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The present study focuses on the geochemistry of large phosphogypsum deposits in Huelva (SW Spain). Phosphogypsum slurry waste from fertiliser production was disposed in large ponds containing aqueous waste (i.e. brines) and exposed to weathering. These evaporation ponds were found to be dynamic environments far from attaining steady state conditions where a number of trace pollutants are subjected to temporal variations in response to changing environmental conditions. Chemical, mineralogical and morphological data were used to improve our understanding on the dynamics of a large number of elements in the phosphogypsum-brine-evaporation deposits system. Weekly sampling of brines over the course of 1 yr indicated a substantial enrichment in potentially harmful elements (e.g. As, Cr, Cu, F, Ni, U, V, Zn) present in time-dependent concentrations. The evaporation deposits formed multi-layered precipitates of chlorides, sulphates, phosphates and fluorides containing a large number of pollutants in readily soluble forms. The precipitation sequence revealed a time-dependent composition reflecting alternating precipitation and re-dissolution processes associated with seasonal changes in the local weather conditions. Concatenation of precipitation/re-dissolution stages was found to progressively enrich the brines in pollutants. These findings were supported by the observations from a tank experiment simulating the phosphogypsum-brine-evaporation deposits system under laboratory conditions. Given the substantially high concentrations of pollutants present in mobile forms in the brine-salt system, actions to abate these compounds should be implemented., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Geochemical anomalies of sulphide like elements (Cu, As and Cd) derived from the industrial activity have been identified in household dust of Huelva (SW Spain) using geochemical maps. Major and trace elements were analysed by ICP-OES and ICP-MS, respectively. Electron images of single particles were analysed by SEM-EDS in order to know their size, shape and composition. The geochemistry of the household dust has been compared to anomalies in deposition particles, PM10 and soils. A zonation has been observed: the eastern part of the city displays higher concentrations of sulphide like elements than the western part, supporting the origin of these elements related to the vicinity of industrial estates (Cu-smelter processes). Other domestic sources (e.g. wall painting) did not contain any geochemical anomalies related to sulphide like elements in household dust. Principal Component Analysis (PCA) was applied for grouping elements with similar sources, and reinforced the identification of a major industrial source in the eastern part. In this context, geochemical composition of household dust is considered as a fingerprint in order to identify industrial sources in the indoor air quality of Huelva., (Copyright © 2017 Elsevier B.V. All rights reserved.)