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Sunflower oil (SFO) and Flaxseed oil (FSO) were microencapsulated using simple and complex coacervation techniques with Opuntia (Cactaceae) mucilage (Mu) and with a combination of Mu with chitosan (Chit). The encapsulation efficiency (EE) of SFO and FSO in emulsions using Mu/Chit shells was 96.7% and 97.4%, respectively. Morphological studies indicated successful entrapment of oils in core shells with particle sizes ranging from 1396 ± 42.4 to 399.8 ± 42.3 nm. The thermogravimetric analyses demonstrated enhanced core protection with thermal stability noted for microcapsules regardless of encapsulation method. The stability of the microcapsules, during in vitro digestion was studied. The obtained results revealed that the microcapsules are intact in oral conditions and have a slow release of oil over stomach digestion and rapid release in the small intestine. The results showed that Mu and Mu/Chit coacervates can be used as effective carrier systems to encapsulate sensitive ingredients and functional oils., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The traditional starch-based intelligent freshness labels struggle to maintain long-term structural stability when exposed to moisture. To solve this problem, we prepared composite crosslinked labels using phytic acid for double crosslinking of corn starch and soybean isolate proteins, with anthocyanin serving as the chromogenic dye. The mechanical properties, hydrophobic characteristics, and pH responsivity of these crosslinked labels were assessed in this study. The prepared double-crosslinked labels showed reduced moisture content (15.96%), diminished swelling (147.21%), decreased solubility (28.55%), and minimized water permeability, which suggested that they have enhanced hydrophobicity and densification. The crosslinked labels demonstrated the ability to maintain morphological stability when immersed in water for 12 h. Additionally, the mechanical properties of the crosslinked labels were enhanced without compromising their pH-sensing capabilities, demonstrated a color response visible to the naked eye for milk and coconut water freshness monitoring, suggesting great potential for application in beverages freshness monitoring., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

Cellulose-based aerogels offer exceptional promise for oily wastewater treatment, but the challenge of low mechanical strength and limited application functions persists. Inspired by the graded porous structures in the animal skeleton and bamboo stem, we firstly report here a stepwise solvent diffusion-induced phase separation approach for constructing the gradient pore-density three-dimensional (3D) cellulose scaffold (GPDS). Benefiting from the regulation of competitive hydrogen bonding between the anti-solvents and the ionic liquid (IL) in cellulose solution, GPDS exhibits the decreased major channels size and increased minor pores amount gradually along the solvent diffusion direction. These endow GPDS with the characteristics of low density (0.019 g/cm) and super strength (high up to 870 KPa). The application of GPDS in the field of oil-water separation has achieved remarkable results, including oil/organic solvent absorption (13-25 g/g GPDS ), immiscible oil-water mixture separation (high efficiency up to 99.8 %, flux > 2000 L/m 2 ·h), and surfactant-stabilized oil-in-water emulsion (efficiency up to 97.7 %). Moreover, a simple hydrophobic treatment further realizes the efficient separation of water-in-oil emulsion (98.5 % efficiency). The as-fabricated GPDS accordingly achieves the multifunctional application in oil-water separation field. Thus, a new avenue is opened to construct 3D cellulose porous scaffold as adsorbent materials in oily wastewater treatment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Recently, fiber-based and functional paper food packaging has garnered significant attention for its versatility, excellent performance, and potential to provide sustainable solutions to the food packaging industry. Fiber-based food packaging is characterized by its large surface area, adjustable porosity and customizability, while functional paper-based food packaging typically exhibits good mechanical strength and barrier properties. This review summarizes the latest research progress on food packaging based on fibers and functional paper. Firstly, the raw materials used for preparing fiber and functional paper, along with their physical and chemical properties and roles in food packaging, were discussed. Subsequently, the latest advancements in the application of fiber and paper materials in food packaging were introduced. This paper also discusses future research directions and potential areas for improvement in fiber and functional paper food packaging to further enhance their effectiveness in ensuring food safety, quality, and sustainability., Competing Interests: Declaration of competing interest The authors declare they have no conflict of interest., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The complexity of plant cell walls on different hierarchical levels still impedes the detailed understanding of biosynthetic pathways, interferes with processing in industry and finally limits applicability of cellulose materials. While there exist many challenges to readily accessing these hierarchies at (sub-) angström resolution, the development of advanced computational methods has the potential to unravel important questions in this field. Here, we summarize the contributions of molecular dynamics simulations in advancing the understanding of the physico-chemical properties of natural fibres. We aim to present a comprehensive view of the advancements and insights gained from molecular dynamics simulations in the field of carbohydrate polymers research. The review holds immense value as a vital reference for researchers seeking to undertake atomistic simulations of plant cell wall constituents. Its significance extends beyond the realm of molecular modeling and chemistry, as it offers a pathway to develop a more profound comprehension of plant cell wall chemistry, interactions, and behavior. By delving into these fundamental aspects, the review provides invaluable insights into future perspectives for exploration. Researchers within the molecular modeling and carbohydrates community can greatly benefit from this resource, enabling them to make significant strides in unraveling the intricacies of plant cell wall dynamics., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

In the quest for greener and more efficient energy storage solutions, the exploration and utilization of renewable raw materials is essential. In this context, cellulose-derived separators play a central role in enhancing the performance of green energy storage devices. However, these often exhibit disadvantageous porosity and limited wet strength. Here, we demonstrate a facile approach to tailor thickness (ca. 40 μm), air permeability (0.1-200 cm 3 s -1 ), and mechanical properties of separators by integration of up to 50 wt% microfibrillated cellulose (MFC) into paper sheets. While the MFC enhanced the formation of dense networks, these separators show a poor dimensional stability (folding and creasing) concomitant with a low strength under wet conditions, crucial for assembly and operation. Crosslinking with 1,2,3,4-butanetetracarboxylic acid (BTCA) however, led to an increase in wet strength by up to 6700 % while ensuring dimensional stability. The electrochemical performance, evaluated by impedance spectroscopy and galvanostatic cycling (7500 repetitions) showed comparable results as commercially available glass and polypropylene separators in terms of ion diffusion, charge-discharge rate performance, Ohmic loss and capacitance retention %. The approach demonstrates that disadvantages of paper-based separators in terms of dimensional stability and wet strength can be overcome by a paper technological approach using crosslinking strategies., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

In this study, we address the challenge of developing highly conductive hydrogels with enhanced stretchability for use in wearable sensors, which are critical for the precise detection of human motion and subtle physiological strains. Our novel approach utilizes amylopectin, a biopolymer, for the uniform integration of liquid metal gallium into the hydrogel matrix. This integration results in a conductive hydrogel characterized by remarkable elasticity (up to 7100 % extensibility) and superior electrical conductance (Gauge Factor = 31.4), coupled with a minimal detection limit of less than 0.1 % and exceptional durability over 5000 cycles. The hydrogel demonstrates significant antibacterial activity, inhibiting microbial growth in moist environments, thus enhancing its applicability in medical settings. Employing a synthesis process that involves ambient condition polymerization of acrylic acid, facilitated by a hydrophobic associative framework, this hydrogel stands out for its rapid gelation and robust mechanical properties. The potential applications of this hydrogel extend beyond wearable sensors, promising advancements in human-computer interaction through technologies like wireless actuation of robotic systems. This study not only introduces a viable material for current wearable technologies but also sets a foundation for future innovations in bio-compatible sensors and interactive devices., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

This work reports on the possibility of using polydopamine (PDA) as a tool to immobilize bromoisobutyryl moieties at the surface of cellulose nanocrystals (CNCs) and initiate Surface Intitiated Atom Transfer Radical Polymerization (SI-ATRP) reactions from these sites. Two different strategies based on i) the stepwise modification of the CNCs with dopamine (DA) and α-bromoisobutyryl bromide (BiBB) (Protocol 1) and ii) the one-step treatment of the CNCs with a mixture of DA and BiBB-modified DA (Protocol 2), were compared. Only the CNC particles treated according to Protocol 1 guaranteed efficient anchoring of the SI-ATRP initiating sites in our experimental conditions (with limited impact on the CNCs crystalline structure), the coated layer being leached out by certain solvents in the case of Protocol 2. The brominated particles displaying the best performances were subsequently tested as potential ATRP macroinitiators, using methyl methacrylate (MMA) and styrene (St) as model monomers. Polymer-grafted particles were successfully obtained, with a grafting density twice as high for Sty as for MMA, demonstrating the validity of this strategy., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Herein, the nanolignin-containing cellulose nanofibrils (LCNF)-enabled ratiometric fluorescent bio-nanocomposite film is developed. Interestingly, the inclusion of LCNF in the cellulose-based film enhances the detecting performance of food freshness, such as high sensitivity to biogenic amines (BAs) (limit of detection (LOD) of up to 1.83 ppm) and ultrahigh discernible fluorescence color difference (ΔE = 113.11). The underlying mechanisms are the fluorescence resonance energy transfer (FRET), π - π interaction, and cation - π interaction between LCNF and fluorescein isothiocyanate (FITC), as well as the increased hydrophobicity due to lignin, which increases the interactions of amines with FITC. Its color stability (up to 28 days) and mechanical property (49.4 Mpa) are simultaneously improved. Furthermore, a smartphone based detecting platform is developed to achieve access to food safety. This work presents a novel technology, which can have a great potential in the field of food packaging and safety., Competing Interests: Declaration of competing interest It is the original work of the authors. All the authors mutually agree that it should be submitted to Food Chemistry The manuscript has not been published or presented elsewhere in part or in entirety and is not under consideration by another journal. The authors declare that they have no conflict of interests. There is no research involving Human Participants and/or Animals., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Utilizing advanced multiple channels for information encryption offers a powerful strategy to achieve high-capacity and highly secure data protection. Cellulose nanocrystals (CNCs) offer a sustainable resource for developing information protection materials. In this study, we present an approach that is easy to implement and adapt for the covalent attachment of various fluorescence molecules onto the surface of CNCs using the Mannich reaction in aqueous-based medium. Through the use of the Mannich reaction-based surface modification technique, we successfully achieved multi-color fluorescence in the resulting CNCs. The resulting CNC derivatives were thoroughly characterized by two dimensional heteronuclear single quantum coherence nuclear magnetic resonance (2D HSQC NMR) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy and X-ray photoelectron (XPS) spectroscopy. Notably, the optical properties of CNCs were well maintained after modification, resulting in films exhibiting blue and red structural colors. This enables the engineering of highly programmable and securely encoded anti-counterfeit labels. Moreover, subsequent coating of the modified CNCs with MXene yielded a highly secure encrypted matrix, offering advanced security and encryption capabilities under ultraviolet, visible, and near-infrared wavelengths. This CNC surface-modification enables the development of multimodal security labels with potential applications across various practical scenarios., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Chemical modification is a reliable and efficient strategy for designing cellulose-based functional materials. Herein, porous quaternized cellulose beads (QCBs) as cationic superabsorbent were fabricated by homogeneous in-situ chemical grafting cellulose molecular chains with glycidyl trimethylammonium chloride (GTAC) in tetraethylammonium hydroxide (TEAOH)/urea aqueous solution followed by acetic acid induced regeneration. The influence of GTAC dosage on the physicochemical-structural properties of cationic QCBs was deeply investigated. Results revealed that cotton liner could well-dissolved in TEAOH/urea aqueous solution, leading to a homogeneous and efficient quaternization medium for cellulose, thereby giving the high DS and positive charge density for quaternized cellulose. NMR results demonstrated the main substitution of GTAC groups at 2-OH and 6-OH positions of the cellulose chains during quaternization reaction. With increasing GTAC dosage, the network skeleton of QCBs gradually transformed from thick fibrils to thin aggregates, as well as enhanced pore volumes and hydrophilicity. Accordingly, QCBs-1.5 with high pore volume (99.70 cm 3 /g) exhibited excellent absorption capacity and efficiency, absorbing 122.32 g of water and 0.45 g of moisture per gram of the beads in 20 min. This work not only offers a simple strategy for the homogeneous quaternization modification of cellulose, but also provides a porous cellulose-based cationic superabsorbent material., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Due to the unsatisfactory mechanical properties of natural polymer-based conductive hydrogels, their applications are limited. Shaanxi Biangbiang noodles can be toughened by applying external mechanical forces through stretching and beating movements; this process provides inspiration for the preparation of high-strength hydrogels. In this paper, we propose a strategy for the preparation of ultrastrong and ultratough conductive hydrogels by directional prestretching and solvent exchange. Neatly arranged fiber bundles containing many intermolecular hydrogen bonds and metal ion coordination bonds are successfully constructed inside the prepared hydrogels. The hydrogel has exceptional mechanical properties, with a fracture stress exceeding 50 MPa, fracture strain approaching 105 %, fracture toughness exceeding 30 MJ m -3 , and high conductivity reaching 11.738 ± 0.06 mS m -1 . Impressively, the hydrogel can maintain its high mechanical properties after being frozen at an ultralow temperature of -80 °C for 7 days. Compared with other tough hydrogels, natural tendons and synthetic rubbers, the hydrogel exhibits excellent mechanical properties. The cellulose-based conductive hydrogel prepared in this study can be applied to robotic soft tissues (such as the Achilles tendon) that require high strength and are operated in extreme environments., Competing Interests: Declaration of competing interest The authors declare no competing financial interest., (Copyright © 2024. Published by Elsevier Ltd.)

Concern about food safety triggers demand on rapid, accurate and on-site detection of foodborne pathogens. Among various fluorescent probes for detection, carbon dots (CDs) prepared by carbonization of carbon-rich raw materials show extraordinary performance for their excellent and tailorable photoluminescence property, as well as their facilely gained specificity by surface customization and modification. CDs-based fluorescent probes play a crucial role in many pathogenic bacteria sensing systems. In addition, microfluidic technology with characteristics of portability and functional integration is expected to combine with CDs-based fluorescent probes for point-of-care testing (POCT), which can further enhance the detection property of CDs-based fluorescent probes. Here, this paper reviews CDs-based bacterial detection methods and systems, including the structural modulation of fluorescent probes and pathogenic bacteria detection mechanisms, and describes the potential of combining CDs with microfluidic technology, providing reference for the development of novel rapid detection technology for pathogenic bacteria in food., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Structure color, arising from the interaction of light with regularly arranged sub-micrometer-sized structures, has spurred interest in sensor design. However, typical cellulose nanocrystal (CNC) photonic films derived from biomass, known for their sustainability and cost-effectiveness, often suffer from limited sensitivity and slow response times due to their dense structure. To address this challenge, we have utilized a unidirectional interlayer freezing-photopolymerization strategy to introduce porous structures into CNC photonic films without compromising their vibrant structural color. This method harnesses ice crystal-induced lamellar pores while preserving the periodic arrangement of CNCs. The underlying mechanism of ice kinetics and CNC assembly is established, highlighting the transition from non-iridescent aerogels to iridescent, porous photonic films. The resulting porous CNC photonic film exhibits apparent color response and rapid sensing capabilities in response to various solvent stimuli, outperforming its non-porous counterparts. We have validated the film as a portable vapor detector for rapid visualized alcohol detection. This approach provides promising developments in sustainable, highly responsive sensor technologies., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Bio-based compounds have become the focus in the development of next-generation materials. The polyphosphated structure and availability of phytic acid has sparked an interest to understand its properties and apply it to making fire-retardant fabrics. However, its degradative effect on natural fibers sets limitations to its potential uses. In this study, we unveiled a new dimension to explore with phytic acid: cellulose fiber foams. Phytic acid enabled synergistic foaming with carboxymethyl cellulose albeit causing issues in long-term wet foam stability. Adding cellulose fibers to this mixture and drying at 160 °C produced solid foams with increased compressive strength and stiffness; comparable to foams cross-linked with the commonly used citric acid. The reduced contact area in low-density fiber networks allowed the cross-linking between phytic acid and the fiber network to mitigate structural weakening due to fiber degradation. Imaging also revealed the formation of a film encompassing fiber bonds; attributed to the strong interaction between phytic acid and carboxymethyl cellulose. Furthermore, phytic acid imparted self-extinguishing fire-retardant properties to the cellulose fiber foams measured using thermogravimetric analysis and cone calorimetry. This work showcases a simple new application for phytic acid without the use of catalysts or solvents. It serves to encourage further development of green practices to continuously challenge the industrial landscape., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

Transparent cellulose papers have emerged as a promising substrate and/or functional component for next-generation sustainable flexible electronics. However, obtaining transparent paper with folding endurance comparable to that of plastic films such as polyethylene terephthalate (PET) remains a major challenge, which was addressed in this study by modulating the multiscale structure (from molecular structure, aggregation structure to fibrous morphology) of wood fibers. Compared to the natural wood fibers, the modified fibers not only retained their length and cellulose degree of polymerization (DP) to a large extent, but also had lower crystallinity and improved swelling capability, which well preserved the fiber strength and dense intertwined fiber network, and led to stronger inter-fiber interactions in the final transparent paper. The obtained paper (CM-paper) exhibits an optical transparency of 91 % and a folding endurance of 37,466 times, comparable to that of commercial PET (39,955 folds). Furthermore, the underlying mechanism for the superior foldability of the transparent paper was unveiled at three scales is explored. Finally, the potential application of CM-paper in electromagnetic induction electrodes was demonstrated, where the CM-paper electrodes exhibit satisfactory conductivity after repeated rubbing. This work offers an innovative approach to produce transparent papers with outstanding foldability, which is expected to plastic replacement., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Polymer-based sensors, particularly those derived from renewable polymers, are gaining attention for their superior properties compared to organic small molecules. However, their complex preparation and poor, uncontrollable sensitivity have hindered further development. Herein, cellulose-based polymer photoluminescence (PL) chemosensors were fabricated using a straightforward and adjustable strategy. Specifically, water-soluble cellulose acetoacetate (CAA) was used as the substance for the in-situ synthesis of 1,4-dihydropyridine (DHPs) fluorescent rings on cellulose chains via a catalyst-free, room-temperature Hantzsch reaction. Benefiting from the synergetic through-space conjugation of DHPs rings and semi-rigid cellulose chains with heteroatoms, the sensors exhibit bright and stable PL properties. Based on this performance, the cellulose-based sensor excels in the specific recognition of Fe 3+ in aqueous systems, showing exceptional selectivity, stability, and anti-interference performance due to the synergy between the inner filter effect (IFE) and intramolecular charge transfer (ICT). Theoretical calculations confirm the role of the extended π-conjugated structure at the DHPs-4 position in modulating the sensor sensitivity, achieving a low limit of detection (LOD) of 0.48 μM. Furthermore, the versatility of the Hantzsch reaction shows the potential of this strategy for developing a new generation of biomass-based polymer portable sensors for real-time and on-site detection., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Cellulose nanofibril (CNF) films with both high strength and high toughness are attractive for applications in energy, packaging, and flexible electronics. However, simultaneously achieving these mechanical properties remains a significant challenge. Herein, a multiscale structural optimization strategy is proposed to prepare high aspect ratio CNFs with reduced crystallinity for strong and tough films. Carboxymethylation coupled with mild mechanical disintegration is employed to modulate the multiscale structure of CNFs. The as-prepared CNFs feature an aspect ratio of >800 and a crystallinity of <60 %. The film prepared using CNFs with a high aspect ratio (~1100) and reduced crystallinity (~54 %) exhibits a tensile strength of 229.9 ± 9.9 MPa and toughness of 22.2 ± 1.4 MJ/m 3 . The underlying mechanism for balancing these mechanical properties is unveiled. The high aspect ratio of the CNFs facilitates the transfer and distribution of local stress, thus endowing the corresponding film with high strength and toughness. Moreover, the low crystallinity of the CNFs permits the movement of the cellulose chains in the amorphous regions, thereby dissipating energy and finally increasing the film toughness. This work introduces an innovative and straightforward method for producing strong and tough CNF films, paving the way for their broader applications., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Hydrogels are highly sought-after absorbent materials for absorbent pads; however, it is still challenging to achieve a satisfactory balance between mechanical performance, water absorption capacity, and active functionalities. In this work, we presented double-network hydrogels synthesized through acrylic acid (AA) polymerization in the presence of quaternized cellulose nanofibrils (QCNF) and Fe 3+ . Spectroscopic and microscopic analyses revealed that the combined QCNF and Fe 3+ facilitated the formation of double-network hydrogels with combined chemical and physical crosslinking. The synergistic effect of QCNF and Fe 3+ resulted in impressive mechanical properties, including tensile strength of 1.98 MPa, fracture elongation of 838.8 %, toughness of 7.47 MJ m -3 , and elastic modulus of 0.35 MPa. In comparison to the single-network PAA hydrogel, the PAA/QCNF/Fe 3+ (PQFe) hydrogels showed higher and relatively stable swelling ratios under varying pH levels and saline conditions. The PQFe hydrogels exhibited notable antioxidant activity, as evidenced by the 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay, and demonstrated effective antibacterial activity against both Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). These hydrogels show promising potential as an absorbent interlayer in absorbent pads for active food packaging., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

Food waste occurs frequently worldwide, though hunger and malnutrition issues have received global attention. Short-term spoilage of perishable foods causes a significant proportion of food waste. Developing simple, green, and low-cost strategies to preserve the freshness of perishable foods is important to address this issue and improving food safety. By using strawberries as the model perishable fruit, this study reported a pectin/carboxy methyl starch sodium (PC) based coating using epigallocatechin gallate-loaded eggshell powder (ES@EGCG) as the functional fillers. In comparison to PC coating, the PC-ES@EGCG coating displayed much-enhanced performance, such as enhanced mechanical (2 folds) and barrier (water vapor & oxygen) properties. This composite coating reduced the weight loss of strawberries from over 60% to around 30% after 7-day storage. Coated strawberries exhibit better freshness retention, which achieves the purpose of preserving strawberries during storage. This study provided a cost-effective and eco-friendly coating strategy for reducing food waste., Competing Interests: Declaration of competing interest The authors report no declarations of interest., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Cellulose microspheres (CMS) are a type of spherical regenerated cellulose particles with versatile properties which have been used as carrier materials in medical and technical applications. The integration of CMS into paper products opens up novel application scenarios for paper products in a wide range of fields. However, the incorporation of CMS carriers into paper products is challenging and hitherto no reports do exist in literature. Here, we present a feasibility study to incorporate up to 50 w.% CMS in paper hand sheets using retention aids. Our primary observations highlight the successful formation of uniform paper hand sheets retaining its tensile strengths at elevated CMS concentrations. Sheets with high CMS contents exhibit an increase in density and display enhanced surface smoothness - an outcome of a CMS layer forming atop the fiber base - which effectively bridges voids and rectifies surface irregularities as supported by Gurley testing, infinite focus microscopy and scanning electron microscopy. While our primary objective centered on the general feasibility to manufacture CMS-containing papers, the resulting composite scaffold carries significant potential as a platform for innovative, functional paper-based materials., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Xylans' unique properties make it attractive for a variety of industries, including paper, food, and biochemical production. While for some applications the preservation of its natural structure is crucial, for others the degradation into monosaccharides is essential. For the complete breakdown, the use of several enzymes is required, due to its structural complexity. In fact, the specificity of enzymatically-catalyzed reactions is guided by the surface, limiting or regulating accessibility and serving structurally encoded input guiding the actions of the enzymes. Here, we investigate enzymes at surfaces rich in xylan using surface plasmon resonance spectroscopy. The influence of diffusion and changes in substrate morphology is studied via enzyme surface kinetics simulations, yielding reaction rates and constants. We propose kinetic models, which can be applied to the degradation of multilayer biopolymer films. The most advanced model was verified by its successful application to the degradation of a thin film of polyhydroxybutyrate treated with a polyhydroxybutyrate-depolymerase. The herein derived models can be employed to quantify the degradation kinetics of various enzymes on biopolymers in heterogeneous environments, often prevalent in industrial processes. The identification of key factors influencing reaction rates such as inhibition will contribute to the quantification of intricate dynamics in complex systems., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

Hydrothermal carbonization (HTC) is an effective strategy for high-value utilization of tea residue (TR), and it was noticed the aqueous phase (AP) has not been extensively studied. This study aimed to investigate the chemical components and characteristics of the AP, and applied it in active food packaging films. The results showed that the total phenolic content of AP was 1.86 mg GAE/mL, and the main compounds in AP were organic acids, alcohols, and amino acids. The AP showed excellent antibacterial activity and antioxidant capacity. The active films were prepared using the casting method. The 4:7-AP/PVA film showed outstanding mechanical properties (tensile strength = 34.18 MPa, elongation at break = 458.67%), antioxidant ability (DPPH scavenging capacity 92.01%), antibacterial activity, water resistance and biocompatibility. The banana preservation test showed the AP/PVA films could successfully prolong the shelf-life of bananas and have the potential to be food packaging films., Competing Interests: Declaration of competing interest The authors declare no competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Treatment of infected wound by simultaneously eliminating bacteria and inducing angiogenesis to promote wound tissue regeneration remains a clinical challenge. Dynamic and reversable hydrogels can adapt to irregular wound beds, which have raised great attention as wound dressings. Herein, a sprayable chitosan-based hydrogel (HPC/CCS/ODex-IGF1) was developed using hydroxypropyl chitosan (HPC), caffeic acid functionalized chitosan (CCS), oxidized dextran (ODex) to crosslink through the dynamic imine bond, which was pH-responsive to the acidic microenvironment and could controllably release insulin growth factor-1 (IGF1). The HPC/CCS/ODex-IGF1 hydrogels not only showed self-healing, self-adaptable and sprayable properties, but also exhibited excellent antibacterial ability, antioxidant property, low-cytotoxicity and angiogenetic activity. In vivo experiments demonstrated that hydrogels promoted tissue regeneration and healing of bacteria-infected wound with a rate of approximately 98.4 % on day 11 by eliminating bacteria, reducing inflammatory and facilitating angiogenesis, demonstrating its great potential for wound dressing., Competing Interests: Declaration of competing interest The author declare that they have no competing financial interests or personal relationships that could have appeared to influence the work reported in the paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Water-soluble silver nanoclusters (AgNCs) as a new type of fluorescent material have attracted much attention for their remarkable optical properties and excellent cytocompatibility. However, it is still challenging to synthesize water-soluble AgNCs with good cytocompatibility and excellent fluorescence. Herein, the dialdehyde nanofibrillated cellulose (DANFC)- reduced water-soluble AgNCs capped by glutathione (GSH) with tunable fluorescence emissions were first reported. The DANFC provides a mild reduction environment and crystal growth system for the coordination between silver ions and GSH compared to conventional methods using strong reducing agents. The AgNCs with intense red fluorescence (R-AgNCs@GSH, size ∼2.24 nm) and green fluorescence (G-AgNCs@GSH, size ∼1.93 nm) were produced by varying the ratios of silver sources and ligands, and could maintain stable fluorescence intensity over 6 months. Moreover, the CCK-8 study demonstrated that the R-AgNCs@GSH and G-AgNCs@GSH reduced by DANFC of excellent cytocompatibility (cell viability >90 %) and enable precise multicolor intracellular imaging of Hela cells in 1 h. This work proposes a novel method to synthesize water-soluble AgNCs with tunable fluorescence emission at room temperature based on the classical silver- mirror reaction (SMR) using DANFC as reducing agent, and the synthesized fluorescent AgNCs have great potential as novel luminescent nanomaterials in biological research., Competing Interests: Declaration of competing interest The authors declare no conflict of interest., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Pulp and paper are gradually transforming from a traditional industry into a new green strategic industry. In parallel, cellulose-derived transparent paper is gaining ground for the development of advanced functional materials for light management with eco-friendly, high performance, and multifunctionality. This review focuses on methods and processes for the preparation of cellulose-derived transparent papers, highlighting the characterization of raw materials linked to responses to different properties, such as optical and mechanical properties. The applications in electronic devices, energy conversion and storage, and eco-friendly packaging are also highlighted with the objective to showcase the untapped potential of cellulose-derived transparent paper, challenging the prevailing notion that paper is merely a daily life product. Finally, the challenges and propose future directions for the development of cellulose-derived transparent paper are identified., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Chloropropanols are among the major food contaminants, and quantifying their content in food is a key food-safety issue. In response to the demand for highly sensitive and selective analysis, the scientific community is committed to continuous innovation and optimization of various analytical techniques. This paper comprehensively reviews the latest developments in chloropropanol analysis technologies and systematically compares and analyzes the working principles, application conditions, advantages, and challenges of these methods. Gas chromatography-mass spectrometry is the preferred choice for chloropropanol analysis in complex sample matrices owing to its high resolution, sensitivity, and accuracy. Electrochemical methods provide strong support for the real-time monitoring of chloropropanols because of their high selectivity and sensitivity towards electrochemically active molecules. Other techniques offer innovative solutions for the rapid and accurate analysis of chloropropanol at different levels. Finally, innovative directions for the development of chloropropanol analysis methods for food safety are highlighted., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The development of highly effective chitosan-based hemostatic materials that can be utilized for deep wound hemostasis remains a considerable challenge. In this study, a hemostatic antibacterial chitosan/N-hydroxyethyl acrylamide (NHEMAA)/Ti 3 C 2 T x (CSNT) composite cryogel was facilely prepared through the physical interactions between the three components and the spontaneous condensation of NHEMAA. Because of the formation of strong crosslinked network, the CSNT cryogel showed a developed pore structure (~ 99.07 %) and superfast water/blood-triggered shape recovery, enabling it to fill the wound after contacting the blood. Its capillary effect, amino groups, negative charges, and affinity with lipid collectively induced rapid hemostasis, which was confirmed by in vitro and in vivo analysis. In addition, CSNT cryogel showed excellent photothermal antibacterial activities, high biosafety, and in vivo wound healing ability. Furthermore, the presence of chitosan effectively prevented the oxidation of MXene, thus enabling the long-term storage of the MXene-reinforced cryogel. Thus, our hemostatic cryogel demonstrates promising potential for clinical application and commercialization, as it combines high resilience, rapid hemostasis, efficient sterilization, long-term storage, and easy mass production., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

Flexible conductive hydrogels (FCHs) have attracted widespread interest as versatile monoliths that can be intricately integrated with various ingredients boasting multiple functionalities. The chemicophysical properties of FCHs cover a wide range, which significantly vary in their building blocks. However, achieving both favorable mechanical strength and high conductivity simultaneously through a facile approach remains a challenge. Herein, polyvinyl alcohol, dialdehyde cellulose nanofibrils, silver nanoparticles, borax, and tannic acid are readily "one-pot" incorporated into FCHs with great tensile stress (499 kPa), tensile strain (4591 %), and compressive stress (269 kPa) due to abundant hydrogen bonding, dynamic borate-diol bonding, and intermolecular acetalization. They also exhibit desired self-healing, generalized-adhesive, and antibacterial performances. Taking advantage of these, FCHs are further employed to support an epidermal sensor, on which remarkable strain sensitivity (gauge factor = 8.22), high-pressure sensitivity (≥ 0.258 kPa -1 ), and fast response (≤ 190 ms) are recorded. Its highly adaptive mechano-electric transformability and functions can be well maintained in serving as an array unit and touch screen pen. The results well addressed in this work are anticipated to pave the universal way of engineering FCHs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Cryogels that are constructed with cellulose nanofibrils (CNF) are important as green materials for a wide range of applications. However, their utilization is limited by inherent hydrophilicity and insufficient mechanical properties. Herein, a processable CNF/nanochitin (NCh)-stabilized Pickering emulsion that contains polylactide (PLA) in the oil phase is developed to directly produce ternary composite cryogels via freeze-drying. The complexation of CNF with NCh promotes CNF adsorption at the surface of PLA droplets, resulting in formation of uniform Pickering PLA droplets. The CNF/NCh complex-stabilized PLA droplets are easy to be translated to the internal structure of the cryogels, exhibiting lightweight nature and possessing highly porous structure. The interconnected network and lamellar structure formed by the CNF/NCh complexes, associating with inclusion of PLA particles, improve the cryogel structure integrity upon post-processing and endow hydrophilic cryogel with water resistance. This study offers a straightforward and eco-friendly Pickering emulsion template on fabrication of the CNF-based composite cryogel with controllable microstructure and mechanical performance, broadening construction of nanocellulose-based composites., Competing Interests: Declaration of competing interest The authors declare no competing interests., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Properties of cellulose are typically functionalized by organic chemistry means. We progress an alternative facile way to functionalize cellulose by functional group counter-cation exchange. While ion-exchange is established for cellulose, it is far from exploited and understood beyond the most common cation, sodium. We build on our work that established the cation exchange for go-to alkali metal cations. We expand and further demonstrate the introduction of functional cations, namely, lanthanides. We show that cellulose nanocrystals (CNCs) carrying sulfate-half ester groups can acquire properties through the counter-cation exchange. Trivalent lanthanide cations europium (Eu 3+ ), dysprosium (Dy 3+ ) and gadolinium (Gd 3+ ) were employed. The respective ions showed distinct differences in their ability of being coordinated by the sulfate groups; with Eu 3+ fully saturating the sulfate groups while for Gd 3+ and Dy 3+ , values of 82 and 41 % were determined by compositional analysis. CNCs functionalized with Eu 3+ displayed red emission, those containing Dy 3+ exhibited no optical functionality, while those with Gd 3+ revealed significantly altered magnetic relaxation times. Using cation exchange to alter cellulose properties in various ways is a tremendous opportunity for modification of the abundant cellulose raw materials for a renewable future., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

The colored and high-saline effluents during the traditional dyeing process poses serious environmental challenge. In our study, an eco-friendly cationic cellulose nano-fiber/chitosan (CCNF/CS) binary versatile auxiliary was designed for the neutral salt-free dyeing and physical enhancement of paper by mixing with pulp simply. Profiting from the rich cationic binding sites of CCNF/CS (Charge density: 3749.67 μmol/g), under near neutral conditions (pH = 6.2), the maximum adsorption capacity of anionic GL (Direct fast turquoise blue GL) on paper with 0.5 % CCNF/CS reached 1865.06 mg/g with a desirable evenness (45.5 % and 92.1 % higher than that of CCNF and NaCl group, respectively), and the dye uptake was up to 97 %. The spontaneous adsorption behavior was aligned with the pseudo-second-order and Langmuir models, with a primary physical mechanism enhanced by chemical forces. The combination of strong electronic attraction, hydrogen bonding, and n-π stacking effects granted CCNF/CS an enhanced proficiency in anionic dye adsorption. In addition, the tensile strength of the resulting paper yarn with 0.5 % CCNF/CS increased to 52.47 MPa under the optimal parameters, deriving from the CCNF/CS-induced inter-fiber cohesion. Overall, our research provided a green promising approach for the innovative neutral salt-free dyeing and mechanical enhancement of paper., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Widely employed petroleum-based food packaging materials have inflicted irreparable harm on ecosystems, primarily stemming from their non-biodegradable attributes and recycling complexities. Inspired by natural nacre with a layered aragonite platelet/nanofiber/protein multi-structure, we prepared high-barrier composite films by self-assembly of cellulose nanofibrils (CNF), cellulose nanocrystals (CNC), montmorillonite (MMT), polyvinyl alcohol (PVA) and alkyl ketene dimer (AKD). The composite films demonstrated outstanding barrier properties with oxygen vapor transmission of 0.193 g·mm·m -2 ·day -1 and water vapor transmission rates of 0.062 cm 3 ·mm·m -2 ·day -1 ·0.1 MPa -1 , which were significantly lower than those of most biomass-degradable packaging materials. Additionally, the impacts of mixing nanocellulose with various aspect ratios on the tensile strength and folding cycles of the films were examined. The exceptional resistance of the composite films to oil and water provides a novel and sustainable approach to reduce non-biodegradable plastic packaging., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Cellulose acetate (CA)-based electrospun nanofiber aerogel (ENA) has drawn extensive attention for wastewater remediation due to its unique separation, inherent porosity and biodegradability. However, the low mechanical strength, poor durability, and limited adsorption ability hinder its further applications. We herein propose using silane-modified ENA, namely T-CA@Si@ZIF-67 (T-ENA), with enhanced resilience, hydrophobicity, durability and hetero-catalysis to remediate a complex wastewater containing oil and drug residues. The robust T-ENA was fabricated by pre-doping tetraethyl orthosilicate (TEOS) and ligand in its spinning precursors, followed by in-situ anchoring of porous ZIF-67 on the electrospun nanofibers (ENFs) via seeding method before freeze-drying and thermal curing (T). Results show that the T-ENA displays enhanced mechanical stability/resilience and hydrophobicity without compromise of its high porosity (>98 %) and low density (10 mg/cm 3 ) due to the silane cross-linking. As a result, the hydrophobic T-ENA shows over 99 % separation efficiency towards different oil-water solutions. Meanwhile, thanks to the enhanced adsorption-catalytic ability and the activation of peroxymonosulfate (PMS) from the porous ZIF-67, fast degradation of carbamazepine (CBZ) residue in the wastewater can be achieved within 20 min. This work might provide a novel strategy for developing CA aerogels to remove organic pollutants., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Deep eutectic solvents (DES) have been regarded as green solvents in the biorefinery of lignocellulosic biomass, but long duration time has severely limited efficiency. The microwave-assisted DES pretreatment along with enzymatic hydrolysis and high-pressure homogenization process was proposed to produce lignin-containing cellulose nanofibrils (LCNF) from corncob. Benefiting from microwave-assisted DES pretreatment, the duration time was greatly shortened; meanwhile the effects of different kinds of DES on the resultant LCNF were investigated. The results showed that, the microwave-assisted DES fabricated LCNF (M-LCNF) was successfully obtained, exhibiting good nano size, thermal stability, colloidal stability, and fluorescence. M-LCNF was further introduced into phytic acid (PA) enhanced poly(acrylamide-co-acrylic acid) (P(AM-co-AA)) network and constructed composite conductive hydrogels (PLP). The obtained hydrogels exhibited good mechanical strength, UV blocking ability, fluorescence, and conductivity. A simple battery assembled with the resultant PLP as electrolyte had an out voltage of 2.41 V. The composite conductive hydrogel showed good sensing performance towards different stimuli (e.g., stretching and compression) and human motions in real time. It is expected that this research would provide an alternative way for green fabrication of LCNF and potential application of LCNF in flexible sensors., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In this study, the quaternized carboxymethyl chitosan (QCMCS), oxidized hyaluronic acid (OHA), 3,3'-dithiobis-(propionohydrazide) (DTP) were used as raw materials for the synthesis of hydrogels with excellent properties as carriers for drug release. The hydrogels were prepared by a simple "one-pot" method without external stimuli on the basis of interactions between formed dynamic covalent bonds (imine bonds, acylhydrazone bonds, disulfide bonds) and hydrogen bonds. The hydrogels had rapid self-healing properties, with a self-healing rate of 96 % after 30 min, as well as good pH responsiveness and excellent cytocompatibility (up to 98 % cell survival). The compressive stress of the hydrogels reached 423 kPa. Moreover, a representative drug (acetylsalicylic acid) demonstrated sustained release in the hydrogels (>72 h). The drug release behaviour was shown to be consistent with the Fick diffusion mechanism by kinetic modelling. Collectively, the findings demonstrate that the QCMCS + OHA + DTP injectable self-healing hydrogels are a potential material for the construction of pH-controlled drug delivery platforms., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

Foams with advanced sensing properties and excellent mechanical properties are promising candidates for smart packaging materials. However, the fabrication of ultra-elastic and durable foams is still challenging. Herein, we report a universal strategy to obtain ultra-elastic and durable foams by crosslinking cellulose nanofiber and MXene via strong covalent bonds and assembling the composites into anisotropic cellular structures. The obtained composite foam shows an excellent compressive strain of up to 90 % with height retention of 97.1 % and retains around 90.3 % of its original height even after 100,000 compressive cycles at 80 % strain. Their cushioning properties were systematically investigated, which are superior to that of wildly-used petroleum-based expanded polyethylene and expanded polystyrene. By employing the foam in a piezoelectric sensor, a smart cushioning packaging and pressure monitoring system is constructed to protect inner precision cargo and detect endured pressure during transportation for the first time., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

Achieving excellent ultraviolet (UV) blocking properties and maintaining high light transmittance are highly challenging. In this study, a facile and green polymer-assisted vacuum filtration strategy was used to prepare cellulose nanocrystal (CNC) one-dimensional photonic crystal (1DPhC) films with excellent UV-blocking performance and good transparency. The polymer-assisted self-assembly behaviors of CNC and the hydrogen bonding interaction between CNC, polyethylene glycol (PEG), and graphene oxide (GO) drive the homogeneous distribution and parallel alignment of GO. The UV absorption of GO and high reflection of UV resulting from the chiral nematic structure of CNCs result in excellent UV-blocking and high visible light transmission. Besides, the strong hydrogen bonding interaction among CNC, PEG, and GO endows the films with obviously increased mechanical properties. The UV-blocking and the transparency of the CNC composite films could reach 98.3 % and 60.5 %, respectively. Besides, the strain at break of the composite film reached 1.72 ± 0.11 %, which was 535.94 % of neat CNC films. The CNC composite films present great potential in the field of UV-blocking glass, sensors, anti-counterfeiting measures, radiation protection, and so on., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In this work, saccharide branched cellulose (saccharide b-Cel) was synthesized by combining reducing saccharides with cellulose molecules using Ugi four-component reaction (Ugi-4CR). First, the carboxyl groups required for Ugi-4CR are obtained by carboxymethylating cellulose molecules. Then, saccharide b-Cel with a controlled molecular structure is formed when the terminal aldehyde group of reducing saccharides combines with the carboxyl group and auxiliary functional group. The types of saccharides, the degree of substitution of carboxymethyl groups, and the degree of branching all affect the molecular structure of saccharide b-Cel. Through molecular structural regulation, the relationship between the branching structure and water retention ability of saccharide b-Cel was examined in detail. This work not only provides new insights into the synthesis of cellulose derivatives, but it also provides a template for the synthesis of other biomass derivatives., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Simultaneously having competitive compressive properties, fatigue-resistant stability, excellent conductivity and sensitivity has still remained a challenge for acrylic-based conductive hydrogels, which is critical in their use in the sensor areas where pressure is performed. In this work, an integrated strategy was proposed for preparing a conductive hydrogel based on acrylic acid (AA) and sodium alginate (SA) by addition of carboxylic-cellulose nanocrystals (CNC-COOH) followed by metal ion interaction to reinforce its compressive strength and conductivity simultaneously. The CNC-COOH played a multifunctional role in the hydrogel by well-dispersing SA and AA in the hydrogel precursor solution for forming a uniform semi-interpenetrating network, providing more hydrogen bonds with SA and AA, more -COOH for metal ion interactions to form uniform multi-network, and also offering high modulus to the final hydrogel. Accordingly, the as-prepared hydrogels showed simultaneous excellent compressive strength (up to 3.02 MPa at a strain of 70 %) and electrical conductivity (6.25 S m -1 ), good compressive fatigue-resistant (93.2 % strength retention after 1000 compressive cycles under 50 % strain) and high sensitivity (gauge factor up to 14.75). The hydrogel strain sensor designed in this work is capable of detecting human body movement of pressing, stretching and bending with highly sensitive conductive signals, which endows it great potential for multi-scenario strain sensing applications., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Nanocellulose films possess numerous merits ascribing to their inherent biocompatibility, non-toxic and biodegradability properties. The potential for practical applications would be improved if their mechanical strength and toughness requirements could be met simultaneously. Herein, dual cross-linked nanocellulose (DC) film was fabricated by the treatments of chemical and physical cross-linking, which was mechanically superior to pure nanocellulose (CNF) films. To further increase the toughness of DC films, spherical cellulose (Sph) was incorporated into DC film (DC-Sph film), and analyzed under different humidity conditions (RH) (from 10 % to 90 %). The changes of functional groups of CNF, DC and DC-Sph films were detected by FTIR and XPS spectrum. The epichlorohydrin and Sph content were optimized, followed by the investigation of RH on the toughness of films. The highest tensile strength (146.6 ± 4.6 MPa) was obtained in DC film at 50 % RH, while the DC-Sph film showed the largest toughness (40.3 ± 3.7 kJ/m 2 ) at 70 % RH. Furthermore, the possible toughening mechanism of DC-Sph film was also discussed., Competing Interests: Declaration of competing interest There is no conflict of interest., (Copyright © 2023. Published by Elsevier Ltd.)

The increasing commercialization of flexible electronic products has sparked a rising interest in flexible wearable energy storage devices. Supercapacitors are positioned as one of the systems with the most potential due to their distinctive advantages: high power density, rapid charge and discharge rates, and long cycle life. However, electrode materials face challenges in providing excellent mechanical strength while ensuring sufficient energy density. This study presents a method for constructing a flexible composite electrode material with high capacitance and mechanical performance by electrochemically depositing high-quality manganese dioxide (MnO 2 ) onto the surface of a nanocellulose (CNF) and carbon nanotube (CNT) conductive film. In this electrode material, the CNF/CNT composite film serves as a flexible conductive substrate, offering excellent mechanical properties (modulus of 3.3 GPa), conductivity (55 S/cm), and numerous active sites. Furthermore, at the interface between MnO 2 and the CNF/CNT substrate, C-O-Mn bonds are formed, promoting a tight connection between the composite materials. The assembled symmetric flexible supercapacitor (FSC) demonstrates impressive performance, with an areal specific capacitance of 934 mF/cm 2 , an energy density of 43.10 Wh/kg, a power density of 166.67 W/kg and a long cycle life (85 % Capacitance retention after 10,000 cycles), suggesting that they hold promise for FSC applications., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

Liquid penetration in porous cellulosic materials is crucial in many technological fields. The complex geometry, small pore size, and often fast timescale of liquid uptake makes the process hard to capture. Effects such as swelling, vapor transport, film flow and water transport within cellulosic material makes transport deviate from well-known relations such as Lucas-Washburn and Darcy's Law. In this work it is demonstrated how Ultra-Fast Imaging NMR can be used to simultaneously monitor the liquid distribution and swelling during capillary uptake of water with a temporal- and spatial resolution of 10 ms and 14.5-18 μm respectively. The measurements show that in a cellulose fiber sheet, within the first 65 ms, liquid first penetrates the whole sheet before swelling takes place for another 30 s. Furthermore, it was observed that the liquid front traps 15 v% of air which is slowly replaced by water during the final stage of liquid uptake. Our method makes it possible to simultaneously quantify the concentration of all three phases (solid, liquid and air) within porous materials during processes exceeding 50 ms (5 times the temporal resolution). We hence believe that the proposed method should also be useful to study liquid penetration, or water diffusion, into other porous cellulosic materials like foams, membranes, nonwovens, textiles and films., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Herein, we propose a carbon/TiO 2 /Co 3 O 4 (CTC) composite carbon aerogel with a 3D porous conductive network structure derived from sodium carboxymethylcellulose (CMC)/Mxene (Ti 3 C 2 T x )/zeolite imidazolium framework-67 (ZIF-67). Among them, CMC is used as the carbon skeleton, which can reduce the powdering caused by volume change and improve the cycle stability. Ti 3 C 2 T x acts as the conductive agent and dispersant for ZIF-67, exposing more reactive sites while constructing fast conductive channels to enhance electrochemical performance. The microstructure of the CTC carbon aerogel is modulated by controlling the mass ratio of Ti 3 C 2 T x to ZIF-67, and the carbon aerogel with a mass ratio of 2:3 (CTC-2:3) is experimentally demonstrated to have the best electrochemical performance. The CTC-2:3 electrode exhibits a high specific capacitance of 481.7 F g -1 at 1 A g -1 and possesses a rate performance of 78.9 % at 10 A g -1 . The assembled asymmetric supercapacitor (ASC, CTC-2:3//Ti 3 C 2 T x ) delivers an energy density of 48.4 Wh kg -1 at a power density of 699.8 W kg -1 . Moreover, the ASC device maintains 85.3 % initial capacitance and 99.1 % coulombic efficiency after 10,000 GCD cycles, indicating good cycling stability. This facile design pathway provides a new insight for the development of high-performance electrode materials., Competing Interests: Declaration of competing interest No conflict of interest exits in the submission of this manuscript, and the manuscript is approved by all authors for publication., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Conductive hydrogels have received increasing attention in the field of wearable electronics, but they also face many challenges such as temperature tolerance, biocompatibility, and stability of mechanical properties. In this paper, a double network hydrogel of MXene/TEMPO bacterial cellulose (TOBC) system is proposed. Through solvent replacement, the hydrogel exhibits wide temperature tolerance (-20-60 °C) and stable mechanical properties. A large number of hydrogen bonds, MXene/TOBC dynamic three-dimensional network system, and micellar interactions endow the hydrogel with excellent mechanical properties (elongation at break ~2800 %, strength at break ~420 kPa) and self-healing ability. The introduction of tannic acid prevents the oxidation of MXene and the loss of electrical properties of the hydrogel. In addition, the sensor can also quickly (74 ms) and sensitive (gauge factor = 15.65) wirelessly monitor human motion, and the biocompatibility can well avoid the stimulation when it comes into contact with the human body. This series of research work reveals the fabrication of MXene-like flexible wearable electronic devices based on self-healing, good cell compatibility, high sensitivity, wide temperature tolerance and durability, which can be used in smart wearable, wireless monitoring, human-machine Interaction and other aspects show great application potential., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Cellulose, an abundant and eco-friendly polymer, is a promising raw material to be used for preparing energy storage devices such as lithium-ion batteries (LIBs). Despite the significance of cellulose functional groups in LIBs components, their structure-properties-application relationship remains largely unexplored. This article thoroughly reviews the current research status on cellulose-based materials for LIBs components, with a specific focus on the impact of functional groups in cellulose-based separators. The emphasis is on how these functional groups can enhance the mechanical, thermal, and electrical properties of the separators, potentially replacing conventional non-renewal material-derived components. Through a meticulous investigation, the present review reveals that certain functional groups, such as hydroxyl groups (-OH), carboxyl groups (-COOH), carbonyl groups (-CHO), ester functions (R-COO-R'), play a crucial role in improving the mechanical strength and wetting ability of cellulose-based separators. Additionally, the inclusion of phosphoric group (-PO 3 H 2 ), sulfonic group (-SO 3 H) in separators can contribute to the enhanced thermal stability. The significance of comprehending the influence of functional groups in cellulose-based materials on LIBs performance is highlighted by these findings. Ultimately, this review explores the challenges and perspectives of cellulose-based LIBs, offering specific recommendations and prospects for future research in this area., Competing Interests: Declaration of competing interest It is the original work of the authors. All the authors mutually agree that it should be submitted to Carbohydrate Polymers. The manuscript has not been published or presented elsewhere in part or in entirety and is not under consideration by another journal. The authors declare that they have no conflict of interests. There is no research involving Human Participants and/or Animals., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Starch and modified starch, spanning various structural levels, are comprehensively reviewed, with a special emphasis on the advancement of starch and its derivative-based delivery systems for bioactive substances. The pivotal aspect highlighted is the controlled release of active ingredients by starch-based delivery systems with distinct hierarchical structures. At the molecular level, diverse categories of starch degradation products, such as dextrin and highly branched starch, serve as versatile amphiphilic carriers for encapsulating active ingredients. At the level of helical structure, the distinctive configuration of the starch-guest complex partly determines the mechanism of controlled release for diverse active components. At the crystal and particle structural level, starch assumes the role of a carrier, effectively modulating the release of active substances, and enhances the innate physiological activity of different active components. As a natural polymer molecule, starch can also generate hydrogel materials in polymer form, expanding its utility in the fields of food, materials, and even medicine., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Nanocellulose finds various applications in advanced electrical devices due to its impressive mechanical properties, thermal stability, and degradability. Cellulose nanocrystals (CNCs) with excellent dielectric properties may act as a fresh dielectric plastic. In this study, a new strategy of small molecule modification was used to improve the dielectric constant, breakdown strength, and band gap of the CNCs. The dipole moments, dipole density, and the anisotropic impact of surface groups on the dielectric constant were studied. The number of sulfates in the CNCs showed a gradient due to alkali treatment and sulfonation, which allowed for a controlled range of the dielectric constant of nanocellulose between 4.9 and 11.9. TEMPO oxidation (2,2,6,6-tetramethylpiperidine-1-oxyl) and cyanoethylation of the CNCs further increased the dielectric constant to 11.1 and 13.2, respectively, and the dielectric loss 10 -1 . By understanding and innovating organic polymer dielectrics, we can provide significant benefits to the electronics and device industries., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

Motivated by the quest for biocompatibility, we report on oil-in-water (O/W), high-internal-phase Pickering emulsions stabilized via complexes of mechanical cellulose nanofibrils (CNF) and food-grade cationic surfactant ethyl lauroyl arginate (LAE). The complexation of oppositely charged CNF and LAE can be held together by electrostatic interaction. Their effect on suspensions electrostatic stabilization, heteroaggregation state, and emulsifying ability was studied and related to properties of resultant interfacial tension between oil and water and 3D printing of emulsions. The Pickering system with adjustable droplet diameter and stability against creaming and oiling-off during storage was achieved resting with LAE loading. Complexes formed by LAE adjustment act as Pickering stabilizers and three-dimensional networks in emulsion system, forming a scaffold with elastoplastic rheological properties that flows above critical stress while, without any additional treatment, exhibiting the required self-standing properties for 3D printing. By understanding the properties of CNF/LAE behavior in bulk and on interfaces, printing edible functional foods of CNF/LAE-based emulgel inks has been demonstrated to enable regulation of oil release., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In this study, hydrophobic nanochitin aerogels are synthesized via one-pot synthesis strategy and subsequent freeze-drying technique, employing nanochitin, hexanal and formaldehyde as primary components. The tert-butyl alcohol (TBA)/water binary solvents are found efficient for well mixing of hydrophilic nanochitin and hydrophobic hexanal, which is fundamental for fabricating hydrophobic aerogels with water contact angle as high as 105°. Schiff base reaction between amino groups in nanochitin and aldehyde groups in hexanal is believed to be the main reason for the successful hydrophobization of nanochitin aerogels. Additionally, formaldehyde is employed to enhance the mechanical properties of aerogels via ice templated crosslinking technique. Nanochitin aerogels prepared in this work possess surface area as high as 237 m 2 g -1 , which are believed benefiting from the TBA/water binary solvents with lower density, smaller ice crystal and convenience in freeze-drying. The ultralow density, ultrahigh porosity, and hydrophobicity nature also lead to the advanced oil adsorption (as high as 210 g g -1 ) of nanochitin aerogels. The simple preparation process, nature sustainability and excellent adsorption performance is believed rendering nanochitin aerogels as a viable alternative for the remediation of oil spills., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)