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In the natural environment, a symphony of environmental factors including sunlight exposure, current fluctuations, sodium chloride concentrations, and sediment dynamics intertwine, potentially magnifying the impacts on the aging process of disposable face masks (DFMs), thus escalating environmental risks. Employing Regular Two-Level Factorial Design, the study scrutinized interactive impacts of ultraviolet radiation, sand abrasion, acetic acid exposure, sodium chloride levels, and mechanical agitation on mask aging. Aging mechanisms and environmental risks linked with DFMs were elucidated through two-dimensional correlation analyses and risk index method. Following a simulated aging duration of three months, a single mask exhibited the propensity to release a substantial quantity of microplastics, ranging from 38,800 ± 360 to 938,400 ± 529 particles, and heavy metals, with concentrations from 0.06 ± 0.02 μg/g (Pb) to 29.01 ± 1.83 μg/g (Zn). Besides, specific contaminants such as zinc ions (24.24 μg/g), chromium (VI) (4.20 μg/g), thallium (I) (0.92 μg/g), tetracycline (0.51 μg/g), and acenaphthene (1.73 μg/g) can be adsorbed significantly by aged masks. The study elucidates pivotal role of interactions between ultraviolet radiation and acetic acid exposure in exacerbating the environmental risks associated with masks, while emphasizing the pronounced influence of many other interactions. The research provides a comprehensive understanding of the intricate aging processes and ensuing environmental risks posed by DFMs, offering valuable insights essential for developing sustainable management strategies in aquatic ecosystems., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Contaminants of emerging concern (CECs) contained in sludge, such as carbamazepine, may be toxic to microorganisms and affect the biogenesis of methane during anaerobic digestion. In this study, different scales of anaerobic digesters were constructed to investigate the inhibitory effect of carbamazepine. Results showed that carbamazepine reduced methane production by 11.3 % and 62.1 % at concentrations of 0.4 and 2 mg/g TS, respectively. Carbamazepine hindered the dissolution of organic matter and the degradation of protein. Carbamazepine inhibited some fermentative bacteria, especially uncultured Aminicenantales, whose abundance decreased by 9.5-93.4 % under carbamazepine stress. It is worth noting that most prior studies investigated the effects of CECs only based on well-known microorganisms, ignoring the metabolisms of uncultured microorganisms. Genome-predicted metabolic potential suggested that 54 uncultured metagenome-assembled genomes (MAGs) associated with acidogenesis or acetogenesis. Therein, uncultured Aminicenantales related MAGs were proved to be acetogenic fermenters, their significant reduction may be an important reason for the decrease of methane production under carbamazepine stress. The toxicity of carbamazepine to microorganisms was mainly related to the overproduction of reactive oxygen species. This study elucidates the inhibition mechanism of carbamazepine and emphasizes the indispensable role of uncultured microorganisms in anaerobic digestion., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Background: Infective endocarditis is a life-threatening uncommon infectious disease, and we aimed to explore the clinical utility of venous or arterial blood-based metagenomic next-generation sequencing (mNGS) approaches to diagnose left-sided infective endocarditis (LSIE)., Methods: We prospectively studied 79 LSIE patients who received valvular surgery in our hospital. Results of blood culture, valve culture, venous blood-based mNGS, arterial blood-based mNGS, venous blood-based mNGS plus blood culture, and arterial blood-based mNGS plus blood culture were evaluated and compared., Results: Both venous blood- and arterial blood-based mNGS methods displayed significantly higher positive detection rates than blood culture and valve culture (43.0 %, 49.4 % vs. 32.9 %, 19.0 %; P < 0.001). Strikingly, when combining blood-based mNGS and blood culture, the positive rate could be further improved to more than 60 %. Moreover, we found mNGS LSIE detection was closely associated with preoperative leukocyte (P = 0.027), neutrophil value (P = 0.018), vegetation ≥ 14 mm (P = 0.043), and vegetations in aortic valve (P = 0.048). In addition, we discovered that blood-based mNGS had a superir capacity over blood culture to detect gram-negative bacteria, fungi, Bartonella Quintana, and mixed infections than blood culture., Conclusion: This study indicates that venous blood- and arterial blood-based mNGS displayed high positive rate in the rapid detection of pathogens in high-risk LSIE patients., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Practical application of biochar may result in more biochar-derived dissolved organic matter (denoted as BDOM) inevitably release into surface waters by infiltration and surface runoff. The photochemical reaction of BDOM has gained intense attention, which played a key role in the fate of organic contaminants. However, the relationships between specific characteristics of BDOM and its photoreactivity are still uncertain. In this study, the characteristics of BDOM pyrolyzed from rice husk derived biochar at different temperature (from 400 °C to 700 °C) and their effect on the photodegradation of oxytetracycline (OTC) were carefully investigated. The 13 C NMR and EEM results indicated the dominated component of BDOM was gradually turned from humic acid like substances with low aromaticity to high aromaticity with abundant oxygen-containing functional groups as pyrolytic temperature increases. Experimental results showed that the apparent rate constants (k obs ) of BDOM700 (4.53 × 10 -2 min -1 ) for OTC photodegradation was approximately one order of magnitude higher than BDOM400 (4.52 × 10 -3 min -1 ), which was closely correlated with their aromaticity (R 2 = 0.944). It was found that 3 BDOM* rather than 1 O 2 played the major role in BDOM mediated photodegradation of OTC (80.13 % vs 14.34 %), and the carbonyl-containing group was identified as the main 3 BDOM* precursor by NaBH 4 reduction experiment. This work highlighted both aromaticity and carbonyl group contents were critical indicators for assessing the potential to generate 3 BDOM* and corresponding photoreactivity., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Although microplastics are emerging marine pollutants that have recently attracted increasing attention, it is still difficult to identify their sources. This study reviewed 6487 articles to determine current research trends and found 237 effective concentration points after sorting, which were distributed in four regions and related to freshwater ecosystems. Results found that 15 environmental variables represented natural and anthropogenic environmental characteristics, of which seven environmental variables were selected for experimental modelling. Random forest models fitted sample data, thus facilitating the identification of regional microplastics distribution. The global random forest model had random forest importance scores (RFISs) for gross domestic product, population, and the proportion of agricultural land use were 15.76 %, 15.64 %, and 14.74 %, respectively; these indicate that human activities significantly affected the global distribution of microplastics. In Asia, agriculture and urban activities are the main sources of microplastics, with an RFIS of 11.58 % and 12.24 % for the proportion of agricultural and urban land use, respectively. Activities in urban areas were determined to be the main influencing factors in North America, with an RFIS of 13.92 % for the proportion of urban land use. Agricultural activities were the main influencing factors in Europe, with RFISs for the proportion of agricultural land use of 16.90 %. Our results indicate that region-specific policies are required to control microplastics in different regions, with soil composition being a latency factor that affects microplastics' distribution., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have influenced the research reported in this study., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Microplastics (MPs) are substrates available for biofilms colonization in natural water environments. The biofilms formation may enhance the ability of MPs to adsorb harmful contaminants. Herein, we investigated the biofilms formation of three different MPs (PVC, PA and HDPE) in simulated natural environment, and observed the chemical structure, charge property, hydrophobicity and other properties of MPs affect microbial biomass and community composition. More importantly, potential pathogens were found in all three MPs biofilms. Furthermore, the adsorption capacities of original MPs and biological aging MPs for norfloxacin (NOR) was compared. HDPE has the largest adsorption capacity for NOR, while PA has the smallest adsorption capacity for NOR. It was concluded that the formation of biofilms enhanced the adsorption of NOR by 50.60 %, 24.17 % and 46.02 % for PVC, PA and HDPE, respectively. In addition, hydrogen-bond interaction, electrostatic interaction and hydrophobic interaction were found to dominate the adsorption of NOR by MPs. Our study contributed to improve the understanding of the interactions between aging MPs and contaminants in the natural water environments, and provided essential information for ecological risk assessment of MPs., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Environmental pollution has drawn forth advanced materials and progressive techniques concentrating on sustainable development. Metal-organic frameworks (MOFs) have aroused vast interest resulting from their excellent property in structure and function. Conversely, powdery MOFs in highly crystalline follow with fragility, poor processability and recoverability. Aerogels distinguished by the unique three-dimensional (3D) interconnected pore structures with high porosity and accessible surface area are promising carriers for MOFs. Given these, combining MOFs with aerogels at molecule level to obtain advanced composites is excepted to further enhance their performance with higher practicability. Herein, we focus on the latest studies on the MOFs@aerogel composites. The construction of MOFs@aerogel with different synthetic routes and drying methods are discussed. To explore the connection between structure and performance, pore structure engineering and quantitation of MOFs content are outlined. Furthermore, various types of MOFs@aerogel composites and their carbonized derivatives are reviewed, as well as the applications of MOFs@aerogel for environmental remediation referring to water purification and air clearing. More importantly, outlooks towards these emerging advanced composites have been presented from the perspective of practical application and future development., (Copyright © 2022 Elsevier B.V. All rights reserved.)

MOF-derived multi-metal nanomaterials are attracting numerous attentions in widespread applications such as catalysis, sensors, energy storage and conversion, and environmental remediation. Compared to the monometallic counterparts, the presence of foreign metal is expected to bring new physicochemical properties, thus exhibiting synergistic effect for enhanced performance. MOFs have been proved as a good platform for the fabrication of polymetallic nanomaterials with requisite features. Herein, various design strategies related to constructing multi-metallic nanomaterials from MOFs are summarized for the first time, involving metal nodal substitution, seed epitaxial growth, ion-exchange strategy, guest species encapsulation, solution impregnation and combination with extraneous substrate. Afterwards, the recent advances of multi-metallic nanomaterials for electrocatalytic applications, including oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), are systematically discussed. Finally, a personal outlook on the future trends and challenges are also presented with hope to enlighten deeper understanding and new thoughts for the development of multi-metal nanomaterials from MOFs., (Copyright © 2022. Published by Elsevier B.V.)

The application of traditional powder catalysts is limited by particle agglomeration and difficult recovery. In this work, a three-dimensional porous aerogel catalyst for organic pollutants degradation in water by activating peroxydisulfate (PDS) was successfully synthesized, which was obtained via directly mixing of MIL-88B(Fe) with sol precursors followed by vacuum freeze-drying and low-temperature calcination. MIL-88B(Fe)/gelatin aerogel-150/PDS (MGA-150/PDS) system displayed satisfactory norfloxacin (NOR) degradation performance, which could remove 98.7% of NOR in 90 min. Its reaction rate constant was 23.2 times higher than the gelatin aerogel/PDS (GA/PDS) system. In addition, Electron paramagnetic resonance (EPR) results and radical trapping experiments revealed both radicals (SO 4 •- , •OH) and non-radical ( 1 O 2 ) pathways had participated in NOR degradation, of which •OH was dominant. Possible degradation pathways were proposed. Moreover, the high degradation efficiency of NOR by MGA-150 composites could still be reached more than 90.0% even after 10 cycles, and the morphology and chemical structure of MGA-150 composites exhibited no significant changes, indicating the arrestive stability of aerogel composites. This progress not only proposed an effective catalyst for PDS activation, but also expanded views for the design and development of 3D functional materials., (Copyright © 2021 Elsevier B.V. All rights reserved.)

The excellent properties of plastics make them widely used all over the world. However, when plastics enter the environmental medium, microplastics will inevitably be produced due to physical, chemical and biological factors. Studies have shown that microplastics have been detected in terrestrial, aquatic and atmospheric environments. In addition, the presence of microplastics will provide a new artificial adhesion substrate for biofilms. It has been proved that the formation of biofilms could significantly change some properties of microplastics. Some studies have found that microplastics attached with biofilms have higher environmental risks and eco-toxicity. Therefore, considering the widespread existence of microplastics and the ecological risks of microplastic biofilms, the physical and chemical properties of biofilms on microplastics and their impact on microplastics in aqueous environment are worth reviewing. In this paper, we comprehensively reviewed representative studies in this area. Firstly, this study reviews that the existence of biofilms could change the transport and deposition of microplastics. Subsequently, the presence of biofilms would enhance the ability of microplastics to accumulate pollutant, such as persistent organic pollutants, heavy metals and antibiotics. Moreover, the effect of biofilms on microplastics enrichment of harmful microorganisms is summarized. Finally, some future research needs and strategies are proposed to better understand the problem of biofilms on microplastics., (Copyright © 2021 Elsevier B.V. All rights reserved.)

This study explored the fate of mobile genetic elements (MGEs) in anaerobic digestion (AD) system with four nanoparticles (NPs) added, including carbon NPs, Al 2 O 3 NPs, ZnO NPs, and CuO NPs. 16S rRNA amplicon sequencing and quantitative PCR to investigate the microbial community, MGEs abundance and the potential host in the AD process. The results of high-throughput sequencing showed that ZnO NPs and CuO NPs significantly reduced the microbial diversity and significantly changed the microbial community structure. Simultaneously, the absolute abundance of MGEs increased by 145.01%, 159.67%, 354.70%, and 132.80% on the carbon NPs, Al 2 O 3 NPs, ZnO NPs, and CuO NPs. The enrichment rate of tnpA-03 in ZnO NPs group was the highest, which could reach up to 2854.80%. Co-occurrence analysis revealed that Proteobacteria harbored the vast majority of MGEs followed by Firmicutes. Redundancy analysis and variation partitioning analysis showed that metabolites were the main factors that shifted the succession of bacterial communities. Moreover, there were significant positive correlations between metabolites and part MGEs (such as tnpA-01, tnpA-02, tnpA-03, tnpA-04, tnpA-05, tnpA-07 and ISCR1). This study provides a new perspective that NPs increase the risk of antibiotic resistance through MGEs during AD process., (Copyright © 2020 Elsevier B.V. All rights reserved.)

The emergence of triclosan (TCS) in the environment has caused extensive concern, but its role in waste activated sludge (WAS) anaerobic fermentation (AF) is still uncertain. This work investigated the impact of TCS on volatile fatty acids (VFAs) recycling from WAS. The results showed that TCS of 200 mg/kg TSS increased the maximum VFA accumulation from 7284 to 15,083 mg COD/L. The increase in total VFA production is attributed to the massive increase in acetic acid. Mechanism exploration showed that TCS promotes WAS solubilization by facilitating cell breakage and extracellular polymeric substances disruption, and stimulates AF by enhancing the activity of key enzymes among all stages. TCS promotes acidification stronger than methanogenesis, which makes VFA production faster than consumption, leading to increased VFA accumulation. These findings provide novel insights for revealing the role of TCS in WAS resource recovery, and offer thoughts for the selective production of final recycling products of TCS-containing WAS., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

N-doped nanoporous carbon (NC) with two-dimensional structure derived from Zn-ZIF-L via KCl exfoliation and carbonization at different temperature were prepared for adsorptive removal of tetracycline (TC). Characterizations revealed the effective dopant of N atoms and low degree of graphitization with more defects related to the enhanced adsorption capacity of the NC materials. Benefiting from the huge surface area (2195.57 m 2 g -1 ), high porosity (1.34 cm 3 g -1 ) and accessible sheeting structure, the NC-800 exhibited its fast and efficient adsorption of TC in 60 min. Meantime, the maximum adsorption of TC could reach 347.06 mg g -1 . Effects of pH, humic acid (HA) and ionic strength (Na + , Ca 2+ ) were studied along with the interactions among influencing factors investigated by response surface model (RSM). By optimizing experimental conditions from RSM, the adsorption capacity could increase to 427.41 mg g -1 . Additionally, electrostatic interaction and hydrogen bond interaction might play a dominating role in adsorption reaction. The NC-800 could maintain a high adsorption level after four cycles. Therefore, the NC-800 with great adsorptive property and reusability could be considered as an effective adsorbent with promising potential in applications for water treatment., (Copyright © 2020 Elsevier B.V. All rights reserved.)

The development of carbon materials brings a new two-dimensional catalyst support, graphdiyne (GDY), which is attracting increasing interest in the field of catalysis. This article presents a systematical review of recent studies about the characteristics, design strategies, and applications of GDY-supported catalysts. The sp- and sp 2 -hybridized carbon, high electrical conductivity, direct band gap, and high intrinsic carrier mobility are key characteristics for GDY to serve as a competitive catalyst support. Hydrothermal method (or solvothermal method), GDY in-situ growth, and electrochemical deposition are commonly used to load catalysts on GDY support. In the applications of GDY-supported photocatalysts, GDY mainly serves as an electron or hole transfer material. For the electrocatalytic hydrogen production, the unique electronic structure and high electrical conductivity of GDY can promote the electron transfer and water splitting kinetics. This review is expected to provide meaningful insight and guidance for the design of GDY-supported catalysts and their applications., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

In this work, we investigated the impact of iron nanoparticle, including magnetite nanoparticles (Fe 3 O 4 NPs) and nanoscale zero-valent iron (nZVI), on the anaerobic digestion (AD) performance. Moreover, the evolutions of antibiotic resistance genes (ARGs), class 1 integrons-integrase (intI1) and potential hosts of ARGs were also investigated. The optimal addition of Fe 3 O 4 NPs and nZVI to promote methane production was 0.5 g/L and 1 g/L, which led to 22.07% and 23.02% increase in methane yield, respectively. The degradation rate of organic matter was also enhanced with the addition of Fe 3 O 4 NPs or nZVI. The results of high-throughput sequencing showed that the reactors with iron NPs exhibited significant differences in microbial community structure, compared to the reactors with the non‑iron NPs. Iron NPs have caused the relative abundance of the dominant bacteria (Proteobacteria, Firmicutes and Actinobacteria) generally decreased, while the dominant archaea (Euryarchaeota) increased in AD sludge. Quantitative PCR results revealed that iron NPs accelerated the reductions in total absolute abundance of ARGs, especially a beta-lactamase resistance encoded gene (blaOXA). Network analysis displayed that the attenuation of ARGs was mainly attributed to the decline of potential hosts (Proteobacteria, Firmicutes and Actinobacteria). Meanwhile, environmental factors (such as pH, soluble chemical oxygen demand and heavy metals) were also strongly correlated with ARGs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Polymeric carbon nitride (PCN) has become the most promising metal-free photocatalysts but its activity is low. Molecule doping of PCN has been proved to be an effective strategy to achieve high photocatalytic performance. Herein, we report a bottom-up method to synthesize modified PCN, which includes 2,5-dibromopyrazine doping, thermal-induced exfoliation and condensation/polymerization. The incorporation of electron-deficiency 2,5-dibromopyrazine into the PCN framework can effectively tune the electronic structures and improve the charge-carrier separation. In addition, the incorporation of 2,5-dibromopyrazine induced significant structural changes from planar symmetric to distortion. The optimized pyrazine doped PCN showed a reaction rate enhancement of 4-fold for the degradation of sulfamethazine compared to that of conventional urea-based PCN. Further reactive species and degradation intermediate detection studies, indicated that O 2 - was generated during the photocatalytic process, which could lead to the decomposition, and finally mineralization of sulfamethazine. 2,5-Dibromopyrazine doped PCN also leads to a 6.3-fold improvement in H 2 generation with the visible light. Especially, phytotoxicity experiments showed that the toxicity of sulfamethazine after degradation is greatly reduced, and the as-prepared photocatalyst is environmentally friendly., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Polymeric carbon nitride semiconductor has been explored as emerging metal-free photocatalyst for solving the energy shortage and environmental issues. However, the efficiency of carbon nitride is still not satisfying. Herein, a facile copolymerization between L-cysteine and dicyandiamide has been applied to forming the modified carbon nitride photocatalysts. The photocatalytic performance was evaluated through degrading sulfamethazine under visible light illumination. The ameliorative structure and tuned energy band result in visible-light adsorption enhancement. In addition, nitrogen vacancies offer more sites to adsorbing molecular oxygen, thereby facilitating the transfer of electrons from carbon nitride to the surface adsorbed oxygen. As a result, the degradation rate of optimized modified carbon nitride sample for sulfamethazine was 0.1062 min -1 , which was almost 12 times than that of carbon nitride (0.0086 min -1 ). Superoxide radicals and holes were mainly responsible for the sulfamethazine photodegradation by modified carbon nitride. Two reaction intermediates/products were observed and identified by high performance liquid chromatography-mass spectrometer, and a possible reaction pathway was proposed. This study provides new insights into the design of highly efficient photocatalyst for other organic pollutants degradation., (Copyright © 2019 Elsevier B.V. All rights reserved.)

As the functional material, iron nanoparticles effectively promote anaerobic digestion (AD) process, including the hydrolysis-acidification process and the biogas production. In this study, nano zero-valent iron (nZVI) and Fe 3 O 4 nanoparticles (Fe 3 O 4 NPs) were added to AD reactors respectively. The AD process was evaluated by the reactors performances, including pH, biogas yields and compositions, as well as the removal ratio of total solids (TS), volatile solids (VS) and soluble chemical oxygen demand (sCOD). Three models (first-order kinetic model, transfer function model and Cone model) were used to explore the kinetics of AD biogas production. The results showed that adding appropriate dose of nZVI or Fe 3 O 4 NPs enhanced anaerobic digestibility of sludge. The highest cumulative biogas yield of 140.34 L with 0.5 g L -1 nZVI and 137.13 L with 1 g L -1 Fe 3 O 4 NPs were obtained by the 80 days of mesophilic operation, respectively. Cumulative biogas productions of these two reactors were significantly enhanced up to 15.70% and 13.44%. TS removal rates reached >70% in all AD reactors with iron nanoparticles, and the highest sCOD removal rates of nZVI and Fe 3 O 4 NPs digesters on the 80th day were 88.22% and 77.63%, respectively. The results of the three-day fermentation experiment and the kinetic parameters showed that the nZVI or Fe 3 O 4 NPs enhanced the hydrolysis-acidification process of the AD, which eventually promoted biogas production. The Cone model was satisfied with the experimental results, which could be used to evaluate the kinetics of AD with iron nanoparticles more reasonably., (Copyright © 2019 Elsevier B.V. All rights reserved.)

With the increasing requirement of efficient organic transformations on the basic concept of Green Sustainable Chemistry, the development of highly efficient catalytic reaction system is greatly desired. In this case, gold (Au)-based nanocatalysts are promising candidates for catalytic reaction, especially for the reduction of nitroaromatics. They have attracted wide attention and well developed in the application of nitroaromatics reduction because of the unique properties compared with that of other conventional metal-based catalysts. With this respect, this review proposes recent trends in the application of Au nanocatalysts for efficient reduction process of nitroaromatics. Some typical approaches are compared and discussed to guide the synthesis of highly efficient Au nanocatalysts. The mechanism on the use of H 2 and NaBH 4 solution as the source of hydrogen is compared, and that proposed under light irradiation is discussed. The high and unique catalytic activity of some carriers, such as oxides and carbons-based materials, based on different sizes, structures, and shapes of supported Au nanocatalysts for nitroaromatics reduction are described. The catalytic performance of Au combining with other metal nanoparticles by alloy or doping, like multi-metal nanoparticles system, is further discussed. Finally, a short discussion is introduced to compare the catalysis with other metallic nanocatalysts., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Chromium metal-organic framework (MIL-101(Cr)) has been widely studied for removing organic contaminants from aqueous solutions due to its excellent water stability and giant pore size, but its low adsorption capacity limits the application. In this study, a new adsorbent MIL-101 loaded with CuCo bimetallic nanoparticles (CuCo/MIL-101) was successfully fabricated and applied in removal of tetracycline (TC) from aqueous solutions. The adsorption capacity of CuCo/MIL-101 for TC increased by 140% compared with that of pure MIL-101, which may be attributed to the chemical bonding between Cu and Co BNPs in MIL-101 and TC molecules. The effects of pH, ionic strength, humic acid and contact time on the adsorption were also discussed in detail. The results showed that the removal efficiency of TC solution with high concentration (100 mg L -1 ) by CuCo/MIL-101 was still as high as 82.9%. The data of adsorption kinetics and isotherms could be well fitted by Elovich model and Freundlich model, respectively. According to the fitting parameters, the maximum adsorption capacity of CuCo/MIL-101 reached up to 225.179 mg g -1 . Additionally, the adsorption process of TC onto CuCo/MIL-101 was spontaneous and endothermic. Electrostatic interactions could play an important role in the adsorption process. The enhanced adsorption capacity, excellent reusability and water stability demonstrated the potential of CuCo/MIL-101 composite as a novel adsorbent for the removal of TC from aqueous solutions., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Eight new triterpenoids, ganoleucoins T-Z(1-3, 5-8), and AA (9), together with eleven known triterpenes were isolated and identified from the wild fruiting bodies of the medicinal mushroom Ganoderma leucocontextum. The structures of new compounds were determined on the basis of NMR and MS spectral analysis. The inhibitory effects of 1-9 on HMG-CoA reductase were tested in vitro. Compounds 1, 7 and 8 showed significant HMG-CoA reductase inhibition with IC 50 values of 10.2, 9.72 and 8.68 μM, respectively. The other isolated compounds presented relatively weak inhibitory activity with IC 50 values >100 μM. Preliminary structure-activity relationship analysis showed that the HMG moiety in 7 and 8 contributed greatly to their inhibitory activity against HMG-CoA reductase. This work further demonstrates the mushroom G. leucocontextum to be valuable herbal medicine that deserves deep investigation., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Genetically engineered bacteria for pollution control of heavy metal have been widely studied, however, using Pseudomonas aeruginosa (P. aeruginosa) that can adapt to various circumstances to remediate heavy metal pollution is rarely reported. In this study, we employed CadR, a cadmium (Cd)-specific binding protein, displaying on the surface of P. aeruginosa with chromosomal expression. The genetically engineered (GE) P. aeruginosa still flourished in the 30th generation in the LB broth which contained 100 μM Cd(II), exhibiting an excellent genetic stability. Chromosomally expressed P. aeruginosa showed an adsorption capacity of up to 131.9 μmol/g of Cd(II). In addition, the low concentration of the coexisting two valence ions has no significant effect on adsorption capacity of Cd(II). This study provides a direction for application of P. aeruginosa in environment remediation., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Adsorption of tetracycline antibiotics from aqueous solutions by a multi-walled carbon nanotube (MWCNT) loaded iron metal-organic framework (MIL-53(Fe)) composite was studied. The adsorbent was characterized by environmental scanning electron microscope, energy dispersive X-ray spectroscopy, brunauer-emmett-teller, thermogravimetric analysis, X-ray diffraction, fourier transform infrared spectrum, and X-ray photoelectron spectrum. The adsorption kinetics of tetracycline hydrochloride (TCN), oxytetracycline hydrochloride (OTC), and chlortetracycline hydrochloride (CTC) were all well fitted to the pseudo-second-order equation as well as the adsorption isotherms could be well delineated via Langmuir equations. The main influencing factors such as pH and ionic strength were studied in detail. At initial pH of 7.0, maximum adsorption capacity of TCN, OTC and CTC on MWCNT/MIL-53(Fe) was 364.37, 325.59, 180.68 mg·g -1 at 25 °C, which was 1.25, 8.28 and 3.34 times than that of single MWCNT, respectively. The adsorption capacity of TCS for this adsorbent was in the order: TCN > OTC > CTC, which was determined by the adsorbate molecule magnitude. In addition, π-π adsorbate-adsorbent interactions played an important role during the adsorption process. The excellent reusability and great water stability indicated the potential application of this novel composite in the removal of TCS from aqueous solutions., (Copyright © 2018. Published by Elsevier B.V.)

Energy and environmental issues are the major concerns in our contemporary "risk society". As a green technique, photocatalysis has been identified as a promising solution for above-mentioned problems. In recent decade, BiOX (X = Cl, Br, I) photocatalytic nanomaterials have sparked numerous interest as economical and efficient photocatalysts for energy conversion and environmental management. The distinctive physicochemical properties of BiOX nanomaterials, especially their energy band structures and levels as well as relaxed layered nanostructures, should be responsible for the visible-light-driven photocatalytic performance improvement, which could be utilized in dealing with the global energy and environmental challenges. In this review, recent advances for the enhancement of BiOX photocatalytic activity are detailedly summarized. Furthermore, the applications of BiOX photocatalysts in water splitting and refractory organic pollutants removal are highlighted to offer guidelines for better development in photocatalysis. Particularly, no relative reports in previous studies were documented in CO 2 reduction as well as heavy metals and air pollutants removal, thus this review presented as a considerable research value. Challenges in the construction of high-performance BiOX-based photocatalytic systems are also discussed. With the exponential growth of studies on BiOX photocatalytic nanomaterials, this review provides unique and comprehensive perspectives to design BiOX-based photocatalytic systems with superior visible light photocatalytic activity. The knowledge of both the merits and demerits of BiOX photocatalysts are updated and provided as a reference., (Copyright © 2018 Elsevier B.V. All rights reserved.)