1. Iron and silicon modified biochar for enhancing cadmium removal from water: Unveiling the crucial role of iron-induced silicon dissolution.
- Author
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Wu H, Liu L, Zhuo Y, Ellam RM, Yan K, Liu J, and Tang J
- Subjects
- Adsorption, Hydrogen-Ion Concentration, Cadmium chemistry, Silicon chemistry, Charcoal chemistry, Iron chemistry, Water Pollutants, Chemical isolation & purification, Water Purification methods, Solubility
- Abstract
The interaction mechanisms of silicon (Si) and active ingredient iron (Fe) on cadmium (Cd) removal are still unknown. Herein, the Fe/Si modified biochar (Fe/Si-BC) was synthesized to enhance Cd removal by pre-immersion of Fe and ball milling loading of Si. Detailed characterizations indicated that Fe and Si were successfully introduced into Fe/Si-BC, resulting in the formation of a new metallic silicate (Ca
2.87 Fe0.13 (SiO3 )2 ). The maximum Cd adsorption capacity of Fe/Si-BC (31.66 mg g-1 ) was 3.6 times and 2.5 times higher than that of Fe-BC (8.89 mg g-1 ) and Si-BC (11.03 mg g-1 ), respectively, deriving from an enhancement of Si dissolution induced by Fe introduction. The dissolved Si could capture and combine Cd to form CdSiO3 precipitation, which was strongly supported by the random forest regression and correlation between dissolved Si content and Cd adsorption capacity. This study advances the mechanistic insights into synergistic functions of Si and Fe in Cd removal., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)- Published
- 2024
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