase of the eruption show a change in transport direction from north east to south west, coinciding with the deposition of a lithic lag breccia unit. This may be attributed to partial collapse of an elevated portion of the island, resulting in the removal of a topographic barrier. Edifice destruction potentially further reduced the overburden on the underlying magmatic system, leading to the most explosive and energetic phase of the eruption in the morning of 27th August 1883. This phase of the eruption culminated in a final period of caldera collapse, which is recorded in the stratigraphy as a second lithic lag breccia. The massive PDC deposits emplaced during this final phase contain glassy blocks up to 8 m in size, observed for the first time in 2019, which are chemically similar to the pyroclastic sequence. These blocks are interpreted as representing stagnant, shallow portions of the magma reservoir disrupted during the final stages of caldera formation. This study provides new evidence for the role that precursory eruptions and amalgamation of shallow crustal magma bodies potentially play in the months leading up to caldera-forming eruptions.

Magmas from continental arcs built on thick crust have elevated incompatible element abundances and “enriched” radiogenic isotope ratios compared to magmas erupted in island and continental arcs overlying thinner crust. The relative influence of the slab, mantle, and upper plate on this variability is heavily debated. The Andean Southern Volcanic Zone (SVZ; 33–46°S) is an ideal setting to investigate the production of enriched continental arc compositions, because both crustal thickness and magma chemistry vary coherently along strike. However, the scarcity of primitive magmas in the thick-crusted northern SVZ has hindered previous regional studies. To better address the origin of enriched continental compositions, we investigate the geochemistry (major and trace element abundances, 87Sr/86Sr and 143Nd/144Nd ratios) of new mafic samples from Don Casimiro and Maipo volcanoes within the Diamante-Maipo Caldera Complex of the northern SVZ. While evolved Diamante-Maipo samples show evidence for crustal assimilation, the trace element and isotopic enrichment of the most mafic samples cannot result from crustal processing, as no known regional or global basement lithologies are enriched in all of the necessary incompatible trace elements. Subduction erosion models similarly fail to account for the enriched isotopic and trace element signature of these samples. Instead, we suggest that the enrichment of northern SVZ magmas is derived from an enriched ambient mantle component (similar to EM1-type ocean island basalts), superimposed on a northward decline in melt extent. A substantial, but nearly uniform contribution of melts from subducting sediment and altered oceanic crust are required at all latitudes. The EM1-like enrichment may arise from recycling of metasomatized subcontinental lithospheric mantle (M-SCLM), as the isotopic trajectory of primitive rear-arc monogenetic cones trend towards the compositions of SCLM melts sampled across South America. Isotopic data from spatially distributed rear-arc centres demonstrate that the arc-parallel variations in the degree of EM1-type enrichment observed in arc-front samples are also present up to 600 km behind the trench in the rear-arc. Rear-arc trace element systematics require significant but variable quantities of slab melts to be transported to the mantle wedge at these large trench distances. Overall, we show that a unified model incorporating variable mantle enrichment, slab additions, and melt extents can account for along and across-arc trends within the SVZ. The recognition that mantle enrichment plays a key role in the production of enriched continental compositions in the SVZ has important implications for our understanding of the chemical evolution of the Earth. If ambient mantle enrichment is not taken into account, petrogenetic models of evolved lavas may overestimate the role of crustal assimilation, which, in turn, may lead models of continental crust growth to overestimate the amount of continental material that has been recycled back into the mantle.

J. Biggs, I.M.Watson, W. Hutchison, T.A. Mather and D.M. Pyle are members of the NERC Centre for the Observation and Modelling of Earthquakes, Volcanoes and Tectonics (COMET). This work forms a contribution to the NERC Large Grant RiftVolc (NE/L01372X/1) awarded to J. Biggs. W. Hutchison was funded by NERC studentship NE/J500045/1. I.M. Watson is part of the NASA-ASTER science team and acknowledges NASA and JAXA for the provision of data. Fumaroles are the surface manifestation of hydrothermal circulation and can be influenced by magmatic, hydrothermal, hydrological and tectonic processes. This study investigates the temporal changes in fumarole temperatures and spatial extent on Aluto, a restless volcano in the Main Ethiopian Rift (MER), in order to better understand the controls on fluid circulation and the interaction between the magmatic and hydrothermal systems. Thermal infrared (TIR) satellite images, acquired by the Advanced Spaceborne Thermal Emission and Reflection radiometer (ASTER) over the period of 2004 to 2016, are used to generate time series of the fumarole temperatures and areas. The thermal anomalies identified in the ASTER images coincide with known fumaroles with temperatures > 80 °C and are located on or close to fault structures, which provide a pathway for the rising fluids. Most of the fumaroles, including those along the major zone of hydrothermal upwelling, the Artu Jawe Fault Zone, have pixel-integrated temperature variations of only ~ 2 ± 1.5 °C. The exception are the Bobesa fumaroles located on a hypothesised caldera ring fault which show pixel-integrated temperature changes of up to 9 °C consistent with a delayed response of the hydrothermal system to precipitation. We conclude that fumaroles along major faults are strongly coupled to the magmatic-hydrothermal system and are relatively stable with time, whereas those along shallower structures close to the rift flank are more strongly influenced by seasonal variations in groundwater flow. The use of remote sensing data to monitor the thermal activity of Aluto provides an important contribution towards understanding the behaviour of this actively deforming volcano. This method could be used at other volcanoes around the world for monitoring and geothermal exploration. Postprint

The halogens (F, Cl, Br, I) form an important suite of tracers of igneous processes, and may be used to track magmas from their point of origin, through their differentiation, evolution, saturation in vapour and escape to the Earth's atmosphere and hydrosphere. This review summarises the current state of the field, starting with an analysis of what is, and what is not, known about the distribution of halogens in Earth's interior reservoirs, and the principal controls on their behaviour during partial melting, crystallisation and degassing. With recent advances in measurement techniques, there is now a new opportunity to improve the inventories of halogen emissions from the open-vent, continuously-degassing systems that dominate the background contribution of volcanoes to the atmosphere. The different approaches to estimating the fluxes of HCl and HF to the atmosphere from arc and global volcanism are converging, and can now be used to place important constraints on the global cycling of halogens through subduction-zone systems. Arc-related volcanic emissions of halogens dominate the global halogen degassing budgets. Our current best estimates of halogen degassing fluxes from arc volcanoes are 4.3 (± 1) Tg/a (HCl), 0.5 (± 0.2) Tg/a (HF), 5-15 Gg/a (HBr) and 0.5-2 Gg/a (HI). © 2008 Elsevier B.V. All rights reserved.

Seismic activity has been postulated as a trigger of volcanic eruption on a range of timescales, but demonstrating the occurrence of triggered eruptions on timescales beyond a few days has proven difficult using global datasets. Here, we use the historic earthquake and eruption records of Chile and the Andean southern volcanic zone to investigate eruption rates following large earthquakes. We show a significant increase in eruption rate following earthquakes of MW > 8, notably in 1906 and 1960, with similar occurrences further back in the record. Eruption rates are enhanced above background levels for ~ 12 months following the 1906 and 1960 earthquakes, with the onset of 3-4 eruptions estimated to have been seismically influenced in each instance. Eruption locations suggest that these effects occur from the near-field to distances of ~ 500 km or more beyond the limits of the earthquake rupture zone. This suggests that both dynamic and static stresses associated with large earthquakes are important in eruption-triggering processes and have the potential to initiate volcanic eruption in arc settings over timescales of several months. © 2008 Elsevier B.V. All rights reserved.

Mt. Etna is a major natural source of Hg to the Mediterranean region. Total mercury concentrations, [Hg] tot, in Castanea sativa (sweet chestnut) leaves sampled 7-13km from Etna's vents (during six campaigns in 2005-2011) were determined using atomic absorption spectroscopy. [Hg] tot in C. sativa was greatest on Etna's SE flank reflecting Hg deposition from the typically overhead volcanic plume. [Hg] tot also showed Hg accumulation over the growing season, increasing with leaf age and recent eruptive activity. [Hg] tot in C. sativa was not controlled by [Hg] tot in soils, which instead was greatest on Etna's NW flank, and was correlated with the proportion of organic matter in the soil (% Org). An elevated [Hg] tot/% Org ratio in soils on Etna's SE flank is indicative of increased Hg deposition. This ratio was also found to decrease with local soil pH, suggesting that Hg deposited to the low pH and organic-poor soils on Etna's SE flank may not be retained but will instead be released to groundwater or re-emitted to the atmosphere. These results show that the deposition of volcanic Hg has clear impacts and confirm that Etna is an important source of Hg to the local environment. © 2012 Elsevier B.V.