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In order to improve the luminous properties of high-power white light-emitting diodes (WLEDs), we proposed a facile preparation of patterned phosphor-in-glass (PiG) in which yellow Y 3 Al 5 O 12 :Ce 3+ (YAG:Ce 3+ ) and red CaAlSiN 3 :Eu 2+ (CASN:Eu 2+ ) phosphor parts are separated. The patterned PiGs with sector piece and concentric ring phosphor geometries were prepared by screen-printing and low-temperature sintering. Experimental results indicated that LED modules packaged by the patterned PiGs yield high luminous efficacy and excellent color quality owing to the reducing reabsorption of yellow emission by red phosphor. In addition, the angular color uniformity (ACU) of LED modules with the ring patterned PiGs are better than those of LED modules with the piece patterned PiGs. It is also discovered that the luminous efficacy and corresponding correlated color temperature (CCT) of LED module packaged by the piece/ring patterned PiG are decreased with the increasing of piece/ring number. [ABSTRACT FROM AUTHOR]

The phosphor-in-glass (PiG) coating was fabricated via multilayer screen-printing and low-temperature sintering. The PiG coating consisted of Eu 2 O 3 -doped P 2 O 5 -ZnO-B 2 O 3 (PZB) glass, Y 3 Al 5 O 12 :Ce 3+ (YAG:Ce) yellow phosphor, and CaAlSiN 3 :Eu 2+ (CASN:Eu) red phosphor. Eu 2 O 3 and CASN:Eu were used to provide red emission for tunable chromaticity of white light-emitting diodes (LEDs), and surprisingly, the luminous efficacy was also enhanced. The impact of the variation in the B 2 O 3 content on the PZB glass and the effect of Eu 2 O 3 , YAG: Ce, and CASN:Eu on the luminescent properties of the PiG coating were investigated. The glass matrix with 8 mol% B 2 O 3 showed the lowest transition temperature and a suitable coefficient of thermal expansion. The spectra showed that the coating can be excited by blue light and produce yellow light and red light. The spatial distribution of the PiG coating was inspected by scanning electron microscopy, and it was observed that only a low erosion of phosphor by the glass matrix occurred. Furthermore, the white LEDs devices were constructed with the PiG coating on the blue LED chips. This method showed a decreased correlated colour temperature of 5137, a increased colour rendering index of 82.8 and an improvement in the luminous efficacy. The PiG coating for tunable chromaticity and enhanced luminous efficacy of white LEDs shows potential for application. [ABSTRACT FROM AUTHOR]