6 results on '"spinel oxide"'
Search Results
2. Cationic regulation of specificity and activity of defective MCo 2 O 4 nanozyme (M=Fe, Co, Ni, Cu) for colorimetric detection of caffeic acid.
- Author
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Feng M, Zhang X, and Huang Y
- Subjects
- Edetic Acid, Cations, Oxidoreductases, Colorimetry, Oxygen, Oxides, Magnesium Oxide, Caffeic Acids, Cobalt, Aluminum Oxide
- Abstract
Spinel oxide has great promise in constructing highly active nanozymes due to its tunable crystal structure. However, it still faces the problems of poor specificity and insufficient enzyme activity, which limits its application in the field of analysis. Herein, a series of transition metal spinel oxides were synthesized by cation regulation strategy, and their enzymatic activity and catalytic mechanism were analyzed. Interestingly, FeCo
2 O4 , Co3 O4 and NiCo2 O4 had oxidase-like activity and peroxidase-like activity, while CuCo2 O4 had specific and high oxidase-like activity. Their oxidase-like activities follow the order of FeCo2 O4 < Co3 O4 < NiCo2 O4 < CuCo2 O4 , which is consistent with their cation radius. The smaller the cation radius of tetrahedral site, the more beneficial it is to increase the oxidase-like activity. The high oxidase-like activity of CuCo2 O4 may be attributed to the production of1 O2 , •O2 - and •OH. EPR results showed the presence of abundant oxygen vacancies in CuCo2 O4 . Upon the introduction of EDTA, TMB color reaction fades because of oxygen vacancies elimination by EDTA, indicating that oxygen vacancies played an important role in the reaction. Based on the inhibition effect of caffeic acid on the high oxidase-like activity of CuCo2 O4 , a simple and sensitive caffeic acid colorimetric sensing platform was developed. The linear range for the detection of caffeic acid is 0.02-15 μM, with a detection limit as low as 13 nM. The constructed sensor enables the detection of caffeic acid in caffeic acid tablets and actual water samples, providing a new strategy for the detection of caffeic acid and drug quality control., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)- Published
- 2024
- Full Text
- View/download PDF
3. Spinel Mixed Oxides for Chemical-Loop Reforming: From Solid State to Potential Application
- Author
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Fabrizio Cavani, Olena Vozniuk, Stefania Albonetti, Nathalie Tanchoux, Francesco Di Renzo, Jean-Marc M. Millet, Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC), Dipartimento di Chimica Industriale 'Toso Montanari' Universita di Bologna (CHIMIND), Alma Mater Studiorum Università di Bologna [Bologna] (UNIBO), Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), SINCHEM Joint Doctorate Programme-Erasmus Mundus Action (framework agreement No. 2013-0037, specific grant agreement no. 2015-1600/001-001-EMJD), Stefania Albonetti, Siglinda Perathoner, Elsje Alessandra Quadrelli, Vozniuk O., Tanchoux N., Millet J.-M., Albonetti S., Di Renzo F., and Cavani F.
- Subjects
Alcohol reforming ,Spinel oxides ,02 engineering and technology ,Raw material ,7. Clean energy ,Hydrogen economy ,0502 economics and business ,Ferrites ,Oxygen carrier ,Water splitting ,050207 economics ,Process engineering ,Oxygen carriers ,Hydrogen production ,business.industry ,05 social sciences ,Fossil fuel ,Global warming ,Ferrite ,[CHIM.MATE]Chemical Sciences/Material chemistry ,[CHIM.CATA]Chemical Sciences/Catalysis ,Chemical looping ,021001 nanoscience & nanotechnology ,Renewable energy ,Spinel oxide ,13. Climate action ,Greenhouse gas ,Environmental science ,0210 nano-technology ,business ,Chemical looping combustion ,Hydrogen - Abstract
International audience; Interest in hydrogen as a possible energy vector is powered by the depletion of fossil fuel feedstocks as well as concerns over global warming, which brings new environmental legislations on the emission of greenhouse gases into the atmosphere. At this point, the future perspective of a hydrogen economy has triggered many researchers to develop and optimize a series of new technologies which differ from conventional industrial processes (like SMR, ATR, POX, and H2O-electrolysis) in their orientation toward the minimization of emission of greenhouse gases (on-site CO2 capture), utilization of renewable feedstock (bio-alcohols, bio-gases, wood, and algae), or renewable energy sources (wind, sunlight, or tides). This chapter gathers information on the most relevant technologies for hydrogen production, including discussions on existing conventional reformingprocesses, as well as developments in advanced and more environmentally benign methods, like chemical-looping.
- Published
- 2019
4. Microstructural and optical properties of spinel oxide MxCo2−xMnO4 (M=Ni, Zn or Cu; 0<x<1) thin films prepared by inorganic polycondensation and dip-coating methods
- Author
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Thi Ly Le, Sophie Guillemet-Fritsch, Pascal Dufour, Christophe Tenailleau, Centre National de la Recherche Scientifique - CNRS (FRANCE), Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE), Université Toulouse III - Paul Sabatier - UT3 (FRANCE), Institut National Polytechnique de Toulouse - INPT (FRANCE), Centre interuniversitaire de recherche et d'ingenierie des matériaux (CIRIMAT), Centre National de la Recherche Scientifique (CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National Polytechnique (Toulouse) (Toulouse INP), and Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC)
- Subjects
Ceramics ,Materials science ,Scanning electron microscope ,Matériaux ,Thin films ,Oxide ,Analytical chemistry ,chemistry.chemical_element ,Mineralogy ,02 engineering and technology ,engineering.material ,01 natural sciences ,Dip-coating ,[SPI.MAT]Engineering Sciences [physics]/Materials ,Absorbance ,chemistry.chemical_compound ,0103 physical sciences ,Materials Chemistry ,Thin film ,010302 applied physics ,Optical properties ,Spinel ,Metals and Alloys ,Surfaces and Interfaces ,021001 nanoscience & nanotechnology ,Microstructure ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry ,Spinel oxide ,engineering ,Colloidal dispersion ,0210 nano-technology ,Cobalt - Abstract
International audience; Spinel oxide nanoparticles of MxCo2 − xMnO4 (M = Ni, Zn, Cu; 0 < x < 1) were prepared at 120 °C by the inorganic polycondensation method. Phase composition and microstructure of each sample powder thus obtained were characterized by X-ray diffraction, X-ray fluorescence and scanning electron microscopy. Nanoparticles are well crystallized and uniformly distributed in both shape and size. Colloidal dispersions were stabilized in a low cost and environmentally friendly solvent solution. Spinel oxide thin films were then deposited on glass substrates by using the dip-coating technique. Their optical properties were measured in the 300–1100 nm wavelength range. Thin films show extremely good absorbance in the ultra-violet and blue regions. The highest absorbance observed in the red region was for x = 0.15 in zinc. A smaller direct band gap was determined when a low amount of doping M element was introduced in the cobalt and manganese spinel oxide material.
- Published
- 2016
5. Preparation of iron cobaltite thin films by RF magnetron sputtering
- Author
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T.M.A. Bui, Ph. Tailhades, H. Le Trong, Antoine Barnabé, Lionel Presmanes, Corine Bonningue, Isabelle Pasquet, Centre National de la Recherche Scientifique - CNRS (FRANCE), Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE), Université Toulouse III - Paul Sabatier - UT3 (FRANCE), Ho Chi Minh City University of Science - HCMC (VIETNAM), University of Transport and Communications - UTC (VIETNAM), Vietnam National University - VNU (VIETNAM), Institut National Polytechnique de Toulouse - INPT (FRANCE), Centre interuniversitaire de recherche et d'ingenierie des matériaux (CIRIMAT), Centre National de la Recherche Scientifique (CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC), and Ho Chi Minh City University of Science (HCMUS)
- Subjects
Materials science ,Matériaux ,Oxide ,Analytical chemistry ,chemistry.chemical_element ,Mineralogy ,In-situ reduction ,02 engineering and technology ,engineering.material ,010402 general chemistry ,01 natural sciences ,[SPI.MAT]Engineering Sciences [physics]/Materials ,chemistry.chemical_compound ,Sputtering ,Exchange field ,Materials Chemistry ,Thin film ,Spinel ,Metals and Alloys ,Surfaces and Interfaces ,[CHIM.MATE]Chemical Sciences/Material chemistry ,Sputter deposition ,021001 nanoscience & nanotechnology ,Microstructure ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Cobaltite ,Magnetic coupling ,chemistry ,Spinel oxide ,Monoxide ,engineering ,sense organs ,0210 nano-technology ,Cobalt - Abstract
International audience; Iron cobaltite thin films with spinel structure have been elaborated by radio-frequency (RF) magnetronsputtering from a Co1.75Fe1.25O4 target. Influence of argon pressure on structure, microstructure and physicalproperties of films has been examined. Iron–cobalt oxide thin films essentially consist of one spinel phasewhen deposited at low pressure (0.5 and 1.0 Pa). At high pressure (2.0 Pa), the global stoichiometry of the filmis changed which results in the precipitation of a mixed monoxide of cobalt and iron beside the spinel phase.This in-situ reduction due to an oxygen loss occurring mainly at high deposition pressure has been revealed byX-ray diffraction and Raman spectroscopy. Microstructural evolution of thin film with argon pressure has beenshown by microscopic observations (AFM and SEM). The evolution of magnetic and electrical properties, versusargon pressure, has been also studied by SQUID and 4 point probe measurements.
- Published
- 2015
6. Microstructure, porosity and roughness of RF sputtered oxide thin films: Characterization and modelization
- Author
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Antoine Barnabé, Lionel Presmanes, Fahd Oudrhiri-Hassani, Philippe Tailhades, Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE), Université Toulouse III - Paul Sabatier - UT3 (FRANCE), and Centre National de la Recherche Scientifique - CNRS (FRANCE)
- Subjects
Materials science ,Surface enhancement factor ,Matériaux ,Thin films ,Oxide ,General Physics and Astronomy ,Mineralogy ,engineering.material ,chemistry.chemical_compound ,Sputtering ,Ellipsometry ,Thin film ,Composite material ,Cobalt oxide ,Microstructure ,Spinel ,Surfaces and Interfaces ,General Chemistry ,Condensed Matter Physics ,Surfaces, Coatings and Films ,Characterization (materials science) ,chemistry ,Spinel oxide ,engineering - Abstract
Spinel CoMnFeO4 thin films are stable materials useful to study the influence of radio-frequency (RF) sputtering experimental conditions on the microstructure of oxide films. It has been demonstrated by various techniques such as electronic and atomic force microscopy (AFM), gas adsorption techniques and ellipsometry, that films prepared with 0.5 Pa sputtering argon pressure and 5 cm target–substrate distance are very dense. On the other hand, the samples obtained under higher pressure and/or longer distances are microporous with a mean pore size generally lower than 2 nm. The specific surface areas of such films reach about 75 m2/g. According to the simple model proposed, the films are made of three layers. From the bottom to the top of the film, the first one at the interface with the substrate is 100% dense. The second layer is made of cylindrical rods set up according to a compact plane. Its porosity is due to the lattice interstices. Hemispheric domes covering each rod make up the third layer, which displays a degree of roughness related to the shape and the hexagonal arrangement of the domes. The surface enhancement factor (SEF), the porosity and roughness, calculated from the model, are in corroboration with the experimental values. The porosity factor is however slightly underestimated by the model for very porous samples.
- Published
- 2008
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