1. In situ synthesis of Fe 3 O 4 @ cyanoethyl cellulose composite as antimicrobial and semiconducting film.
- Author
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Dacrory S, Moussa M, Turky G, and Kamel S
- Subjects
- Anti-Bacterial Agents chemical synthesis, Anti-Bacterial Agents chemistry, Antifungal Agents chemical synthesis, Antifungal Agents chemistry, Aspergillus niger drug effects, Candida albicans drug effects, Cellulose chemical synthesis, Density Functional Theory, Electric Conductivity, Escherichia coli drug effects, Ferrosoferric Oxide chemistry, Magnetic Phenomena, Models, Chemical, Porosity, Staphylococcus aureus drug effects, Anti-Bacterial Agents pharmacology, Antifungal Agents pharmacology, Cellulose analogs & derivatives, Cellulose pharmacology, Ferrosoferric Oxide pharmacology
- Abstract
Cyanoethyl cellulose (CEC)/ magnetite (Fe
3 O4 ) flexible composite film with enhanced dielectric and magnetic properties was successfully prepared. CEC has been synthesized from micro crystalline cellulose (MCC). The effects of magnetite mass fraction on the morphology, microstructure, thermal stability, and antimicrobial activity of the as-prepared composite films were investigated. The Vibrating sample magnetometer (VSM) and broadband dielectric spectrometer was also employed to study the magnetic and dielectric properties, respectively. In addition to study the computational calculation of MCC, and CEC by DFT/ B3LYP/6-31G (d) basis sets. The results showed that, the sample that is magnetite free has a diamagnetic response to the applied magnetic field, however the other samples that is loaded with magnetite show super-paramagnetic behavior indicating that the particles' sizes of the magnetite mostly below 20 nm. Also, antimicrobial activities of composite films against (G + ve), (G-ve), were investigated., Competing Interests: Declaration of Competing Interest The authors declare that they have no conflict to interests., (Copyright © 2020 Elsevier Ltd. All rights reserved.)- Published
- 2020
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