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Summary: Ecological engineering of soil formation in tailings is an emerging technology toward sustainable rehabilitation of iron (Fe) ore tailings landscapes worldwide, which requires the formation of well-organized and stable soil aggregates in finely textured tailings. Here, we demonstrate an approach using microbial and rhizosphere processes to progressively drive aggregate formation and development in Fe ore tailings. The aggregates were initially formed through the agglomeration of mineral particles by organic cements derived from microbial decomposition of exogenous organic matter. The aggregate stability was consolidated by colloidal nanosized Fe(III)-Si minerals formed during Fe-bearing primary mineral weathering driven by rhizosphere biogeochemical processes of pioneer plants. From these findings, we proposed a conceptual model for progressive aggregate structure development in the tailings with Fe(III)-Si rich cements as core nuclei. This renewable resource dependent eco-engineering approach opens a sustainable pathway to achieve resilient tailings rehabilitation without resorting to excavating natural soil resources.

The impacts of macroplastics (macro-), microplastics (MPs,

Arsenic exists universally in freshwater and marine environments, threatening the survival of aquatic organisms and human health. To elucidate arsenic bioaccumulation and biotransformation processes in aquatic organisms, this review evaluates the dissolved uptake, dietary assimilation, biotransformation, and elimination of arsenic in aquatic organisms and discusses the major factors influencing these processes. Environmental factors such as phosphorus concentration, pH, salinity, and dissolved organic matter influence arsenic absorption from aquatic systems, whereas ingestion rate, gut passage time, and gut environment affect the assimilation of arsenic from foodstuffs. Arsenic bioaccumulation and biotransformation mechanisms differ depending on specific arsenic species and the involved aquatic organism. Although some enzymes engaged in arsenic biotransformation are known, deciphering the complicated synthesis and degradation pathway of arsenobetaine remains a challenge. The elimination of arsenic involves many processes, such as fecal excretion, renal elimination, molting, and reproductive processes. This review facilitates our understanding of the environmental behavior and biological fate of arsenic and contributes to regulation of the environmental risk posed by arsenic pollution.

Global development has been heavily reliant on the overexploitation of natural resources since the Industrial Revolution. With the extensive use of fossil fuels, deforestation, and other forms of land-use change, anthropogenic activities have contributed to the ever-increasing concentrations of greenhouse gases (GHGs) in the atmosphere, causing global climate change. In response to the worsening global climate change, achieving carbon neutrality by 2050 is the most pressing task on the planet. To this end, it is of utmost importance and a significant challenge to reform the current production systems to reduce GHG emissions and promote the capture of CO2 from the atmosphere. Herein, we review innovative technologies that offer solutions achieving carbon (C) neutrality and sustainable development, including those for renewable energy production, food system transformation, waste valorization, C sink conservation, and C-negative manufacturing. The wealth of knowledge disseminated in this review could inspire the global community and drive the further development of innovative technologies to mitigate climate change and sustainably support human activities.

The effect and mechanistic evidence of biochar on the (im)mobilization of potentially toxic elements (PTEs) in multi-contaminated soils, with respect to the role of surface-functional groups and organic/inorganic compounds of biochar, are poorly understood. Herein, biochars produced from grass residues, rice straw, and wood were applied to a mining-soil contaminated with As, Cd, Pb, and Zn for 473-d. Biochars did not reduce the mobilization of Cd and Zn, whereas they simultaneously exhibited disparate effects on As and Pb mobilization. The phenolic hydroxyl and carboxylic groups on the wood biochar’s surfaces promoted the conversion of Pb2+ into PbCO3/Pb(OH)2 and/or PbO, minimally by the rice and grass biochars. Rice and grass biochars led to the dissolution of scorodite and the formation of less stable forms of Fe-oxide-bound As (i.e., goethite and ferrihydrite); furthermore, it resulted in the reduction of As(V) to As(III). The PTEs mobilization and phytoavailability was mainly governed by the release of dissolved aliphatic- and aromatic-carbon, chloride, sulfur chemistry, phosphate competition, and the electrostatic repulsion in biochar-treated soils. In conclusion, pristine-biochar has a limited impact on the remediation of multi-contaminated soils, and the use of modified-biochar, possessing higher surface areas and functionality and active exchange sites, are preferred under such conditions.

Human exposure to arsenic (As) through the consumption of rice (Oryza sativa L.) is a worldwide health concern. In this paper, we evaluated the major causes for high inorganic As levels in cooked rice foods, and the potential of post-harvesting and cooking options for decreasing inorganic As content in cooked rice, focusing particularly on As endemic areas. The key factors for high As concentration in cooked rice in As endemic areas are: (1) rice cultivation on As-contaminated paddy soils; (2) use of raw rice grains which exceed 200 μg kg−1 of inorganic As to cook rice; and (3) use of As-contaminated water for cooking rice. In vitro and in vivo methods can provide useful information regarding the bioaccessibility of As in the gastrointestinal tract. Urinary levels of As can also be used as a valid measure of As exposure in humans. Polishing of raw rice grains has been found to be a method to decrease total As content in cooked rice. Sequential washing of raw rice grains and use of an excess volume of water for cooking also decrease As content in cooked rice. The major concern with those methods (i.e. polishing of raw rice, sequential washing of raw rice, and use of excess volume of water for cooking rice) is the decreased nutrient content in the cooked rice. Cooking rice in percolating water has recently gained significant attention as a way to decrease As content in cooked rice. Introducing and promoting rainwater harvesting systems in As endemic areas may be a sustainable way of reducing the use of As-contaminated water for cooking purposes. In conclusion, post-harvesting methods and changes in cooking practices could reduce As content in cooked rice to a greater extent. Research gaps and directions for future studies in relation to different post-harvesting and cooking practices, and rainwater harvesting systems are also discussed in this review. Keywords: Arsenic speciation, Cooked rice, Health risks, Arsenic mitigation, Arsenic-contaminated water

Mercury (Hg) is a highly toxic element, which is frequently enriched in flooded soils due to its anthropogenic release. The mobilization of Hg and its species is of ultimate importance since it controls the transfer into the groundwater and plants and finally ends in the food chain, which has large implications on human health. Therefore, the remediation of those contaminated sites is an urgent need to protect humans and the environment. Often, the stabilization of Hg using amendments is a reliable option and biochar is considered a candidate to fulfill this purpose. We tested two different pine cone biochars pyrolyzed at 200 °C or 500 °C, respectively, with a view to decrease the mobilization of total Hg (Hgt), methylmercury (MeHg), and ethylmercury (EtHg) and/or the formation of MeHg and EtHg in a contaminated floodplain soil (Hgt: 41 mg/kg). We used a highly sophisticated automated biogeochemical microcosm setup to systematically alter the redox conditions from ~−150 to 300 mV. We continuously monitored the redox potential (EH) along with pH and determined dissolved organic carbon (DOC), SUVA254, chloride (Cl−), sulfate (SO42−), iron (Fe), and manganese (Mn) to be able to explain the mobilization of Hg and its species.However, the impact of biochar addition on Hg mobilization was limited. We did not observe a significant decrease of Hgt, MeHg, and EtHg concentrations after treating the soil with the different biochars, presumably because potential binding sites for Hg were occupied by other ions and/or blocked by biofilm. Solubilization of Hg bound to DOC upon flooding of the soils might have occurred which could be an indirect impact of EH on Hg mobilization. Nevertheless, Hgt, MeHg, and EtHg in the slurry fluctuated between 0.9 and 52.0 μg/l, 11.1 to 406.0 ng/l, and 2.3 to 20.8 ng/l, respectively, under dynamic redox conditions. Total Hg concentrations were inversely related to the EH; however, ethylation of Hg was favored at an EH around 0 mV while methylation was enhanced between −50 and 100 mV. Phospholipid fatty acid profiles suggest that sulfate-reducing bacteria may have been the principal methylators in our experiment. In future, various biochars should be tested to evaluate their potential in decreasing the mobilization of Hg and to impede the formation of MeHg and EtHg under dynamic redox conditions in frequently flooded soils. Keywords: Mercury, Redox processes, Wetlands, Biochar, Agro-environmental management, PLFA

Trace elements (TEs) may have toxic effects to plants and humans; thus, countries and organizations impose maximum allowable regulation limits of their concentrations in soils. Usually such limits are placed in different categories according to soil use, soil properties or based on both attributes. However, some countries have regulation limits irrespective of differentiation in soil properties. In this review, we aimed at collecting TE regulation limits in soils from major countries and organizations around the globe, and critiquing them by assessing potential human health risks in the case of soils attaining the maximum allowable values. We explored the soil-to-human pathway and differentiated among three major exposures from TEs, i.e., residential, industrial and agricultural. We observed the existence of problems concerning TE regulation limits, among which the fact that limits across countries do not regulate the same TEs, not even a minimum number of TEs. This indicates that countries do not seem to agree on which regulation limits of TEs pose a high risk. Also, these regulation limits do not take into account TE mobility to neighbouring environment interphases such as plant, especially edible, and water matrices. Moreover, limits for same TEs are vastly diverse across countries; this indicates that those countries have conflicting information concerning TE-related health risks. Subsequently, we addressed this problem of diversity by quantifying resultant risks; we did that by calculating human health risk indices, taking into consideration the cases in which the highest allowable TE limits are attained in soil. Arsenic limits were found to generate a relatively high hazard quotient (HQi, accounting for human intake over the maximum allowable oral reference dose for that same TE), indicating that its risk tends to be underestimated. Other TE limits, such as those of Cd, Cu, Ni, Pb, and Zn typically result in low HQi, meaning that limits in their cases are rather overprotective. Our approach reveals the need of reducing diversity in regulation limits by drafting soil legislations of worldwide validity, since risks are common across countries. We suggest that new directions should strategically tend to (a) reduce limits of TEs with underestimated contribution to health risk (such as As), (b) cautiously increase limits of TEs that currently cause minor health risks, (c) quantify TE risks associated with uptake to edible plants and potable water, and (d) consider multi-element contamination cases, where risks are cumulatively enhanced due to TE synergism. Keywords: Metal(loid)s, Soils, Critical limits, Health risk assessment

The tremendous amount of food waste from diverse sources is an environmental burden if disposed of inappropriately. Thus, implementation of a biorefinery platform for food waste is an ideal option to pursue (e.g., production of value-added products while reducing the volume of waste). The adoption of such a process is expected to reduce the production cost of biodegradable plastics (e.g., compared to conventional routes of production using overpriced pure substrates (e.g., glucose)). This review focuses on current technologies for the production of polyhydroxyalkanoates (PHA) from food waste. Technical details were also described to offer clear insights into diverse pretreatments for preparation of raw materials for the actual production of bioplastic (from food wastes). In this respect, particular attention was paid to fermentation technologies based on pure and mixed cultures. A clear description on the chemical modification of starch, cellulose, chitin, and caprolactone is also provided with a number of case studies (covering PHA-based products) along with a discussion on the prospects of food waste valorization approaches and their economic/technical viability. Keywords: Food waste, Valorization, Biorefinery, Polyhydroxyalkanoates (PHA), Biopolymer, Bioplastic

Exchangeable lead (Pb) extracted by ammonium acetate from three independent incubation studies was assessed to understand the influence of feedstock, pyrolysis temperatures, and production conditions on Pb immobilization capacities of different biochars. Vegetable waste biochar, pine cone, wood bark, cocopeat, red pepper stalk, and palm kernel shell were used as feedstocks (food supply and agricultural wastes) to produce biochars at 200–650 °C with and without N2/CO2. Biochars were applied at 5 and 2.5% (w w−1) to a Pb contaminated (i.e., 1445 mg kg−1) agricultural soil collected near an old mine. Lead immobilization in biochar treated soils at the end of incubation period was normalized per gram of biochar applied. Biochar produced from vegetable waste at 500 °C showed the highest Pb immobilization (87%) and highest total exchangeable cations (13.5 cmol(+) kg−1) at the end of the 45 d incubation period. However, on the basis of Pb immobilization per gram of biochar, red pepper stalk biochar produced in CO2 at 650 °C was the best in Pb immobilization (0.09 mg kg−1 g−1 biochar) compared to the other biochars. The enhanced ability to immobilize Pb by biochar produced in CO2 could be due to the presence of siloxanes (SiOSi) on biochar surface. Pearson correlation analysis revealed that alkaline pH, ash%, and N% of biochars influence in Pb immobilization and exchangeable cation availability in soil. Biochar production atmosphere considerably change its properties that influence Pb immobilization. Further studies are needed on the modification of properties and Pb immobilization by biochars produced from various feedstocks in CO2. Keywords: CO2 pyrolysis, Soil stabilization, Metals/metalloids, Waste valorization/recycling, Black carbon, Engineered biochar

Little is known about the effects of applying amendments on soil for immobilizing metal(loid)s on the soil microbial community. Alterations in the microbial community were examined after incubation of treated contaminated soils. One soil was contaminated with Pb and As, a second soil with Cd and Zn. Red pepper stalk (RPS) and biochars produced from RPS in either N2 atmosphere (RPSN) or CO2 atmosphere (RPSC) were applied at a rate of 2.5% to the two soils and incubated for 30 days. Bacterial communities of control and treated soils were characterized by sequencing 16S rRNA genes using the Illumina MiSeq sequencing. In both soils, bacterial richness increased in the amended soils, though somewhat differently between the treatments. Evenness values decreased significantly, and the final overall diversities were reduced. The neutralization of pH, reduced available concentrations of Pb or Cd, and supplementation of available carbon and surface area could be possible factors affecting the community changes. Biochar amendments caused the soil bacterial communities to become more similar than those in the not amended soils. The bacterial community structures at the phylum and genus levels showed that amendment addition might restore the normal bacterial community of soils, and cause soil bacterial communities in contaminated soils to normalize and stabilize. Keywords: Bacterial diversity, Community structure, Charcoal, Engineered biochar, Potentially toxic element

Stabilization/solidification (S/S) is a low-cost and high-efficiency remediation method for contaminated soils, however, conventional cement-based S/S method has environmental constraints and sustainability concerns. This study proposes a low-carbon, cement-free, clay-based approach for simultaneous S/S of As and Pb in the contaminated soil, and accordingly elucidates the chemical interactions between alkali-activated clay binders and potentially toxic elements. Quantitative X-ray diffraction and 27Al nuclear magnetic resonance analyses indicated that the addition of lime effectively activated the hydration of kaolinite clay, and the presence of limestone further enhanced the polymerization of hydrates. X-ray photoelectron spectroscopy showed that approximately 19% of As[III] was oxidized to As[V] in the alkali-activated clay system, which reduced toxicity and facilitated immobilization of As. During the cement-free S/S process, As and Pb consumed Ca(OH)2 and precipitated as Ca3(AsO4)2·4H2O and Pb3(NO3)(OH)5, respectively, accounting for the low leachability of As (7.0%) and Pb (5.4%). However, the reduced amount of Ca(OH)2 decreased the degree of hydration of clay minerals, and the pH buffering capacity of the contaminated soil hindered the pH increase. Sufficient dosage of lime was required for ensuring satisfactory solidification and contaminant immobilization of the clay-based S/S products. The leachability of As and Pb in high-Ca S/S treated soil samples was reduced by 96.2% and 98.8%, respectively. This is the first study developing a green and cement-free S/S of As- and Pb-contaminated soil using clay minerals as an environmentally compatible binding material. Keywords: Green/sustainable remediation, Low-carbon contaminant immobilization, Calcined clay, Alkali-activated materials, Waste valorization/recycling, Arsenic/lead leachability

Mercury (Hg) is a potentially harmful trace element in the environment and one of the World Health Organization's foremost chemicals of concern. The threat posed by Hg contaminated soils to humans is pervasive, with an estimated 86 Gg of anthropogenic Hg pollution accumulated in surface soils worldwide. This review critically examines both recent advances and remaining knowledge gaps with respect to cycling of mercury in the soil environment, to aid the assessment and management of risks caused by Hg contamination. Included in this review are factors affecting Hg release from soil to the atmosphere, including how rainfall events drive gaseous elemental mercury (GEM) flux from soils of low Hg content, and how ambient conditions such as atmospheric O3 concentration play a significant role. Mercury contaminated soils constitute complex systems where many interdependent factors, including the amount and composition of soil organic matter and clays, oxidized minerals (e.g. Fe oxides), reduced elements (e.g. S2−), as well as soil pH and redox conditions affect Hg forms and transformation. Speciation influences the extent and rate of Hg subsurface transportation, which has often been assumed insignificant. Nano-sized Hg particles as well as soluble Hg complexes play important roles in soil Hg mobility, availability, and methylation. Finally, implications for human health and suggested research directions are put forward, where there is significant potential to improve remedial actions by accounting for Hg speciation and transportation factors. Keywords: Hg(II), Elemental mercury, Soil pollution, Methyl mercury, Remediation

Soil microorganisms are an important indicator of soil fertility and health. However, our state of knowledge about soil microbial activities, community compositions and carbon use patterns under metal contaminations is still poor. This study aimed to evaluate the influences of heavy metals (Cd and Pb) on soil microorganisms by investigating the microbial community composition and carbon use preferences. Metal pollution was approached both singly and jointly with low (25 and 2500 mg kg−1) and high (50 and 5000 mg kg−1) concentrations of Cd and Pb, respectively, in an artificially contaminated soil. In a laboratory incubation experiment, bio-available and potentially bio-available metal concentrations, selected soil properties (pH, electrical conductivity, total organic carbon and total nitrogen), and microbial parameters (microbial activity as basal respiration, microbial biomass carbon (MBC) and microbial functional groups) were determined at two sampling occasions (7 and 49 days). Metal contamination had no effect on the selected soil properties, while it significantly inhibited both microbial activity and MBC formation. Contaminated soils had higher microbial quotient (qCO2), suggesting there was higher energy demand with less microbially immobilized carbon as MBC. Notably, the efficiency of microbial carbon use was repressed as the metal concentration increased, yet no difference was observed between metal types (p > 0.05). Based on the microbial phospholipid fatty acids (PLFA) analysis, total PLFAs decreased significantly under metal stress at the end of incubation. Heavy metals had a greater negative influence on the fungal population than bacteria with respective 5–35 and 8–32% fall in abundances. The contaminant-driven (metal concentrations and types) variation of soil PLFA biomarkers demonstrated that the heavy metals led to the alteration of soil microbial community compositions and their activities, which consequently had an adverse impact on soil microbial carbon immobilization. Keywords: Heavy metals, Soil organic carbon, Microbial carbon decomposition, Microbial activity, Microbial community composition, PLFAs

Shale gas extraction via horizontal drilling and hydraulic fracturing (HF) has enhanced gas production worldwide, which has altered global energy markets and reduced the prices of natural gas and oil. Water management has become the most challenging issue of HF, as it demands vast amounts of freshwater and generates high volumes of complex liquid wastes contaminated by diverse potentially toxic elements at variable rates. This critical review focuses on characterizing HF wastewater and establishing strategies to mitigate environmental impacts. High prioritization was given to the constituents with mean concentrations over 10 times greater than the maximum contamination level (MCL) guidelines for drinking water. A number of potentially harmful organic compounds in HF wastewaters were identified via the risk quotient approach to predict the associated toxicity for freshwater organisms in recipient surface waters. Currently, two options for HF wastewater treatment are preferred, i.e., disposal by deep well injection or on-site re-use as a fracturing fluid. Supplementary treatment will be enforced by increasingly rigorous regulations. Partial treatment and reuse remain the preferred method for managing HF wastewater where feasible. Otherwise, advanced technologies such as membrane separation/distillation, forward osmosis, mechanical vapor compression, electrocoagulation, advanced oxidation, and adsorption-biological treatment will be required to satisfy the sustainable requirements for reuse or surface discharge. Keywords: Unconventional energy, Hydraulic fracturing, Environmental pollution, Metals/metalloids, Wastewater treatment, Sustainable remediation

Phase changes of natural hematite are often practiced to improve heavy metal removal and magnetism for easy recycling. In this work, pinewood biomass (PB) and natural hematite (H) admixtures were pyrolyzed at 300, 450 and 600 °C under N2 environment to prepare HBC nanocomposites (HBC300, HBC450 and HBC600). The X-ray diffraction (XRD) confirmed the reductive transformation of hematite (crystallite size ≈ 47 nm) into magnetite (25 nm) and further to wustite (25 nm) and zerovalent iron (48 nm). The Langmuir isotherms showed that the maximum sorption capacities of HBC300, HBC450, and HBC600 were 173, 138, and 130 mmol kg−1 for Cd2+, and 359, 172, and 197 mmol kg−1 for Cu2+, respectively. The higher pH up to 5 increased sorption of both Cd2+ and Cu2+, whereas the higher ionic strength (0.05–0.4 M) decreased Cd2+ sorption. Sorption of Cd2+ and Cu2+ by HBC300 was accompanied by one order of magnitude greater cation release than HBC450 and HBC600. In a binary system, Cd2+ sorption was depressed by over four times in presence of Cu2+. Overall, ion exchange was more pronounced for HBC300, and Cu2+ was more favorably retained by specific sorption than Cd2+. The greater magnetism of HBC nanoparticles favors separation from aqueous solutions. Keywords: Heavy metals, Pyrolysis, Iron oxide, Reduction, Ion exchange, Water and wastewater treatment

Potentially toxic elements such as heavy metals are ubiquitous in the environment. Risk-based environmental management relies upon identifying pollution sources, pathways, and the exposed population. In a Chinese urban setting, many residents live in high-rise buildings without private gardens. Therefore, the main residential risk of exposure to contaminated soils and dusts may be associated with public open spaces. As children are the most vulnerable receptor, playgrounds represent an important yet often overlooked exposure point. The present study assessed plausible sources of heavy metals at children's playgrounds in a representative metropolitan environment. Soil and equipment dust samples were collected from 71 playgrounds across Beijing, which were analyzed for 11 different heavy metals. Principal component analysis (PCA) was used to identify the latent constructs which control heavy metal variability and reflect potential sources. Cluster analysis (CA) was conducted to group sampled locations, which provided further insights on plausible sources. The main factors extracted from the PCA were then subject to geostatistical analysis. The systematic combination of GIS with multivariate statistical analysis proved valuable for elucidating anthropogenic and natural sources. Elevated Be, V, Cr, Mn, Co, Ni, As in playground soils were found to derive mainly from the natural background (spatial autocorrelation = 2 km), while elevated Cu and Pb was attributed to traffic activities (spatial autocorrelation = 17 km), especially along the routes of Beijing's inner ring-roads, the major roads toward the northwest and northeast, and the international airport. These results suggest that heavy metals in playground equipment dust may derive mainly from atmospheric deposition of air pollution of both natural and anthropogenic origin (spatial autocorrelation = 11–13 km). Among them, Be, V, Mn, Co, Cu, As, Pb were attributed to atmospheric pollution deriving from the north of Beijing, brought by the prevailing northern wind in the winter season; whereas, Cr and Ni may possibly be brought from the southeast by the summer season winds. Knowledge of anthropogenic vs. natural origins of heavy metals in playgrounds is critical in assessing health impact and designing policy instruments for metropolitan areas. Keywords: Heavy metals, GIS, Atmospheric deposition, Air pollution, Soil contamination

This paper evaluates a novel sorbent for the removal of potentially toxic elements, inherent cations, and hetero-chloride from hydraulic fracturing wastewater (FWW). A series of iron-biochar (Fe-BC) composites with different Fe/BC impregnation mass ratios (0.5:1, 1:1, and 2:1) were prepared by mixing forestry wood waste-derived BC powder with an aqueous FeCl3 solution and subsequently pyrolyzing them at 1000 °C in a N2-purged tubular furnace. The porosity, surface morphology, crystalline structure, and interfacial chemical behavior of the Fe-BC composites were characterized, revealing that Fe chelated with CO bonds as COFe moieties on the BC surface, which were subsequently reduced to a CC bond and nanoscale zerovalent Fe (nZVI) during pyrolysis. The performance of the Fe-BC composites was evaluated for simultaneous removal of potentially toxic elements (Cu(II), Cr(VI), Zn(II), and As(V)), inherent cations (K, Na, Ca, Mg, Ba, and Sr), hetero-chloride (1,1,2-trichlorethane (1,1,2-TCA)), and total organic carbon (TOC) from high-salinity (233 g L−1 total dissolved solids (TDS)) model FWW. By elucidating the removal mechanisms of different contaminants, we demonstrated that Fe-BC (1:1) had an optimal reducing/charge-transfer reactivity owing to the homogenous distribution of nZVI with the highest Fe0/Fe2+ ratio. A lower Fe content in Fe-BC (0.5:1) resulted in a rapid exhaustion of Fe0, while a higher Fe content in Fe-BC (2:1) caused severe aggregation and oxidization of Fe0, contributing to its complexation/(co-)precipitation with Fe2+/Fe3+. All of the synthesized Fe-BC composites exhibited a high removal capacity for inherent cations (3.2–7.2 g g−1) in FWW through bridging with the CO bonds and cation-π interactions. Overall, this study illustrated the potential efficacy and mechanistic roles of Fe-BC composites for (pre-)treatment of high-salinity and complex FWW. Keywords: Engineered biochar, Mineral-carbon composites, Metals/metalloids, Fracturing wastewater treatment, Sustainable remediation

Globally, contamination of groundwater with toxic arsenic (As) is an environmental and public health issue given to its carcinogenic properties, thereby threatening millions of people relying on drinking As-contaminated well water. Here, we explored the efficiency of various biosorbents (egg shell, java plum seed, water chestnut shell, corn cob, tea waste and pomegranate peel) for arsenate (As(V)) and arsenite (As(III)) removal from As-contaminated water. Significantly, egg shell and java plum seed displayed the greatest As(III) elimination (78–87%) at 7 pH followed by water chestnut shell (75%), corn cob (67%), tea waste (74%) and pomegranate peel (65%). In contrast, 71% and 67% of As(V) was removed at pH 4.1 and 5.3 by egg shell and java plum seed, respectively. The maximum As(V) and As(III) sorption by all the biosorbents was obtained, notably for egg shell and java plum seed, after 2 h contact time. Langmuir isotherm and pseudo-second order models best fitted the sorption data for both forms of As. The –OH, –COOH, –NH2 and sulfur-bearing surface functional groups were possibly involved for As(III) and As(V) removal by biosorbents. The scanning electron microscopy combined with the energy dispersive X-ray spectroscopy (SEM-EDX) analysis showed that the heterogeneous surface of biosorbents, possessing rough and irregular areas, could have led to As sorption. Both As(V) and As(III) were successfully desorbed (up to 97%) from the biosorbents in four sorption/desorption (regeneration) cycles. This pilot-scale study highlights that egg shell and java plum seed have the greatest ability to remove both As species from As-contaminated drinking water. Importantly, these findings provide insights to develop an inexpensive, effective and sustainable filtration technology for the treatment of As in drinking water, particularly in developing countries like Pakistan. Keywords: Arsenic contamination, Filtration materials, Drinking water, Health, Groundwater

Microplastics are well known for vector transport of hydrophobic organic contaminants, and there are growing concerns regarding their potential adverse effects on ecosystems and human health. However, recent studies focussing on hydrophilic compounds, such as pharmaceuticals and personal care products (PPCPs), have shown that the compounds ability to be adsorbed onto plastic surfaces. The extensive use of PPCPs has led to their ubiquitous presence in the environment resulting in their cooccurrence with microplastics. The partitioning between plastics and PPCPs and their fate through vector transport are determined by various physicochemical characteristics and environmental conditions of specific matrices. Although the sorption capacities of microplastics for different PPCP compounds have been investigated extensively, these findings have not yet been synthesized and analyzed critically. The specific objectives of this review were to synthesize and critically assess the various factors that affect the adsorption of hydrophilic compounds such as PPCPs on microplastic surfaces and their fate and transport in the environment. The review also focuses on environmental factors such as pH, salinity, and dissolved organics, and properties of polymers and PPCP compounds, and the relationships with sorption dynamics and mechanisms. Furthermore, the ecotoxicological effects of PPCP-sorbed microplastics on biota and human health are also discussed.

The aim of this work was to study the redox-induced mobilization of Ag, Sb, Sn, and Tl in the dissolved, colloidal, and sediment phase of a mining soil treated and untreated with biochar as affected by the redox potential (EH) -dependent changes of soil pH, dissolved organic carbon, Fe, Mn and S. The experiment was conducted stepwise at two EH cycles (+200 mV → -30 mV → +333 mV → 0 mV) using biogeochemical microcosm. Silver was abundant in the colloidal fraction in both cycles, indicating that Ag might be associated with colloids under different redox conditions. Antimony, Sn and Tl were abundant in the colloidal fraction in the first cycle and in the dissolved fraction in the second cycle, which indicates that they are retained by colloids under oxic acidic conditions and released under reducing alkaline conditions. Release of dissolved Sb, Sn, and Tl was governed positively by pH, Fe, S, and dissolved aromatic compounds. Biochar mitigated Ag release, but promoted Sb, Sn, and Tl mobilization, which might be due to the wider range of EH (-12 to +333) and pH (4.9–8.1) in the biochar treated soil than the un-treated soil (EH = -30 to +218; pH = 5.9–8.6). Also, the biochar surface functional groups may act as electron donors for the Sb, Sn, and Tl reduction reactions, and thus biochar may play an important role in reducing Tl3+ to Tl+, Sb5+ to Sb3+, and Sn4+ to Sn2+, which increase their solubility under reducing conditions as compared to oxic conditions. Thallium and Sb exhibit higher potential mobility in the solid phase than Sn and Ag. Biochar increased the potential mobility of Sb, Sn, and Tl under oxic acidic conditions. The results improve our understanding of the redox-driven mobilization of these contaminants in soils.

In this study, a magnesium oxide (MgO) coated corncob biochar (MCB) was synthesized by pyrolyzing MgCl2 pretreated corncob, for a better performance in lead immobilization in a contaminated soil compared with corncob biochar (CB). The properties and microstructures of CB and MCB were investigated. It was observed that MgO particles ranging from 1 to 2 μm were well coated on MCB, and the MgO content in MCB was calculated at 29.90% in w/w. The surface area of the biochar was significantly enhanced from 0.07 to 26.56 m2/g after the MgO coating. The MgO coating also significantly facilitated the lead removal percentage from 23% to 74% in aqueous solution by biochar. CB failed to immobilize lead in a soil washing residue and could not reduce its environmental risks in a laboratory incubation study. In contrast, MCB was applied to the soil and resulted in a significant reduction in TCLP leached lead from 10.63 to 5.24 mg/L (reduced by 50.71%). The comparison between MCB and other amendments suggests that the biochar component of MCB adsorbed lead onto its surface through cation-π interaction and increased surface adsorption due to higher surface area, and then the MgO coated on MCB's surface further enhanced the adsorption through precipitation. The synergistic roles of biochar-mineral composites make them a promising candidate for soil remediation. Keywords: Engineered biochar, Magnesium oxide (MgO), Biochar-mineral composite, Lead immobilization, In situ stabilization, Soil remediation

Biochar can reduce the mobility and availability of potentially toxic elements (PTEs) in soils and improve soil properties. However, immobilization efficiencies of biochar can be varied according to environmental conditions, such as pH and redox potential (Eh), especially for soils under flood-dry cycles. In the current study, biochar produced at 300 and 550 °C (referred as BC300 and BC550, respectively) and its feedstock (pine sawdust biomass, BM) were used to amend a lead (Pb)-contaminated soil under pre-defined redox windows (from −300 to +250 mV). Key features of the soil-solution were evaluated in detail, including pH, dissolved organic carbon, sulphate, and dissolved Al, Fe, and Mn. The BC550 reduced the amount of dissolved Pb and showed a different pattern of Eh-pH in the soil slurry compared with BM and BC300. This might be attributed to its higher alkalinity and surface area. The highest amount of dissolved Pb was found at slightly anoxic conditions (−100 to 0 mV) in CS (control soil), S&BM (soil amended with BM), and S&BC300 (soil amended with BC300), which could be associated with the dissolution of Fe/Mn oxides. Moreover, the fitting results of Pb X-ray absorption fine structure (XAFS) indicated that the proportion of Pb(CH3COO)2 was decreasing when changing from anoxic to oxic condition in S&BC300, while the Pb speciation pattern in soil was stable in S&BC550. These results suggested that BC550 is more suitable amendment for Pb immobilization than BM and BC300 in this study. In addition, biochar produced at higher temperatures can be more stable so it can be suitable for remediation of Pb-contaminated soils which are frequently flooded. Keywords: Immobilization/stabilization, Lead dissolution/mobility, Paddy soil, XANES spectroscopy, Black carbon

Human exposure to lead (Pb) is a growing global public health concern. Elevated blood lead is thought to cause the mental retardation of >0.6 million children globally each year, and has recently been attributed to ~18% of all-cause mortality in the US. Due to the severe health risk, the international community, led by the United Nations Environment Programme (UNEP) and the World Health Organization (WHO), is actively supporting the global phase-out of lead-based paint by 2020. However, there are many significant hurdles on the way to achieving this goal. In light of the importance of the lead-based paint issue, and the urgency of achieving the 2020 phase-out goal, this review provides critical insights from the existing scientific literature on lead-based paint, and offers a comprehensive perspective on the overall issue. The global production and international trade of lead-based paints across Asia, Africa, Latin America, and Europe are critically discussed – revealing that lead-based paints are still widely used in many low and middle-income developing countries, and that the production and trade of lead-based paint is still wide-spread globally. In India, as well as many south-east Asian, African, Latin American and European countries, lead concentrations in paints often exceed 10,000 mg/kg. This will certainly pose a serious global threat to public health from surfaces painted with these products for many decades to come. The sources and pathways of exposure are further described to shed light on the associated health risk and socioeconomic costs. Finally, the review offers an overview of the potential intervention and abatement strategies for lead-based paints. In particular, it was found that there is a general lack of consensus on the definition of lead based paint; and, strengthening regulatory oversight, public awareness, and industry acceptance are vital in combating the global issue of lead based paint. Keywords: Lead-based paint, Lead exposure, Blood lead level, Soil contamination

Shrimp processing and consumption generate large amounts of waste shrimp shell (WSS) rich in chitin and protein. Herein, we successfully synthesized WSS-based hydrochar (WSH) adsorbent through deproteinization and deacetylation followed by hydrothermal carbonization (HTC) and acid washing. For comparison, another hydrochar (CCH) adsorbent was synthesized from HTC of commercial chitosan under identical conditions. Specifically, WSH contained rich nitrogen-containing functional groups with a long aliphatic chains structure. Acid etching of calcium carbonate in WSS led to a higher specific surface area of WSH (12.65 m2/g) which was nearly 6 times higher than that of CCH (2.13 m2/g). The lower deacetylation degree of WSH was responsible for higher amide I and amino groups retained therein. Under an optimal initial solution pH of 4.0, WSH could rapidly achieve a superb adsorption capacity of 755.08 mg/g for methyl orange molecule. Moreover, the adsorption process followed a pseudo-second-order kinetics model and was well described by a monolayer adsorption pattern based on the Langmuir isotherm model with correlation coefficients higher than 0.9989. Prominent adsorption performance of WSH for methyl orange was mainly attributed to electrostatic interactions, while steric hindrance effect had a detrimental impact on the adsorption capacity of CCH. Superb adsorption capacity and excellent regeneration performance suggest WSH could be a promising and affordable adsorbent candidate for anionic dye removal. Keywords: N-containing functional groups, Biochar, Chitosan, Adsorption isotherm, Electrostatic interaction, Steric hindrance

Soil contamination by potentially toxic elements (PTEs) has led to adverse environmental impacts. In this review, we discussed remediation of PTEs contaminated soils through immobilization techniques using different soil amendments with respect to type of element, soil, and amendment, immobilization efficiency, underlying mechanisms, and field applicability. Soil amendments such as manure, compost, biochar, clay minerals, phosphate compounds, coal fly ash, and liming materials are widely used as immobilizing agents for PTEs. Among these soil amendments, biochar has attracted increased interest over the past few years because of its promising surface properties. Integrated application of appropriate amendments is also recommended to maximize their use efficiency. These amendments can reduce PTE bioavailability in soils through diverse mechanisms such as precipitation, complexation, redox reactions, ion exchange, and electrostatic interaction. However, soil properties such as soil pH, and clay, sesquioxides and organic matter content, and processes, such as sorption/desorption and redox processes, are the key factors governing the amendments' efficacy for PTEs immobilization in soils. Selecting proper immobilizing agents can yield cost-effective remediation techniques and fulfill green and sustainable remediation principles. Furthermore, long-term stability of immobilized PTE compounds and the environmental impacts and cost effectiveness of the amendments should be considered before application. Keywords: Soil quality, Soil amendment, Bioavailability, Green/sustainable remediation, Toxic metal(loid)s

Mercury contamination in soil, water and air is associated with potential toxicity to humans and ecosystems. Industrial activities such as coal combustion have led to increased mercury (Hg) concentrations in different environmental media. This review critically evaluates recent developments in technological approaches for the remediation of Hg contaminated soil, water and air, with a focus on emerging materials and innovative technologies. Extensive research on various nanomaterials, such as carbon nanotubes (CNTs), nanosheets and magnetic nanocomposites, for mercury removal are investigated. This paper also examines other emerging materials and their characteristics, including graphene, biochar, metal organic frameworks (MOFs), covalent organic frameworks (COFs), layered double hydroxides (LDHs) as well as other materials such as clay minerals and manganese oxides. Based on approaches including adsorption/desorption, oxidation/reduction and stabilization/containment, the performances of innovative technologies with the aid of these materials were examined. In addition, technologies involving organisms, such as phytoremediation, algae-based mercury removal, microbial reduction and constructed wetlands, were also reviewed, and the role of organisms, especially microorganisms, in these techniques are illustrated. Keywords: Hg(II), Elemental mercury, Methylmercury, Remediation techniques, Novel materials

On 11 May 2019, the Mauna Loa, Hawaii, Earth System Research Laboratory reported the highest CO2 concentration in human meteorological history. Continuing CO2 rise will devastate ecosystems, and ice dependent species like polar bears ultimately will disappear. Commercial aviation is presently a relatively small CO2 contributor, but this CO2 intensive mode of transportation is projected to increase greatly. Scientists and conservationists are often among the most frequent of flyers, despite their recognition that emissions must be reduced. Here we illustrate the carbon footprint of air travel in terms of its impact on the sea ice habitat necessary for polar bear persistence, and suggest our colleagues reduce their air travel where-ever possible. Each metric ton of CO2 emitted melts ~3 m2 of arctic summer sea ice, and current air travel melts over 5000 m2 each year. Each scientist making the short flight from Copenhagen to Oslo to join an IUCN polar bear meeting will melt ~1 m2 of Arctic summer sea-ice. Annually hundreds of scientists and conservationists make frequent flights of much greater distances for AMAP, CAFF, IUCN, and other conservation related meetings. Much of this travel could be avoided with better planning and employing internet linkages for remote participation. When air travel, such as for necessary fieldwork, cannot be easily substituted by Web linkage, we all should search for routes and carriers allowing the lowest CO2 emissions. We encourage all of our colleagues to join ‘No Fly Climate Sci’ to show their commitment to CO2 reduction and learn more about doing so. As scientists, if we are serious about preserving polar bears and their Arctic sea ice habitat, we need to walk the talk and show an example for the rest of society by significantly reducing our air travel. Keywords: Climate, Carbon dioxide, Mercury, Pollution, Extinction, Legislation

Elevated level of arsenic (As) in marine sediment via deposition and accumulation presents long-term ecological risks. This study proposed a sustainable stabilization/solidification (S/S) of As-contaminated sediment via novel valorization of red mud waste, blast furnace slag and calcined clay mineral, which were selected to mitigate the increased leaching of As under alkaline environment of S/S treatment. Quantitative X-ray diffraction and thermogravimetric analyses illustrated that stable Ca-As complexes (e.g., Ca5(AsO4)3OH) could be formed at the expense of Ca(OH)2 consumption, which inevitably hindered the hydration process and S/S efficiency. The 29Si nuclear magnetic resonance analysis revealed that incorporation of metakaolin for As immobilization resulted in a low degree of hydration and polymerization, whereas addition of red mud promoted Fe-As complexation and demonstrated excellent compatibility with As. Transmission electron microscopy and elemental mapping further confirmed the precipitation of crystalline Ca-As and amorphous Fe-As compounds. Therefore, red mud-incorporated S/S binder achieved the highest efficiency of As immobilization (99.9%), which proved to be applicable for both in-situ and ex-situ S/S of As-contaminated sediment. These results advance our mechanistic understanding for the design of green and sustainable remediation approach for effective As immobilization. Keywords: Green/sustainable remediation, Potentially toxic element, Arsenic leachability, Waste valorization/recycling, Hydration and polymerization, Precipitation chemistry

Particulate plastics in the terrestrial and aquatic environments are small plastic fragments or beads (i.e., 5 mm down to the nanometre range). They have been frequently referred to as ‘micro-plastics’ or ‘nano-plastics’. Research has identified particulate plastics as a vector for toxic trace elements in the environment. The adsorption of toxic trace elements by particulate plastics may be facilitated by their high surface area and functionalized surfaces (e.g., through the attachment of natural organic matter). Other factors, such as environmental conditions (e.g., pH and water salinity), surface charge, and trace element oxidation status, also influence the adsorption of trace elements onto particulate plastics. Because of their small size and persistence, particulate plastics and the associated toxic trace elements are readily ingested and accumulated in many terrestrial and aquatic organisms. Thus, these plastics can have severe environmental consequences, such as the development of metal toxicity, within aquatic and terrestrial organisms. Humans could also become exposed to particulate plastics through food chain contamination and airborne ingestion. This review provides an overview of the sources of particulate plastics in the environment. To this end, we describe particulate plastics made of synthetic polymers, their origin, and characteristics with emphasis on how particulate plastics and associated toxic trace elements contaminate terrestrial and aquatic ecosystems. Future research needs and strategies are discussed to help reduce the environmental risks of particulate plastics as a potent vector for the transportation of toxic trace elements. Keywords: Microplastics, Microbeads, Heavy metals, Toxicity-vector, Ecotoxicity

The accumulation of potentially toxic elements (PTEs) in aquatic ecosystems has become a global concern, as PTEs may exert a wide range of toxicological impacts on aquatic organisms. Submerged plants and the microorganisms attached to their surfaces, however, have displayed great potential as a means of coping with such pollution. Therefore, it is crucial to understand the transport pathways of PTEs across sediment and organisms as well as their accumulation mechanisms in the presence of submerged plants and their biofilms. The majority of previous studies have demonstrated that submerged plants and their biofilms are indicators of PTE pollution in the aquatic environment, yet relatively little is known about PTE accumulation in epiphytic biofilms. In this review, we describe the transport pathways of PTEs in the aquatic environment in order to offer remarkable insights into bioaccumulation mechanisms in submerged plants and their biofilms. Based on the literature cited in this review, the roles of epiphytic biofilms in bioaccumulation and as an indicator of ecosystem health are discussed. Keywords: Potentially toxic element, Submerged plant, Biofilm, Bioaccumulation, Indicator species

The concept of planetary health acknowledges the links between ecosystems, biodiversity and human health and well-being. Soil, the critical component of the interconnected ecosystem, is the most biodiverse habitat on Earth, and soil microbiomes play a major role in human health and well-being through ecosystem services such as nutrient cycling, pollutant remediation and synthesis of bioactive compounds such as antimicrobials. Soil is also a natural source of antimicrobial resistance, which is often termed intrinsic resistance. However, increasing use and misuse of antimicrobials in humans and animals in recent decades has increased both the diversity and prevalence of antimicrobial resistance in soils, particularly in areas affected by human and animal wastes, such as organic manures and reclaimed wastewater, and also by air transmission. Antimicrobials and antimicrobial resistance are two sides of the sword, while antimicrobials are essential in health care; globally, antimicrobial resistance is jeopardizing the effectiveness of antimicrobial drugs, thus threatening human health. Soil is a crucial pathway through which humans are exposed to antimicrobial resistance determinants, including those harbored by human pathogens. In this review, we use the nexus of antimicrobials and antimicrobial resistance as a focus to discuss the role of soil in planetary health and illustrate the impacts of soil microbiomes on human health and well-being. This review examines the sources and dynamics of antimicrobial resistance in soils and uses the perspective of planetary health to track the movement of antimicrobial-resistance genes between environmental compartments, including soil, water, food and air. Keywords: Planetary health, Human health, Soil microbiome, Antimicrobials, Resistome

The transformation of trace metals (TMs) in natural environmental systems has created significant concerns in recent decades. Ultramafic environments lead to potential risks to the agricultural products and, subsequently, to human health. This unique review presents geochemistry of ultramafic soils, TM fractionation (i.e. sequential and single extraction techniques), TM uptake and accumulation mechanisms of ultramafic flora, and ultramafic-associated health risks to human and agricultural crops. Ultramafic soils contain high levels of TMs (i.e. Cr, Ni, Mn, and Co) and have a low Ca:Mg ratio together with deficiencies in essential macronutrients required for the growth of crops. Even though a higher portion of TMs bind with the residual fraction of ultramafic soils, environmental changes (i.e. natural or anthropogenic) may increase the levels of TMs in the bioavailable or extractable fractions of ultramafic soils. Extremophile plants that have evolved to thrive in ultramafic soils present clear examples of evolutionary adaptations to TM resistance. The release of TMs into water sources and accumulation in food crops in and around ultramafic localities increases health risks for humans. Therefore, more focused investigations need to be implemented to understand the mechanisms related to the mobility and bioavailability of TMs in different ultramafic environments. Research gaps and directions for future studies are also discussed in this review. Lastly, we consider the importance of characterizing terrestrial ultramafic soil and its effect on crop plants in the context of multi-decadal plans by NASA and other space agencies to establish human colonies on Mars. Keywords: Soil contamination, Geochemistry, Trace elements, Bioaccumulation, Translocation, Extremophytes