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Bivalves, such as oysters and mussels, are exposed to environmental pollutants, like microplastics (MPs) and arsenic (As). This study investigated co-existence and interaction of MPs and As (total As and As species) in two bivalve species from the Chinese coastline. Smaller MPs (20-100 μm) averaged 30.98 items/g, while larger MPs (100-500 μm) averaged 2.98 items/g. Oysters contained more MPs (57.97 items/g) in comparison to mussels (11.10 items/g). In Contrast, mussels had a higher As concentrations (8.36-23.65 mg/kg) than oysters (4.97-11.02 mg/kg). The size and composition of MPs influenced As uptake and speciation in bivalves, with inorganic arsenic (iAs) and methylated arsenic (MMA and DMA) correlating with larger-sized MPs. Polyethylene (PE) may interact with the formation of arsenobetaine (AsB) in oyster. This study provides valuable insights into the interaction of MPs and As in marine ecosystems and highlights their implications for food safety., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Pharmaceuticals and personal care products (PPCPs) have raised increasing concern worldwide due to their continuous release and potential hazards to the ecosystem and human health. This study optimized the entropy weight model (EW-WRSR) that combines entropy weight with multi-criteria decision analysis to investigate pollution patterns of PPCPs in the coasts and estuaries. The results revealed that occurrences of PPCPs from the 1940s to the present were consistent with using PPCPs, different types of human activities, and local urban development. This helped better understand the history of PPCP contamination and evaluate the uncertainty of EW-WRSR. The model predicted hotspots of PPCPs that were consistent with the actual situation, indicating that PPCPs mainly enter the nearshore ecosystem by the form of sewage discharge and residual aquaculture. This study can provide method that identifying highly contaminated regions on a global scale., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

For four decades, cordgrass (Spartina alterniflora) has invaded salt marshes in the Yellow Sea, altering physical, biogeochemical, and biological processes. Here, we investigated the ecological effects of S. alterniflora invasion on benthic environments compared to native halophytes. S. alterniflora contributed to higher carbon accumulation rates compared with bare tidal flat in sediments (3.4 times), through greater primary production and root biomass, compared to Suaeda japonica (2.5 times) and Phragmites australis (2.4 times) over the given period. The results showed that S. alterniflora eradication treatments inhibited its growth but did not significantly affect the benthic communities. Compared to P. australis and bare tidal flats, S. alterniflora invasion resulted in lower greenhouse gas emission and higher contributions to macrobenthos nutrition, and increased sediment stability and carbon burial. Overall, these multiple lines of evidence provide new insights on S. alterniflora invasion, suggesting that the current eradication policy would be carefully reviewed., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

This study utilizes ultraviolet and fluorescence spectroscopic indices of dissolved organic matter (DOM) from sediments, combined with machine learning (ML) models, to develop an optimized predictive model for estimating sediment total organic carbon (TOC) and identifying adjacent land-use types in coastal sediments from the Yellow and Bohai Seas. Our results indicate that ML models surpass traditional regression techniques in estimating TOC and classifying land-use types. Penalized Least Squares Regression (PLR) and Cubist models show exceptional TOC estimation capabilities, with PLR exhibiting the lowest training error and Cubist achieving a correlation coefficient 0.79. In land-use classification, Support Vector Machines achieved 85.6 % accuracy in training and 92.2 % in testing. Maximum fluorescence intensity and ultraviolet absorbance at 254 nm were crucial factors influencing TOC variations in coastal sediments. This study underscores the efficacy of ML models utilizing DOM optical indices for near real-time estimation of marine sediment TOC and land-use classification., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Despite being phased out for decades, per- and polyfluoroalkyl substances (PFAS) are still widely detected in the environment and accumulated in many aquaculture organisms for human consumption. Thus, there is growing concern about whether fish consumption can cause PFAS-associated health impacts on humans since fish is a vital protein source for global populations. Here, we assess the potential driving factors of fish consumption by analysing the aquaculture, demographic and socio-economic data across 31 provinces/municipalities in China, followed by estimating the health risk of PFAS via fish consumption. We found that per capita fish consumption was primarily driven by fish production and total area for freshwater aquaculture, while urbanization rate and median age of consumers were also important. The health risk of PFAS was low (hazard quotient <1) in most provinces, while urban consumers were more prone to PFAS than rural consumers across all provinces. Since PFAS have been phased out worldwide, their health risk to humans through fish consumption would be lower than previously thought. To reduce PFAS intake for the high-risk populations, we recommend that fish should be well cooked before consumption, preferably using water-based cooking methods, and that alternative protein sources should be consumed more as the substitute for fish., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Emerging pollutants are hazardous to the ecological environment and human health, and these issues have attracted increasing attention from scholars. In the current study, the Taiwan Strait is long and narrow, highly influenced by terrestrial domains, and frequently disturbed by human activities. Conversely, the Luzon Strait is an open sea far from the shore, and the impact of human activities on it is minimal. The description of antibiotics in two different types of seas revealed that contaminants were most commonly detected in both straits. In particular, the coasts of the Minjiang River, Jinjiang River, and Jiulong River were found to be pollution hotspots in the Taiwan Strait. The calculation of risk quotients revealed that antibiotics were more sensitive to algae. Furthermore, estimation of the risk quotients of the mixtures found that antibiotics in the environment do not pose a high risk to aquatic organisms at different trophic levels., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Organic ultraviolet filters (OUVFs) are functional ingredients used in cosmetics to protect skin from the harmful effects of ultraviolet (UV) radiation. This study presents recent findings on the distribution of OUVFs in the Pearl River Estuary (PRE), located in southern China. This investigation was conducted during the early stages of the Covid-19 pandemic when the stay-at-home policy was implemented. Analysis revealed the presence of OUVFs in both the surface and bottom water samples collected from eight major outlets of the Pearl River. The OUVFs were detected in both the dissolved phase and suspended particulate matter, with a total concentration ranging from 7.19 ± 6.54 to 20.5 ± 9.62 ng/L. Notably, OUVFs' concentrations in the study period were significantly lower compared to those reported before the pandemic. This implies that effective reduction of OUVF emissions can be achieved through usage reduction combined with the management of direct discharge and appropriate treatment by urban wastewater treatment facilities. During the study period, the annual release of OUVFs was approximately 12.6 kg/1000 people/year, with the greatest contribution from the Hu Men outlet. Consequently, it is imperative to consider the potential ecological risks associated with the release of OUVFs from the PRE into the marine environment, particularly with the potential for an accompanying rebound in risk upon the lifting of restrictions on outdoor activities in the post Covid-19 time., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier B.V.)

River deltas, as important food production centers, support 66 % of the world's population, together with other coastal areas. However, agriculture in river deltas is negatively affected by soil salinization and agricultural intensification. Improving the soil carbon pool is a mutually beneficial solution for maximizing crop production and improving climate resilience to secure food production. In this study, long-term croplands in the Yellow River Delta (YRD), with a wheat-maize (WM) rotation system and a single cotton (SC) cropping system, were selected to explore the changes in soil organic carbon (SOC) stocks and the driving mechanisms at 0-20 cm depth from 1980 to 2020. We found that, over the past 40 years, the SOC stocks in WM and SC croplands had increased by 10.05 Mg C ha -1 and 7.44 Mg C ha -1 , respectively. The Random forest model revealed that in the WM croplands, soil N stock and available K were the most important driving factors of SOC stocks, while in SC croplands, soil type and salinity were the most important driving factors of SOC stock dynamics. An increase in soil salinity to 2.0 ‰ caused a 17.5 % loss in SOC stocks in SC croplands. Our results show that, in the long run, croplands with a WM rotation system have stronger carbon sequestration potential. Depending on the planting system, promoting crop carbon input under high soil nutrients and affecting SOC decomposition by soil salinity are two different pathways of SOC sequestration in delta croplands. We propose that nutrient management and organic fertilizer application are crucial for increasing SOC stocks in the WM and SC croplands, respectively. This study confirms that it is of practical significance to take measures to promote soil carbon sequestration at the farmland scale and to provide scientific guidance for the sustainable development of river delta agriculture., Competing Interests: Declaration of competing interest No conflict of interest exits in the submission of this manuscript., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Continuously release of perfluoroalkyl substances (PFASs) would pose non-negligible impacts on environment, organisms, and human health. In present study, 18 PFASs in 7 typical economic invertebrates and their habitats were investigated from the South China Sea. The higher concentrations of PFASs in the nearshore water (6.61-15.54 ng/L) and sediment (0.82-8.84 ng/g) obviously due to frequent human activities. Long-chain PFASs have tendency to accumulate in sediment, however, short-chain PFASs dominated in biota. The acute reference dose (%ARfD) and hazard ratios (HR) of major PFASs in biota were all <100 %, and also below 1, respectively, which means that consumption of PFASs from seafood does not pose risk and threat to human health. However, it should be taken into account that the HR of PFHxA in Mimachlamys nobilis reached 0.82. Potential adverse effects toward human health induced by short-chain PFASs (such as <6 C) via invertebrate seafood consumption should be concerned., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Liquid crystal monomers (LCMs), an emerging group of organic pollutants related to electronic waste, have been frequently detected from various environmental matrices, including landfill leachate. The persistence of LCMs requires robust technology for remediation. The objectives of this study were to evaluate the feasibility, performance and mechanism of the remediation of a typical LCM 4-[difluoro(3,4,5-trifluorophenoxy)methyl]- 3,5-difluoro-4'-propylbiphenyl (DTFPB) via synchronized oxidation-adsorption (SOA) Fenton technology and verify its application in DTFPB-contaminated leachate. The SOA Fenton system could effectively degrade 93.5% of DTFPB and 5.6% of its total organic carbon (TOC DTFPB ) by hydroxyl radical oxidation (molar ratio of Fe 2+ to H 2 O 2 of 1/4 and pH 2.5-3.0) following a pseudo-first-order model under 0.378 h -1 . Additionally, synchronized adsorption of DTFPB and its degradation intermediates by in situ resultant ferric particles via hydrophobic interaction, complexation, and coprecipitation contributed to almost 100% of DTFPB and 33.4% of TOC DTFPB removal. Three possible degradation pathways involving eight products were proposed, and hydrophobic interactions might drive the adsorption process. It was first confirmed that the SOA Fenton system exhibited good performance in eliminating DTFPB and byproducts from landfill leachate. This study provides new insights into the potential of the Fenton process for the treatment of emerging LCMs contamination in wastewater., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 The Authors. Published by Elsevier B.V. All rights reserved.)

The ubiquitous distribution of perfluoroalkyl substances (PFASs) poses a threat to the health of aquatic organisms and humans. Bullfrogs are considered a popular aquatic food product in South China, providing high protein and tasty cuisine; however bullfrogs have been shown to contain significant concentrations of PFASs. However, the risk-benefit ratios of PFASs and nutrient contents in cooked bullfrogs are not well understood. PFASs and nutrients were investigated in raw and cooked specimens of cultured and wild bullfrogs in this study. Novel PFASs showed higher detection levels and accumulation in wild bullfrogs than in cultured bullfrogs. Potential factors such as fat and fatty acid ratio affected PFASs accumulation in different tissues and by different cooking methods of bullfrogs. All cooking methods can reduce PFASs in edible tissues while significantly enhancing the nutritive value index (NVI) compared to raw bullfrogs. Steaming was the most effective way to reduce PFASs (rate of reduction was over 66%) and resulted in a lower risk of contributing to arteriosclerosis than other cooking methods assessed by atherogenicity index (AI) values. Cultured bullfrogs instead of wild bullfrogs were recommended for human consumption, and steaming was regarded as a better cooking method in terms of risk-benefit concerns. Overall, this work provides quantitative analysis of cooking methods that alter PFASs and nutrients in bullfrogs., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Heavy metal pollution greatly harms the soil environment and poses threats to food safety and human health. This study aimed to quantify and analyze the sources of heavy metals and assess the health risks associated with the human intake of contaminated vegetables in South China. Heavy metals (Cd, As, Hg, Cu, Ni, Pb, Zn, and Cr) in soil and vegetables (leaf vegetables, legume vegetables, and cucurbits) were investigated and evaluated for contamination. By combining the correlation analysis (CA), positive matrix factorization (PMF), and GeoDetector model, source apportionments were comprehensively identified. Results showed that Cd was the predominant element in soils throughout the study area. Industrial (28.36 %, 20.24 %, 31.50 %), agricultural (27.19 %, 46.50 %, 27.30 %), besides traffic, atmospheric deposition and natural sources were identified as the dominant sources of heavy metals in GD01, GD02, and GD03, respectively. The human health risk assessment showed that the total non-cancer risk of heavy metals (i.e., Cr, Ni, As, Cd, and Pb) ingested through vegetables was 2.3E+00 for children and 9.67E-01 for adults, and the total cancer risk for children was 2.54E-02 and 1.07E-02 for adults, both of which exceeded acceptable levels. It is worth noting that children are more susceptible to health risks due to the consumption of contaminated vegetables than adults., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Increased anthropogenic activities have caused contamination of perfluoroalkyl substances (PFASs) in lakes worldwide. However, how to remediate their contamination remains unclear. In this study, a heavily polluted lake, Baiyangdian Lake in China, was selected to investigate current PFASs levels in multimedia, stimulate their transport fate based upon an optimized fugacity model, and finally identify appropriate remediation pathways. From 2008-2019, the average concentrations of PFASs in the lake increased approximately 7-40 times in the environment and biota. Spatially, with continuous import of perfluorohexane sulfonate (PFHxS) and perfluorooctanoic acid (PFOA), barring fish, a noticeable north-south difference was distinguished in the PFASs composition in multimedia from the lake. Based on the optimized fugacity model simulation, the water phase was the primary transport path (~76.5%) for PFASs, with a total flux of 333 kg y -1 . Compared with bioaccumulation fluxes in submerged plants (6.2 kg y -1 ), emerged plants (2.6 kg y -1 ), and fish (1.1 kg y -1 ), the exchange flux of PFASs between water and sediment remained high (~94 kg y -1 ). Considering remediation cost, sediment cleaning is currently the most cost-effective pathway, while harvesting submerged plant could be a promising pathway in the future. This study provides a basis for remediating PFASs-polluted lakes on a global scale., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Mangroves are highly dynamic ecosystems that offer important services such as maintaining biodiversity, filtering pollutants, and providing habitats for fishes. We investigated the uptake and accumulation of nutrients and potentially toxic elements in mangrove plants and fish to better understand the role of mangrove restoration in maintaining mangrove biota quality. In mangrove plants, the average bioconcentration factors of nutrients and potentially toxic elements were in the order P > Pb > Mn > Mg > Se > Zn > Hg > Cu > Cd > As > Co > Cr > Ni > Fe > V > Sb, where only P (all plant species) and Pb (Sonneratia apetala Buchanan-Hamilton) had a BCF > 1.0 in mangrove plants. In general, Sonneratia spp. had better performances than Kandelia candel (Linn.) Druce, Aegiceras corniculatum (Linn.) Blanco and Acanthus ilicifolius L. Sp. in terms of nutrient uptake and toxic metal(loid)s accumulation, and the best uptake capacity was found in S. apetala. Fast growth and easy adaptation make S. apetala suitable for a restored mangrove ecosystem, but continual management is needed to prevent its suppression of mangrove species diversity. The concentration of As, Cd, Hg, Cu, Cr and Pb in the mangrove sediment were 30-220% higher than the Chinese National Standard of Marine Sediment Quality Class I limits, suggesting that the sediments were unsuitable for aquaculture and nature reserves. Although a higher toxic metal(loid)s concentration in the sediment was found, the target hazard quotient (THQ) of this toxic metal(loid)s in 5 mangrove habitat fishes was <1.0, except THQ of Pb in Boleophthalmus pectinirostris Linnaeus was 1.17, and THQ of Cr in Bostrychus sinensis Lacépède was 1.12. The low THQ (less than 1.0) of mangrove habitat fishes suggested that the restored mangrove system could alleviate the bioaccumulation of toxic metal(loid)s in mangrove fish., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Environmentally persistent free radicals (EPFRs) are emerging pollutants in contaminated soils and have attracted significant attention. Chinese coke production making a great contribution to the globe is increasingly identified as the non-ignorable source of EPFRs. However, the distribution level, influence factors, and biotoxicity of EPFRs at coking sites remain poorly understood. Herein, a typical coking plant in Tangshan, China, featuring two functional regions (the reconstructed project (RP) and elimination engineering (EE)) was used to study the existence of EPFRs. The spin density of the EPFRs in coking soils was 3.20 × 10 20 -3.11 × 10 21 spins/g with g-factor values of 2.0020-2.0036. The EPFRs presented higher concentrations and g-factor values in RP region than in EE region, and a mixture of carbon-centered radicals and carbon-centered radicals with adjacent oxygen atoms as well as carbon-centered radical was ascertained in the former and the latter, respectively. Correlation analysis and FT-ICR-MS results indicated that polycyclic aromatic hydrocarbons (PAH) together with other unsaturated hydrocarbons and condensed aromatic contaminants, might contribute to the EPFRs formation in the soils of RP region, whereas PAHs were the main source of EPFRs in EE region. Soil components were determined to investigate the influence factors in EPFRs formation. Cu and Fe 2 O 3 were recognized as the markedly positive influence factors, while TOC had a negative impact on EPFR formation. Visible light irradiation can induce the transformation and generation of EPFRs. As representative contaminants, both toluene and 2-chlorophenol can create EPFRs in coking soil under visible light irradiation. The potential biotoxicity tests of Photobacterium phosphoreum T3 spp. showed that EPFRs from the soils diminished bacterial luminescence. Such effect was proven to be induced by the OH based on the quenching experiment. Understanding the influence factors of EPFRs formation and their biotoxicity in coking soils is critical for developing risk assessments and prevention strategies., Competing Interests: Declaration of competing interest The authors declare that there are no conflicts of interest., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Novel aryl hydrocarbon receptor (AhR) agonists were identified in coastal sediments in the Yellow and Bohai Seas by use of a combination of effect-directed analysis (EDA) and in silico prediction. A total of 125 sediments were screened for AhR-mediated potencies using H4IIE-luc bioassay. Great potencies were observed in organic extracts, mid-polar fraction (F2), and subfractions of F2 (F2.6-F2.9) of sediments collected from Nantong, Qinhuangdao, and Yancheng. Less than 15% AhR potencies could be explained by detected dioxin-like PAHs. Full-scan screening analysis was conducted for the more potent fractions using GC-QTOFMS to investigate the presence of unmonitored AhR agonists. A five-step prioritization strategy was applied; 92 candidate compounds satisfied all criteria. Among these chemicals, thirteen were evaluated for AhR efficacy. Six compounds; benz[b]anthracene, 6-methylchrysene, 2-methylbenz[a]anthracene, 1-methylbenz[a]anthracene, 1,12-dimethylbenzo[c]phenanthrene, and indeno[1,2,3-cd]fluoranthene, exhibited significant AhR-mediated efficacies. 1,12-dimethylbenzo[c]phenanthrene and indeno[1,2,3-cd]fluoranthene were identified as novel AhR agonists. Potency balance analysis showed that the six newly identified AhR agonists explained 0.4-100% of the total AhR-mediated potencies determined. Overall, combining EDA and in silico prediction applied in this study demonstrated the benefits of assessing the potential toxic effects of previously unidentified AhR agonists in sediments from the coasts of China and Korea., (Copyright © 2022 The Authors. Published by Elsevier B.V. All rights reserved.)

A copepod bioassay with Tigriopus japonicus was applied to evaluate the relative ecotoxicity of sediments in the Yellow and Bohai seas, and contributions of individual PAHs to copepod toxicity were evaluated. Mean toxicity was greatest in the Yellow Sea of China, followed by the Bohai Sea and Yellow Sea of Korea. Elevated concentrations of sedimentary PAHs, alkylphenols, and styrene oligomers back-supported the significant toxicities observed in bioassay. Copepod toxicity in relation to PAHs indicated the greatest contribution by indeno[1,2,3-c,d]pyrene. However, lacked contribution by PAHs, viz., 2.4 and 3.0 % for the total immobilization and mortality, respectively, indicated a large proportion of unknown toxicants being widely distributed along the Yellow Sea Large Marine Ecosystem (YSLME) coastline. Overall, the present study provides useful baseline information for evaluating the potential sedimentary toxicants, with emphasizing further investigation to identify the unknown toxicants at an LME scale, and elsewhere., (Copyright © 2022 The Authors. Published by Elsevier Ltd.. All rights reserved.)

To improve the prediction accuracy of soil heavy metals (HMs) by spatial interpolation, a novel interpolation method based on genetic algorithm and neural network model (GANN model), which integrates soil properties and environmental factors, was proposed to predict the soil HM content. Eleven soil HMs (Cu, Pb, Zn, Cd, Ni, Cr, Hg, As, Co, V and Mn) were predicted using the GANN model. The results showed that the model had a good prediction performance with correlation coefficients (R 2 ) varying from 0.7901 to 0.9776. Compared with other traditional interpolation methods, including inverse distance weighting (IDW), ordinary kriging (OK), universal kriging (UK), and spline with barriers interpolation (SBI) methods, the GANN model had a relatively lower root mean square error value, ranging from 0.0497 to 77.43, suggesting that the GANN model might be a more accurate spatial interpolation method and the soil properties together with the environmental geographical factors played key roles in prediction of soil HMs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Perfluoroalkyl substances (PFASs) are known to be persistent and toxic, and can be accumulated and trophic magnified in the environments. PFASs are widely distributed, and their coastal input poses a threat to the health of aquatic organisms and local residents. In present study, 17 PFASs including one emerging polyether substitute in water, sediment, and organisms were investigated from the South China Sea. Perfluorobutanoic acid (PFBA) was predominant in water, of which concentration ranged from ND to 10.26 ng/L, with a mean of 5.21 ng/L. Similar to sediment and organisms, PFBA was the substance with the highest concentration detected among PFASs. This result seemingly indicated that use of short-chain PFASs as substitutes for long-chain PFASs in recent years. Trophic magnification factors (TMFs) of PFASs were estimated in the marine food web. TMFs > 1 was observed only in perfluorooctane sulfonic acid (PFOS), indicating a biomagnification potential of PFOS in the given ecosystem. The estimated daily intake (EDI) of PFOS and PFOA were most prevalent in mollusk, whereas the EDI of PFBA was greater in fish and shrimp. The hazard ratio (HR) reported for seven dominant PFASs were lower than 1, which suggests that PFASs via seafood consumption would not cause significant health risk to local residents., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Microplastic pollution in marine environment has been a growing public concern in recent years. This article analyzed the scientific literatures related to marine microplastics through a combination of social network analysis and bibliometrics. Researches related to microplastics have grown rapidly since 2011, with approximately two-thirds of the total number of articles published in the last three years. Researchers in United States and Europe have provided tremendous support, however, the efforts and progress of Chinese researchers cannot be ignored. Moreover, the international cooperation is getting closer, and related strategies are launched continuously. The results showed that Marine Pollution Bulletin is the most active journal. Through keyword analysis, we understand the development history and current hotspots of the whole microplastics researches, including ecological risks, interrelationship between microplastics and other pollutants, and detection methodology. Finally, some suggestions and perspectives for future microplastics research are provided., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

The Yellow and Bohai seas have long been contaminated by persistent toxic substances (PTSs) from numerous (un)known anthropogenic sources. In this study, we used Vibrio fischeri bioassay to evaluate ecotoxicological profiles associated with sedimentary PTSs contamination at a large marine ecosystem (LME) scale. A total of 125 surface sediments collected from the coastal areas of the Yellow and Bohai seas were analyzed both for aqueous and organic extracts. Not surprisingly, the results indicated site-dependent toxicities, but most sites were identified as non-toxic to V. fischeri. For aqueous extracts and organic extracts, 13% and 8% of samples, respectively exhibited marginal toxicity, while 0% and 2% of samples exhibited moderate toxicity. However, it should be noted that organic extracts (mean TU = 56) induced stronger toxicities than aqueous samples (mean TU = 0.4). This result generally back-supported the high toxicity potentials associated with sedimentary sink of organic pollutants. Several PTSs measured in the samples indicated a significant contribution to the observed V. fischeri toxicities. Of note, polycyclic aromatic hydrocarbons (PAHs; r = 0.28, p < 0.05), styrene oligomers (r = 0.41, p < 0.01), and alkylphenols (r = 0.38, p < 0.05) showed significant associations to the observed bacterial inhibition. Among PAHs, benzo[a]anthracene and phenanthrene exhibited a significant contribution to the observed V. fischeri toxicities. Meantime, salinity which reflects the distance from the point sources of land-driven pollutants along the rivers and estuaries in the Yellow and Bohai seas was a key environmental variable representing the sample toxicities. Overall, the present study provides baseline information for evaluating the potential sediment toxicity to implement responsible coastal management at an LME scale, and elsewhere., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Polycyclic aromatic hydrocarbons (PAHs) are widely present in the environment. The coking industry is an important industrial source of PAHs. Coke production in China accounts for 67.44% of total global coke production. Tangshan, a coastal city on the Bohai Rim, contains the largest cluster of coking plants in China. Extremely high PAH emissions in Tangshan may cause long-distance cross-border pollution problems. In this study, the concentrations and sources of 16 priority PAHs in soil at a coking plant in Tangshan were determined and the risks posed by the PAHs were assessed. The PAH concentrations were generally higher in surface soil than subsurface soil, particularly near the coke oven, crude benzol, and coal blending areas. The dibenz[a,h]anthracene (DBA) concentrations were higher than the risk screening value (1500 ngg -1 ) but lower than the control value (15,000 ngg -1 ) for type II land defined in Chinese standard (GB36600-2018). The main sources of PAHs were coal combustion, the coke oven, and traffic. The PAH concentrations were higher in the ammonium sulfate, boiler room, coal blending, and coke oven areas than in the other areas. Toxic equivalent concentrations were calculated to assess the toxic and carcinogenic risks posed by PAHs. The toxic equivalent concentrations were relatively high in the boiler, crude benzol, and coal blending areas, where the toxic equivalent concentrations for the sums of seven highly carcinogenic PAHs contributed 95% of the toxic equivalent concentrations for the sums of the 16 PAHs that were analyzed. The carcinogenic risks posed to humans were therefore assessed using the concentrations of the seven highly carcinogenic PAHs. Dermal contact was found to be an important exposure pathway leading to carcinogenic risks. The carcinogenic risk posed by DBA was > 1 × 10 -6 but < 5 × 10 -6 , indicating that DBA concentrations at the study site monitored closely., (Copyright © 2021 The Authors. Published by Elsevier Inc. All rights reserved.)

Perfluoroalkyl substances (PFASs) have raised great attention as emerging contaminants due to their persistent and bioaccumulative characteristics. Following the global actions to limit perfluorooctanesulfonic acid (PFOS) and its salts, chlorinated polyfluorinated ether sulfonate (F-53B), as an alternative perfluorochemical, has been a focus during this period. In this study, PFASs in coastal seawater, sediment, and seaweed from the significant aquaculture bases of Porphyra haitanensis in the southeast of China were investigated. Their bioaccumulation and ecological risk were elucidated and associated human exposures to PFASs with consumption of aquatic products for rural and urban groups were calculated. The total PFASs levels in seawater and sediment were 21.52-241.86 ng/L and 4.55-26.54 ng/g·dw, respectively. F-53B was found frequently and has relative high concentration in seawater (ND-2.13 ng/L). The Porphyra haitanensis and Siganus fuscescens were also analyzed, with PFASs concentrations ranging from 10.45 to 29.98 ng/g·dw and 7.17 to 25.43 ng/g·dw, respectively. The total logarithm BAF of F-53B and PFOS in two kinds of detected seafoods were within 0-2.94 and 2.01-3.25, these values did not vary in different sites. The estimated daily intake (EDI) of PFASs through aquatic products consumption in rural and urban residents were 0.03-26.50 ng/kg bw/day and 0.17-37.01 ng/kg bw/day, respectively, based on the Dietary Guidelines for Chinese residents. The total EDI of PFASs via Porphyra haitanensis and Siganus fuscescens in different groups were significantly lower than the suggested tolerable daily intake (PFOS, 150 ng/kg bw/day; PFOA, 1500 ng/kg bw/day), which indicates that PFASs did not induce health risks to the residents living around these aquaculture bases., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Polyfluoroalkyl substances (PFASs) are recognized as emerging contaminants that have captured worldwide attention. They are primarily transported in environments and spread around the globe due to their persistent and bioaccumulative characteristics. In this study, 15 PFASs were detected in major rivers of the rapidly developing coastal areas of China and South Korea. The concentrations and compositions of these PFASs varied greatly between different regions along the coastline. The total concentrations ranged from 14.9 to 16,500 ng L -1 , and the mean concentrations of Σ 15 PFASs in Liaodong Bay, Bohai Bay, Laizhou Bay, and the west coast of South Korea were 124 ng L -1 , 81.4 ng L -1 , 1550 ng L -1 , and 36.2 ng L -1 , respectively. In Laizhou Bay, the relatively high perfluorooctanoic acid (PFOA) was due to the high usage and manufacturing of PFOA-containing products and contributed 59% of the total compounds. In Liaodong Bay and Bohai Bay, PFBA and PFOA were the most abundant compounds, accounting for >55% of the total compounds. Along the west coast of South Korea, PFBA and PFPeA were the most prevalent compounds, contributing 28% and 24% of the total compounds, respectively. The data collected in the last decade were analyzed to investigate the temporal trends of selected PFASs. The total concentration of Σ 10 PFASs decreased in both China and South Korea, while the proportion of short-chain PFASs increased. The proportion of C 4 -C 7 PFCAs in South Korea rapidly increased from 46% to 79% but decreased from 49% to 43% in China. The positive matrix factorization (PMF) model successfully addressed the site-specific source apportionment, which showed that 53% of the PFASs in Laizhou Bay were due to fluorine manufacturing. The results of this study provide novel insights into elucidating the spatiotemporal distribution and complicated sources of PFASs over a large area and provide a clear message for all stakeholders, water and coastal managers, and scientists., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

The presence of pharmaceuticals and personal care products (PPCPs) has become a global concern, as it poses a threat to the environment, especially to the aquatic ecosystem. This study focused on 30 PPCPs found in the Baiyangdian basin of the Xiong'an New Area, in the core of Beijing-Tianjin-Hebei region, with intensive human interventions during two seasons. In general, 30 PPCPs were all frequently detected, ranging from 42.3 to 7710 ng/L in May and 48.9 to 1300 ng/L in November. Sulfamethoxazole, ofloxacin, anhydro-erythromycin, carbamazepine, caffeine, and were screened as the predominant PPCPs. The rivers input was an essential source of PPCPs. The source apportionment with a series of analytical methods revealed that domestic sewage was the primary source, and untreated water also crucial for PPCPs contamination. The risk assessment suggested carbamazepine, caffeine, ofloxacin, and anhydro-erythromycin exhibited relatively high ecological risks for protecting most species such as algae, fish, and flowers in the aquatic ecosystem, especially near the outlet of WWTPs. Thus, management strategies for such PPCPs will be needed. Intensive human interventions, including a prohibition of fish breeding, water diversion project, and wastewater treatment in villages, were having an effective role in alleviating PPCPs contamination., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Due to potential adverse effects and bioaccumulation in biota and humans, perfluoroalkyl substances (PFASs) have raised wide attention in recent years. Ingestion is a vital pathway for PFASs to transmit to humans especially through water and fish. In present study, PFASs in water and fish from the drinking water source of Beijing in China were investigated. Three layers of water were collected in order to find the connection between concentrations of PFASs and depth of water, which showed no prominent correlation. PFASs in water from Miyun Reservoir with concentrations of 5.30-8.50 ng/L, were relatively lower compared with other reports on raw drinking water. Perfluorobutanoic acid (PFBA) and perfluorooctanoic acid (PFOA) were the dominant PFASs. In addition, six species of fish (including Cyprinus carpio, Carassius auratus, Erythroculter dabryi, Pseudohemiculter dispar, Hypophthalmichthys molitrix and Siniperca chuatsi) were analyzed, with concentrations of PFASs ranging from 1.70 to 14.32 ng/g wet weight (w.w.). Due to relatively stronger bioaccumulation potential, long chain perfluorinated carboxylates (PFCAs) and perfluorinated sulfonates (PFSAs) were detected with higher concentrations, especially perfluoroundecanoic acid (PFUdA) and perfluorodecanoic acid (PFDA). The estimated daily intake (EDI) of PFASs through drinking water and fish consumption were 0.20-0.34 and 3.44-12.61 ng/kg bw/day based on Exposure Factors Handbook of Chinese Population, respectively. In addition, the EDI of high-priority concern PFASs via pork, chicken and dust were also calculated, with value of 0.015-0.043, 0.003-0.013 and 0.074-0.390 ng/kg bw/day, respectively. The total EDI of PFOS and PFOA via diverse pathways were less than suggested tolerable daily intake (PFOS, 150 ng/kg bw/day; PFOA, 1500 ng/kg bw/day), indicating that the detected levels would not cause severe health effects on Beijing residents., (Copyright © 2019 Elsevier Inc. All rights reserved.)

Perfluoroalkyl acids (PFAAs) have been widely detected and pose potential risks to both human and ecosystem health. Since the probation of perfluorooctane sulfonate (PFOS) by the Stockholm Convention, perfluorooctanoate (PFOA) has frequently been used as a chemical intermediate and processing aid. Owing to a lack of effective treatment technologies for PFOA, surrounding environments have been highly affected. Previous studies by our group have reported elevated PFOA levels in the Xiaoqing River, which receives sewage from a major fluorochemical manufacturer in northern China. To further explore the transport, flux, and ecological risk of the perfluorooctanoate in the river, this study conducted a 2-year sampling campaign of surface water from 2014 to 2015. An extremely high PFOA concentration (mean: 62.3 μg L -1 ) was observed for the Xiaoqing River in comparison with other studies. The highest average concentration and flux of PFOA were recorded in the autumn and summer, respectively. With data on selected hydrological parameters and cross-sections, PFOA concentrations were modeled using DHI MIKE 11. To explore the current loads and environmental capacity of PFOA, two scenarios (i.e., emissions based on observed concentrations and on the predicted no-effects concentration, PNEC) were set. The simulation results based on observed data showed that PFOA loads in the Xiaoqing River were 11.4 t in 2014, and 12.5 t in 2015. Based on the PNEC, the environmental carrying capacity of PFOA was estimated to be 13.9 t in 2014, and 13.8 t in 2015. The current loads of PFOA were found to approach the maximum environmental carrying capacity. Relatively high risks around both the fluorine industrial park (FIP) and estuary area were identified. In comparison with other suggested guidelines, threats to the ecological status of the river would be severe, which suggests that stringent management and emission criteria are needed for this industry., (Copyright © 2018 Elsevier B.V. All rights reserved.)

To investigate benthic ecological quality associated with coastal pollution in the Bohai Sea and northern Yellow Sea, a sediment quality triad (SQT) approach was applied. Chemical (six groups of persistent toxic substances (PTSs) and 8 metals and metalloids), toxicological (AhR-mediated potency), and ecological (bacterial and meiofaunal communities) elements were selected and used in an integrated sediment assessment. The benthic meiofaunal community was newly analyzed and used as an additional component of the infaunal community during the SQT. Concentrations of chemicals and potential toxicity in sediments both indicated moderate to severe pollution in the study area, characterized by site-specific and land-uses. In particular, As, DDTs, and bioassay-derived dioxin equivalents exceeded corresponding sediment quality guidelines at nearly all locations. Limited occurrences of meiofaunal taxa (mean = 5.2) and relatively low species diversity, mainly comprised of nematodes (75.3%) and copepods (14.6%), among locations was generally consistent with pollution. The benthic community was consistent with compound-specific responses to gradients of contamination, particularly for As. Densities of two taxa, Nematoda and Nemertea exhibited strong negative correlations with concentrations of As. Compound-, site-, and taxa-specific variability of pollution of sediments was further supported by results of cluster analysis (CA) and nonmetric multidimensional scaling (NMDS). Finally, assessment integrating five benthic quality elements, including: 1) PTSs; 2) metals and metalloids; 3) sediment toxicity; 4) sediment microbiome; and 5) benthic meiofaunal community, explained contamination of sediments associated with land-uses, locality, or habitat. Status of the benthic community could not be explained by single component and their associations were not quantitative. Results of the integrated assessment, considering multiple benthic quality elements were useful to address overall quality of sediment, and were consistent with chemical-, species-, or site-dependent pollution of sediments in the Bohai and Yellow Seas., (Copyright © 2018 Elsevier B.V. All rights reserved.)

China has gradually become the most important manufacturing and consumption centre for perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) in the world, and inadvertently become the world's major contamination hotspots. However, a systematic analysis of pollution pathways for PFOS/PFOA into the different environmental compartments and their quantification in China has yet to be carried out. This study focused on PFOS and PFOA release into the environment in the central and eastern region of China, which accounts for the vast majority of national emission. About 80-90% of PFOS/PFOA contamination in the Chinese environment was estimated to come directly from manufacturing and industrial sites mostly via wastewater discharge from these facilities. The other major contamination sources for PFOS were identified as being linked to aqueous fire-fighting foams (AFFFs), and pesticides including sulfluramid. For PFOA, following some way behind industrial wastewater, were industrial exhaust gas, domestic wastewater and landfill leachate as contamination sources. For surface water contamination, the major pollution contributors after industrial wastewater were AFFF spill runoff for PFOS, and domestic wastewater and precipitation-runoff for PFOA. The majority of PFOS that contaminated soil was considered to be linked with infiltration of AFFF and pesticides, while most PFOA in soil was attributed to atmospheric deposition and landfill leachate. Where groundwater had become contaminated, surface water seepage was estimated to contribute about 50% of PFOS and 40% of PFOA while the remainder was mostly derived from soil leaching. A review of the available monitoring data for PFOS/PFOA in the literature supported the view that industrial wastewater, landfill leachate and AFFF application were the dominant sources. Higher concentrations of PFOA than PFOS found in precipitation also corroborated the prediction of more PFOA release into air. To reduce PFOS/PFOA contamination of the Chinese environment the focus for control should be on industrial wastewater emissions., (Copyright © 2016 Elsevier B.V. All rights reserved.)

Perfluoroalkyl acids (PFAAs) have been widely used in surfactant applications, especially as processing acids for fluoropolymer production. This study provides an analysis of sources of certain PFAAs emitted from the intensive fluoropolymer facilities in the Xiaoqing River Basin of China. Concentrations of perfluorooctanoic acid (PFOA) as great as 0.97mg/L in surface water and 10.5μg/g dry weight in surface sediment have been detected near the effluent of one facility (F1) that produces polytetrafluoroethylene (PTFE) and other fluoropolymers with massive capacity. With the great emission of PFAAs to water in natural conditions, the log KOC values decreased for short-chain PFCAs. Mass loads of PFAAs indicated that emissions of PFAAs from other facilities or sources were much less than those from F1, which emitted 174kg/d of PFAAs including 159kg/d of PFOA to the rivers. Even though production and emissions of PFOA have been strictly controlled in other countries since 2006, production of PFOA as well as several other fluoropolymers that use PFOA as processing aids has been increasing at F1 in recent years. We recommended that production shift should be taken into consideration in PFOA elimination actions., (Copyright © 2015 Elsevier B.V. All rights reserved.)

This study investigated the concentrations and distribution of Perfluoroalkyl and polyfluoroalkyl substances (PFAS) in sediments of 12 rivers from South Bohai coastal watersheds. The highest concentrations of ΣPFAS (31.920 ng g(-1) dw) and PFOA (29.021 ng g(-1) dw) were found in sediments from the Xiaoqing River, which was indicative of local point sources in this region. As for other rivers, concentrations of ΣPFAS ranged from 0.218 to 1.583 ng g(-1) dw were found in the coastal sediments and from 0.167 to 1.953 ng g(-1) dw in the riverine sediments. Predominant PFAS from coastal and riverine areas were PFOA and PFBS, with percentages of 30% and 35%, respectively. Partitioning analysis showed the concentrations of PFNA, PFDA and PFHxS were significantly correlated with organic carbon. The results of a preliminary environmental hazard assessment showed that PFOS posed the highest hazard in the Mi River, while PFOA posed a relative higher hazard in the Xiaoqing River., (Copyright © 2013 Elsevier Ltd. All rights reserved.)

Perfluoroalkyl acids (PFAAs) have been used in a variety of products for many years and have been detected worldwide in human serum. Previous studies have suggested the potential effects of PFAAs on serum lipids. To investigate the associations between serum concentrations of PFAAs and serum lipid levels, 133 participants were randomly selected from the people coming for health check-up in Yuanyang Red Cross Hospital of Henan, China. Linear regression analysis revealed that perfluoro-octanoic acid (PFOA), perfluorononanoic acid (PFNA), and perfluorodecanoic acid (PFDA), with a median concentration of 1.43, 0.37, and 0.19 ng/mL, respectively, were positively associated with total cholesterol (TC). Those in the highest quartile of PFOA exposure had ln-TC levels 0.24 mmol/L higher than those in the lowest quartile. For PFNA and PFDA, effect estimates were 0.25 and 0.16 mmol/L, respectively. A positive association between high-density lipoprotein cholesterol (HDLC) and PFDA was found, and there was a 0.18 mmol/L increase of HDLC for the top PFDA quartile compared with the lowest quartile. PFOA and PFNA were positively associated with low-density lipoprotein cholesterol (LDLC). Ln-LDLC levels of people in both top PFOA and PFNA quartiles were 0.33 mmol/L higher than those in the lowest quartiles. Logistic regression analysis indicated that increased PFOA and PFOS quartiles were positively associated with an increased risk of abnormal TC and LDLC when controlling for no confounding factors., (Copyright © 2014 Elsevier Inc. All rights reserved.)

The contamination status and health risks of benzene, toluene, ethylbenzene and xylene (BTEX) in air, soil, dust and groundwater were evaluated in a pesticide chemical region located in Hebei province, China. The concentrations of BTEX in air ranged from 7.80 to 238ug/m(3) and those in soil and dust ranged from lower than limit of detection (LOD) to 32,360ng/g dw, and those in groundwater varied from 2.68 to 98.6ug/L. Generally, the levels of BTEX in multimedia matrixes were all below the standards established in China. Health risk assessment was performed based on the monitoring data via inhalation, dermal contact and ingestion pathways and hazard quotient (HQ) was calculated to be on the order of 10(-7), below 10(-6), and Hazard index (HI) levels of BTEX were lower than 1.0. However, both HQ and HI ascended with an increase in work experience/exposure. Integrated risk management was proposed to eliminate BTEX pollution and to protect occupational health of workers in those industries., (Copyright © 2014 Elsevier Inc. All rights reserved.)

Distributions and magnitude of metals in water, sediment and soil collected from the watershed and estuarine areas of southern Bohai Sea, were investigated. The largest dissolved concentrations of As, Cu and Zn in water were 347.70, 2755.00, 2076.00 μg/L, respectively, much higher than corresponding drinking water guidelines. The greatest concentrations of Cu, Zn, Cr, Ni, Pb, As and Cd in sediments were 1462.2, 1602.17, 196.43, 67.15, 63.54, 73.86 and 1.41 mg/kg, dw, respectively. The mean concentrations of Cu, Ni, Cd, Zn, Cr, Pb and As in soils were 24.67, 24.73, 0.14, 64.75, 56.52, 25.12 and 9.34 mg/kg, dw, respectively. Land use was confirmed to be an important factor of influence on soil metal concentrations. Metal contents along the watershed of Jie River were significantly greater than in other locations. The detection of metals in relatively high concentrations from different environmental matrices in this region indicates the necessity of further studies., (Copyright © 2013 Elsevier Ltd. All rights reserved.)

The concentration of total mercury [Hg] in waters, sediments and biota (carp and crabs) as well as the concentration of methyl mercury [MeHg] in biota from upstream (surface water systems) and downstream (coastal and estuarine systems) areas within coastal watersheds along the Chinese Northern Bohai and Yellow Seas were investigated. In most waters tested, the [Hg] could have adverse effects on coastal wildlife. Based on the Chinese water quality standards for mercury, 67% of upstream waters cannot be used for agriculture or recreation. Furthermore, 53% of downstream waters cannot be used as harbors or for industrial development. The [Hg] in 3% of sediments from the Wuli and Luanhe Rivers were sufficient to cause adverse effects on ecosystems. The [Hg] in 41% of downstream crabs and the [MeHg] in 29% of downstream crabs were higher than the limits for human consumption set by the Chinese government. In all abiotic and biotic samples, only the downstream carp from the Northern Yellow Sea had a [Hg] or [MeHg] higher than those from the Northern Bohai Sea. Industrialization and urbanization were the primary sources of mercury contamination in the aquatic ecosystems studied., (Copyright © 2012 Elsevier B.V. All rights reserved.)

Perfluorinated compounds (PFCs) in water, sediment, soil, and biota collected from estuarine and coastal areas of the north Bohai Sea, China, were determined by use of HPLC-MS/MS. Significant concentrations of PFCs were found in water (mean: 18.4 ng/l) and biologic samples (fish: 265 ng/g dw), while concentrations of PFCs in soils and sediments were less. The predominately detected compound was perfluorooctanesulfonate (PFOS), with a maximum concentration of 30.9 ng/l in water and 791 ng/g dw in fish. Concentrations of PFCs were significantly greater in the Liaohe River system than other locations, which suggests point sources in this urbanized and industrialized region. PFOS concentrations in water and biota were both less than the reported threshold concentrations. Detection of PFCs at relatively great concentrations in various environmental matrices from this region suggested that further studies characterizing concentrations of PFCs, their sources and potential risk to both humans and wildlife are needed., (Copyright © 2011 Elsevier Ltd. All rights reserved.)