10 results on '"Chen, De"'
Search Results
2. Nitrogen-containing carbon nanofibers as supports for bimetallic Pt-Mn catalysts in aqueous phase reforming of ethylene glycol.
- Author
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Pazos Urrea, Monica, Herold, Felix, Chen, De, and Rønning, Magnus
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CARBON nanofibers , *BIMETALLIC catalysts , *ETHYLENE glycol , *CATALYTIC activity , *NITROGEN , *PLATINUM group , *STEAM reforming , *CHARGE transfer - Abstract
Aqueous phase reforming (APR) of ethylene glycol was performed at 225 °C and 30 bar in batch and continuous reaction conditions. The effect on the APR performance by functionalizing carbon supports with nitrogen and adding Mn to Pt-based catalysts was investigated. The presence of nitrogen species on the carbon surface and Mn-addition (PtMn) improved the catalytic activity and promoted H 2 production. XPS results suggest that the enhancement of the catalytic activity may be attributed to charge transfer from platinum to the nitrogen groups and Mn. Pt-based catalysts were stable under the studied reaction conditions, while up to 97 % of the manganese leached into the liquid solution during APR. However, the catalytic activity was maintained even with such significant decrease in Mn content, indicating that only a small amount of Mn is necessary to maintain the promotional effect on Pt during APR. [Display omitted] • Electronic interactions between Pt-N and Pt-Mn led to enhanced catalytic activity. • N-doped carbon nanofibers effectively improved H 2 yield in aqueous phase reforming. • Pt-based catalyst promoted with Mn presented higher H 2 yield and selectivity. • Metal-support interactions are key factors in promoting catalytic activity. [ABSTRACT FROM AUTHOR]
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- 2023
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3. ABO3 perovskite catalyst screening for chemical looping methane partial oxidation from descriptor-based microkinetic analysis.
- Author
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Niu, Zi-Hua, Yang, Jie, Zhou, Ze-Yi, Lei, Ming, Sui, Zhi-Jun, Chen, De, Zhou, Xing-Gui, and Zhu, Yi-An
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CHEMICAL-looping combustion , *OXYGEN carriers , *PARTIAL oxidation , *METHANE , *PEROVSKITE , *CATALYTIC activity , *CATALYSTS , *VOLCANOES - Abstract
• Microkinetic analysis is used to screen perovskites for methane partial oxidation. • The catalytic activity varies in the order LaMnO 3 > LaFeO 3 > LaCoO 3 ≈ LaCrO 3. • Bulk oxygen vacancy formation energy is identified as a single descriptor. • 667 combinations of A- and B-cations have been screened in terms of stability. • SrRuO 3 , SmRhO 3 , LaIrO 3 , NdRhO 3 , and BaOsO 3 are identified as catalyst candidates. DFT calculations and descriptor-based microkinetic analysis have been performed to screen ABO 3 perovskite catalysts for methane partial oxidation. The scaling relations indicate the adsorption energies of H@O and CH 3 @B have the capability of representing the energetics of methane oxidation, and bulk oxygen vacancy formation energy is identified to be a better single descriptor of the kinetics. The resultant volcano-shaped plot shows the catalytic activity varies in the order LaMnO 3 > LaFeO 3 > LaCoO 3 ≈ LaCrO 3 , which agrees with the experimental findings and thus validates our theoretical predications. By screening 667 combinations of A- and B-cations based on electron neutrality, structural tolerance factors, and experimental verification, 77 ABO 3 have been identified to be stable. Of them, SrRuO 3 , SmRhO 3 , LaIrO 3 , NdRhO 3 , and BaOsO 3 are located at the summit of the volcano, which also exhibit satisfactory CO selectivity and enhanced carbon resistance compared to LaFeO 3 , and may act as the oxygen carrier candidates. [ABSTRACT FROM AUTHOR]
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- 2024
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4. Tailoring catalytic properties of V2O3 to propane dehydrogenation through single-atom doping: A DFT study.
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Zhang, Jun, Zhou, Rui-Jia, Chang, Qing-Yu, Sui, Zhi-Jun, Zhou, Xing-Gui, Chen, De, and Zhu, Yi-An
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CATALYTIC dehydrogenation , *DEHYDROGENATION , *CATALYST selectivity , *PROPANE , *DENSITY functional theory , *CATALYTIC activity - Abstract
[Display omitted] • The electronic structure of V 2 O 3 upon single-atom doping is examined. • A weak Lewis acid-base interaction is found to occur on the pristine surface. • The first dehydrogenation step is identified as the rate-limiting step for PDH. • Mn 1 -V 2 O 3 is suggested to be a good catalyst candidate for PDH. Vanadium-oxide-based catalysts have recently been found very promising for the catalytic dehydrogenation of propane. In this work, self-consistent density functional theory calculations have been performed to examine how the electronic structure of the V 2 O 3 (0001) surface is modified by single-atom doping and how the catalytic properties can be tailored to propane dehydrogenation. The structural stability of single-atom-doped V 2 O 3 (0001) surfaces is assessed by comparing the adsorption energies of single atoms with the cohesive energies of bulk metals. A weak Lewis acid-base interaction is found to occur on the pristine surface, which can be strengthened and weakened by substitution of single atoms for V and O, respectively. On these two types of oxide surfaces, single atoms act as promoters and active sites. The first dehydrogenation step is identified as the rate-limiting step by microkinetic analysis. On all the single-atom-doped surfaces, the activation energy for water formation is higher than that for hydrogen recombination, implying that reduction of the oxide surfaces is difficult to take place during the course of the reaction. If a compromise between the catalytic activity and catalyst selectivity is made, Mn 1 -V 2 O 3 is suggested to be a good candidate as the catalyst for propane dehydrogenation. [ABSTRACT FROM AUTHOR]
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- 2021
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5. Coordination number engineering of Zn single-atom sites for enhanced transfer hydrogenation performance.
- Author
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Song, Yaping, Guo, Rou, Feng, Binbin, Fu, Yanghe, Zhang, Fumin, Zhang, Yifei, Chen, De-Li, Zhang, Jiangwei, and Zhu, Weidong
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TRANSFER hydrogenation , *ELECTRON distribution , *ELECTRON density , *METAL catalysts , *CATALYTIC activity , *NANOPARTICLES - Abstract
• A series of Zn SACs synthesized via a ZIF-8-mediated sacrificial template strategy. • Zn–N–C–T exhibited high performance in transfer hydrogenation nitrobenzene to aniline. • The activity of Zn–N–C–T is closely related to the coordination number of Zn sites. • The hydrogenation mechanism over Zn–N–C–1223 is disclosed by the DFT calculations. Metal single-atom catalysts (SACs) have great potential to replace traditional nanoparticle catalysts in practical applications, however, the task-specific construction of SACs containing metal–nitrogen (M−N) moiety with tunable M−N coordination number remains a colossal challenging issue. Herein, we report a facile strategy to modulate the s-band of Zn by constructing N-coordinated Zn SACs (denoted as Zn–N–C–T, T stands for the pyrolysis temperature) with tunable nitrogen coordination number (denoted as Zn–N x , x = 2, 3, and 4) and Zn loadings (ranging from 0.8 to 6.8% by weight) via a metal–organic framework-mediated pyrolysis method. The catalytic activity of Zn–N–C–T is found to be closely related to the coordination number of Zn single atomic sites for the transfer hydrogenation of nitroarene to arylamine, using hydrazine hydrate as a hydrogen source under environmental benign conditions, among which the under-coordinated Zn–N 3 with defect and asymmetric electron distribution in Zn–N–C–1223 exhibits the best catalytic activity, followed by lower-coordinated Zn–N 2 with defect in Zn–N–C–1273 and saturated coordination Zn–N 4 in Zn–N–C–1123. Experimental results and theoretical analysis uncover that appropriately lowering the coordination number increases the electron density of Zn single atoms and simultaneously introduces H-acceptor sites, which cooperatively contribute to the enhancement of the performance for transfer hydrogenation. [ABSTRACT FROM AUTHOR]
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- 2023
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6. Improving the catalytic activity of β-glucosidase from Coniophora puteana via semi-rational design for efficient biomass cellulose degradation.
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Zhou, Hai-Yan, Chen, Qi, Zhang, Yi-Feng, Chen, Dou-Dou, Yi, Xiao-Nan, Chen, De-Shui, Cheng, Xin-Ping, Li, Mian, Wang, Hong-Yan, Chen, Kai-Qian, Liu, Zhi-Qiang, and Zheng, Yu-Guo
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CATALYTIC activity , *CELLULOSE , *BIOMASS , *GLYCOSIDASES , *SITE-specific mutagenesis , *LIGNOCELLULOSE , *ENZYME kinetics - Abstract
In order to improve the degradation activity of β-glucosidase (CpBgl) from Coniophora puteana , the structural modification was conducted. The enzyme activity of mutants CpBgl-Q20C and CpBgl-A240S was increased by 65.75% and 58.58%, respectively. These mutants exhibited maximum activity under the same conditions as wild-type CpBgl (65 ℃ and pH 5.0), slightly improved stabilities compared that of the wild-type, and remarkably enhanced activities in the presence of Mn2+ or Fe2+. The V max of CpBgl-Q20C and CpBgl-A240S was increased to 138.18 and 125.14 μmol/mg/min, respectively, from 81.34 μmol/mg/min of the wild-type, and the catalysis efficiency (k cat / K m) of CpBgl-Q20C (335.79 min−1/mM) and CpBgl-A240S (281.51 min−1/mM) was significantly improved compared with that of the wild-type (149.12 min−1/mM). When the mutant CpBgl-Q20C were used in the practical degradation of different biomasses, the glucose yields of filter paper, corncob residue, and fungi mycelia residue were increased by 17.68%, 25.10%, and 20.37%, respectively. The spatial locations of the mutation residues in the architecture of CpBgl and their unique roles in the enzyme-substrate binding and catalytic efficiency were probed in this work. These results laid a foundation for evolution of other glycoside hydrolases and the industrial bio-degradation of cellulosic biomass in nature. [Display omitted] • Improved β-glucosidase mutants were obtained via site-directed mutagenesis. • The activity of CpBgl-Q20C and CpBgl-A240S was increased by 65.75% and 58.58%. • The molecular mechanism of improved activity was preliminarily elucidated. • CpBgl-Q20C and CpBgl-A240S effectively promoted biomass cellulose degradation. [ABSTRACT FROM AUTHOR]
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- 2023
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7. Enhanced catalytic performance of transition metal-doped Cr2O3 catalysts for propane dehydrogenation: A microkinetic modeling study.
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Zhang, Rui, Chang, Qing-Yu, Ma, Fang, Zeeshan, Muhammad, Yang, Ming-Lei, Sui, Zhi-Jun, Chen, De, Zhou, Xing-Gui, and Zhu, Yi-An
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CATALYSTS , *CATALYSIS , *DEHYDROGENATION , *CATALYTIC activity , *PROPANE , *TRANSITION metal oxides , *TRANSITION metal catalysts - Abstract
[Display omitted] • Substitution of transition metals for Cr increases the acidity of the adjacent O. • Linear scaling relations are established to identify the PDH activity descriptor. • High propylene selectivity of the M 1 -Cr 2 O 3 catalysts is achieved. • Cu 1 -Cr 2 O 3 is predicted to be the best catalyst for PDH among the 13 doped Cr 2 O 3. The catalytic behavior of M 1 -Cr 2 O 3 (M = Mn-Cu, Ru-Ag, and Os-Au) in propane dehydrogenation (PDH) has been studied by employing microkinetic modeling combined with results from periodic DFT + U calculations. Calculated results indicate that most of the single atoms concerned can be stably present on the Cr 2 O 3 surface. The adsorption energy calculations and Bader charge analysis demonstrate that the acidity of the O sites adjacent to the M sites would be enhanced upon doping, which in turn strengthens the atomic H adsorption and the co-adsorption of various PDH species. The surface H formation energy is identified as the reactivity descriptor for PDH over the M 1 -Cr 2 O 3 catalysts, and a volcano curve of the PDH activity is obtained. By calculating the difference between the propylene dehydrogenation and desorption barriers, it is found that some M 1 -Cr 2 O 3 catalysts show improved selectivity towards propylene, as compared to Cr 2 O 3. Comparison between the formation barriers of H 2 and H 2 O reveals that single-atom doping has no apparent negative effect on the catalytic stability of the Cr 2 O 3 surface. The Cu 1 -Cr 2 O 3 catalyst is finally identified as the most promising catalyst for PDH among the 13 M 1 -Cr 2 O 3 catalyst candidates, considering the catalytic activity, selectivity, stability, and cost. [ABSTRACT FROM AUTHOR]
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- 2022
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8. Au/uncalcined TS-1 catalysts for direct propene epoxidation with H2 and O2: Effects of Si/Ti molar ratio and Au loading.
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Feng, Xiang, Duan, Xuezhi, Yang, Jia, Qian, Gang, Zhou, Xinggui, Chen, De, and Yuan, Weikang
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GOLD catalysts , *PROPENE , *EPOXIDATION , *CHEMICAL stability , *ACTIVATION (Chemistry) , *CATALYTIC activity - Abstract
For direct propene epoxidation with H 2 /O 2 , TS-1 with blocked micropores (TS-1-B) is recognized as an attractive support for Au catalysts with enhanced stability and activity by suppressing the deactivation caused by micropore blocking. In this work, as a consecutive effort, effect of Si/Ti molar ratio of TS-1-B on catalytic performance is investigated. It is shown that the optimum Si/Ti molar ratio is 40. In other words, both lower and higher ratios are unfavorable for the formation of propylene oxide, which are possibly attributed to the presence of extra-framework Ti species and the difficult transmission of hydroperoxide species from Au surface to nearby Ti sites, respectively. Based on this, effect of Au loading on catalytic performance is further examined. When the Au loading is 0.13 wt%, the catalyst shows not only high PO formation rate of 158 g PO h −1 kg Cat −1 comparable to the reported best activity without adding promoters, but also significantly enhanced stability at 200 °C over 30 h. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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9. Improvement of catalytic performance of endoglucanase CgEndo from Colletotrichum graminicola by site-directed mutagenesis.
- Author
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Zhou, Hai-Yan, Yi, Xiao-Nan, Chen, Qi, Zhou, Jian-Bao, Li, Shu-Fang, Cai, Xue, Chen, De-Shui, Cheng, Xin-Ping, Li, Mian, Wang, Hong-Yan, Chen, Kai-Qian, Liu, Zhi-Qiang, and Zheng, Yu-Guo
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SITE-specific mutagenesis , *COLLETOTRICHUM , *MUTAGENESIS , *CATALYTIC activity , *PICHIA pastoris , *CELLULASE - Abstract
In order to improve the catalytic efficiency of cellulase for more effective utilization of lignocellulose, a novel endoglucanase (CgEndo) from Colletotrichum graminicola was expressed by Pichia pastoris X33 and modified by site-directed mutagenesis. Two mutants, Y63S and N20D/S113T, with 62.31% and 57.14% increased enzyme activities were obtained, respectively. On this basis, their biochemical properties, kinetic parameters, structural information as well as the application in biomass degradation were investigated and compared with the wild-type CgEngo. The results indicated that the mutation Y63S and N20D/S113T resulted in an improvement of proximity between enzyme and substrate through conformational changes of the catalytic region, which might contribute to the higher enzyme activities and catalysis efficiency (K cat / K m) of Y63S and N20D/S113T. These findings laid important foundation for the further engineering of this endoglucanase and practical application in efficient degradation of cellulosic biomass in nature. [Display omitted] • Improved endoglucanase CgEndo mutants were obtained via site-directed mutagenesis. • The activities of Y63S and N20D/S113T were 62.31% and 57.14% increased, respectively. • Y63S and N20D/S113T could effectively promote natural cellulose degradation. [ABSTRACT FROM AUTHOR]
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- 2022
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10. Effect of Ag on the control of Ni-catalyzed carbon formation: A density functional theory study
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Xu, Yue, Fan, Chen, Zhu, Yi-An, Li, Ping, Zhou, Xing-Gui, Chen, De, and Yuan, Wei-Kang
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SILVER compounds , *NICKEL catalysts , *DENSITY functionals , *DOPED semiconductors , *CHEMICAL kinetics , *CATALYTIC activity - Abstract
Abstract: First-principles calculations have been performed to examine the effect of doped Ag on the kinetics of Ni-catalyzed methane dissociation and coke formation. The close-packed Ag/Ni(111) and stepped Ag/Ni(211) surfaces as well as the defect facets with step sites blocked by Ag or C atoms are constructed to investigate the role of the coordinatively unsaturated sites in the catalytic performance of Ni nanoparticles. The most stable CH x (x =0–4) adsorption configurations and transition states for methane dissociation have been identified on both Ni and Ag/Ni surfaces. The calculated results indicate that the activation energy for methane dissociation is increased with the Ag coverage on Ni(111), and the C atoms deposited on the catalyst surface can be readily separated into small islands by Ag. On Ni(211) Ag atoms are predicted to bind preferentially to the middle-step sites which act as the nucleation center for the growth of filamentous carbon and therefore have the potential to prevent catalyst particles from being destroyed. Meanwhile, as the energy barrier for methane dissociation on the Ag-blocked Ni(211) surface is even higher than that on pure Ni(111), the active center is transferred from the stepped surface to the close-packed surface. These findings provide a rational interpretation of the experimental observations that Ag/Ni catalyst exhibits lower catalytic activity towards steam methane reforming but high resistance to coke deposition. [Copyright &y& Elsevier]
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- 2012
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