Search

Nickel ferrite owns a lot of advantages as electrode materials for supercapacitor, such as high energy density and excellent theoretical capacity. Whereas, the electrochemical performances of NiFe 2 O 4 in terms of rate performance and cycle stability are not satisfactory due to the low conductivity. While carbon fiber is a kind of material with high conductivity. Hence, NiFe 2 O 4 @ slit modified hollow carbon fiber is obtained through the coaxial electrospinning method. The slits on hollow carbon fibers are beneficial to the contact of inner NiFe 2 O 4 nanoparticles with electrolyte. Results of electrochemical tests show that at a current density of 1 A/g, the specific capacitance of NiFe 2 O 4 @ slit modified hollow carbon fiber is calculated to be 225.4 F/g, higher than that of NiFe 2 O 4 nanoparticles of 134.8 F/g. Moreover, a better cycle and rate performances (100 % vs 80 %; 71.9 % vs 47.5 %) are achieved. This work displays that slit modified hollow carbon fiber can improve the electrochemical performance of NiFe 2 O 4 efficiently. [Display omitted] • Carbon fibers are introduced to enhance the rate and cycle performances of NiFe 2 O 4. • Slits are obtained utilizing Al 2 O 3 sacrificial hard templates. • Slits are beneficial to the contact of NiFe 2 O 4 and electrolyte. [ABSTRACT FROM AUTHOR]

In the recent years, MXenes (2D transition metal carbides, carbon nitrides and nitrides) and its precursor MAX phases have been widely investigated in electrochemical research. In this research, we successfully prepared a core-shell structured compound——Ti 3 C 2 @Ti 2 SnC/CNFs (MXene@TSC/C) as an anode material for lithium ion battery via electrospinning method. Results showed that this type of compound has a specific capacity of 288.9 mAh·g−1 at the current density of 0.4 A g−1 after 300 cycles, accompany with a retention rate of capacity of 105.4% in the rate performance test. These performances were benefit from the core-shell structured CNFs and Ti 3 C 2 MXenes. This work supported a novel way to improve the electrochemical property of MXene and MAX phases, which was expected to further explored. [ABSTRACT FROM AUTHOR]

A sol-gel method was employed for the synthesis of new High-entropy boride (HEB) powders, (Hf 0.2 Nb 0.2 Cr 0.2 Ta 0.2 Mo 0.2)B 2 , with nanoscale. The as-synthesized powders were obtained at a relatively low temperature of 1650 °C, and had small average particle size of 62.09 nm. X-ray diffraction confirmed that the (Hf 0.2 Nb 0.2 Cr 0.2 Ta 0.2 Mo 0.2)B 2 powders were hexagonal single-phase without any oxide impurities. In particular, electrochemical performance of the (Hf 0.2 Nb 0.2 Cr 0.2 Ta 0.2 Mo 0.2)B 2 powders with multiphase and high-entropy single phase were investigated using a three-electrode system. The improved electrochemical performance of the HEB powders is realized, with 27% higher in specific capacitance compared to the powders with multiphase. The HEB powders electrode exhibits a high capacitance retention of 97.03% after 5000 cycles. [ABSTRACT FROM AUTHOR]

Morphology of transition metal oxide largely affects its electrochemical energy storage properties. This also applies to its composites. In this paper, NiFe 2 O 4 /Graphene nanosheets composites (NFO/GNSs) are successfully prepared by a facile hydrothermal method. NiFe 2 O 4 (NFO) in the sample exhibits a unique nanosheet morphology, vertically arranging on the graphene nanosheets (GNSs). Microscopically, NFO nanosheets interpenetrate on the surface of graphene to form a continuous network structure. The sample exhibits excellent specific capacitance and rate performance. It is worth mentioning that the specific capacitance increases to 140% after 5000 cycles, showing superior cycle stability. This may be due to the conductive network formed by NFO nanosheets and GNSs. Excellent electrochemical performance indicates excellent application prospects of materials in supercapacitor electrodes. Image 1 • Unique NiFe 2 O 4 nanosheets structure with graphene nanosheets was successfully prepared by a hydrothermal method. • NiFe 2 O 4 nanosheets/graphene performed a better specific capacitance, arriving at 464.15 F/g at current density of 1 A/g. • The network structure formed between NiFe 2 O 4 nanosheets and graphene nanosheets provides excellent cycle performance. [ABSTRACT FROM AUTHOR]

Transitional metal nitrides (TMNs) are regarded as comparatively promising electrode materials for supercapacitor due to the high electronic conductivity, good corrosion resistance and special electron structure. Herein, in this work a heterostructure Co 2 N-Ni 3 N nanosheets-nanowires arrays grown on Ni foam (NF) are designed and synthesized by a simple hydrothermal reaction and nitriding treatment. The prepared Co 2 N-Ni 3 N/NF nanoarrays has a high electrical conductivity, abundant surface active sites, charge transfer channels and the synergy effect between each component, which makes it exhibit outstanding electrochemical performance. Electrochemical test results revealed that the areal capacitance of Co 2 N-Ni 3 N/NF was 2.17 F cm−2 at 1 mA cm−2 using a three-electrode system in 1 M KOH. Meanwhile, when the current density increases to 20 mA cm−2, it can still retain 62.21% of the original capacitance, suggesting a good rate capability. In addition, in two-electrode test with Co 2 N-Ni 3 N/NF as the positive electrode and activated carbon as the negative electrode, a maximum energy density of 145.65 μWh cm−2 is shown when the power density is 0.75 mW cm−2. And it has 85.90% capacitance retention after 5000 cycles. [Display omitted] • Unique Co 2 N-Ni 3 N nanoarray heterostructure was successfully synthesized. • Co 2 N-Ni 3 N/NF achieves an areal capacitance 2.17 F cm-2 at current density of 1 mA cm-2. • The Co 2 N-Ni 3 N/NF // AC exhibits good electrochemical performance in two-electrode tests. [ABSTRACT FROM AUTHOR]

Core-shell hierarchical structured composites have demonstrated great advantages in numerous energy storage devices. In particular, structured composites with rationally structural components and controllable morphology are the most effective in enhancing electrochemical properties. In this work, MnO 2 @NiCo 2 O 4 @Ti 3 SiC 2 /CC (carbon cloth) core-shell hierarchical structured composites were designed and successfully synthesized via electrospinning followed by a two-step hydrothermal reaction. The Ti 3 SiC 2 /CC nanofibers and core-shell nanoarrays were able to improve the specific capacitance and cycling stability. In the three-electrode system, the specific capacitance of MnO 2 @NiCo 2 O 4 @Ti 3 SiC 2 /CC was observed as 1938.2 F/g at a current density of 1 A/g, while the rate capability retention was observed as 81.7% between 1 and 10 A/g. Furthermore, a superior cycling stability was observed following 5000 cycles with a specific capacitance retention rate of 55.4%. Employing MnO 2 @NiCo 2 O 4 @Ti 3 SiC 2 /CC as the all solid-state supercapacitor positive electrode exhibited a high energy density of 58.0 W h/kg at the power density of 800 W/kg. Results demonstrate the potential of the MnO 2 @NiCo 2 O 4 @Ti 3 SiC 2 /CC as an electrode material with phenomenal electrochemical properties for supercapacitors. [ABSTRACT FROM AUTHOR]

Abstract Bimetallic carbides with high activity and stability are promising potential materials for energy-storage application. However, the researches about Fe 2 MoC as electrode material on supercapacitors are comparatively weak, and the processing methods of Fe 2 MoC were also relatively few. Herein, a simple hydrothermal method, combining with carbothermic treatment at 900 °C, is explored to fabricate molybdenum iron carbon (Fe 2 MoC) successfully. Chitosan is not only a carbon source, but also a chelating agent to form bimetallic carbide rather than two separated monometallic carbide during the high-temperature treatment. Fe 2 MoC nanoparticles possessing large specific surface, high activity, stability and small resistance were the promising candidate for electrode material. Systematic electrochemical characterizations have verified the Fe 2 MoC (chitosan as carbon source) possesses a specific capacitance (97.7 F/g at a current density of 0.5 A/g), high rate capability (97.0% capacitance retention from 0.5 to 10 A/g) and cycling stability (83.9% capacitance retention after 1000 cycles) in 1 M KOH. In addition, it offers the energy density of 6.74 Wh/kg at a power density of 21 kW/kg. In view of the low-cost and excellent performance, Fe 2 MoC will hold great promise in energy-storage field for supercapacitors. [ABSTRACT FROM AUTHOR]

As the precursor of MXenes (2D transition metal carbides, carbon nitrides and nitrides), MAX phase materials have attracted ever-increasing attention in electrochemical applications. In this work, we have successfully hybridized a MAX phase, Ti 2 SnC, with various ratios of carbon nanofibers (CNFs) via electrospinning. The results show that the Ti 2 SnC/CNFs compounds possess a stable lithium ion storage ability as an anode material, reaching a stable specific capacity of up to 367.5 mAh·g−1 after 500 charge/discharge cycles at the current density of 1.0 A g−1, which are drastically better than some other MAX phase materials such as Ti 3 SiC 2 and Nb 2 SnC. This strategy provides a new pathway for the improvement of the electrochemical stability of MAX phase, which has a wide application prospect. • Ti 2 SnC/CNFs was successfully prepared by an electrospinning method. • CNFs retard the volume expansion of Ti 2 SnC during the charge/discharge process. • Ti 2 SnC/CNFs performed stable lithium ion capacitance (367.5 mAh·g−1 at 1.0 A g−1). [ABSTRACT FROM AUTHOR]

MAX phase materials, the precursors of MXenes (2D transition metal carbides, carbon nitrides, and nitrides), have become increasingly popular in electrochemical applications. In this study, we have successfully prepared Ti 2 SnC with high lithium capacity via the in-situ formation of SnO 2. Results show that there are TiC nanowhiskers and SnO 2 inside the Ti 2 SnC MAX calcined at 800 ℃, and the initial specific capacity could reach 377 and 371 mAh·g−1 at high current densities of 400 mA·g−1 and 1.0 A·g−1, respectively. These values are higher than those of most MAX phase materials reported in previous studies, such as Ti 3 SiC 2 and Nb 2 SnC, but the stability and rate performance are inferior, which is a direction for the future. This paper provides a new pathway for the application of MAX phases in electrochemistry, which has more in-depth application prospects. ● Ti 2 SnC with in-situ formation of SnO 2 was successfully prepared by a calcination method. ● The Ti 2 SnC layered structure slows down the volume expansion of in-situ prepared SnO 2. ● This anode material performed a better specific capacitance, arriving at 377 mAh/g at the current density of 1.0 A/g. [ABSTRACT FROM AUTHOR]

The layered transition metal oxides are an essential class of cathode materials in sodium-ion batteries. However, the capacity decay mechanisms of many materials at a wide voltage window are still ambiguous. Therefore, research on the intrinsic structure of materials at the electronic or atomic level is of great significance to unlock the potential of more materials. In this study, a new family of layered NaNi 0.45 Mn 0.3 Ti 0.2 M 0.05 O 2 (M = Nb/Mo/Cr) has been demonstrated to combine high specific capacity (NaNi 0.45 Mn 0.3 Ti 0.2 Cr 0.05 O 2 , 12 mA g−1, 185.7 mAh g−1, 2-4.2 V) with preferable Na+ insertion/extraction activity (1920 mA g−1, 111.2 mAh g−1). The participation of Ni2+/Ni3+ and Cr3+/Cr4+/Cr6+ in the redox reaction upon cycling significantly contributes to the superior specific capacity, and the diffusion kinetics calculation indicates that the substitution of Cr for Ni can create a more suitable path with a low energy barrier for Na+ movement, which is particularly crucial for the rate performance. Besides, the unfavorable cycling stability is affected by the distortion of the crystal structure, suggesting that the Jahn-Teller effect of Mn3+/Ni3+ and the second-order Jahn-Teller effect of Nb5+/Mo6+ (d0 transition metal) together with Cr6+ migration caused by disproportionation of Cr4+ have inescapable responsibilities. Additionally, the reversible phase transition between the O3 and P3 phases upon Na+ insertion/extraction at a wide voltage window is identified by in situ XRD measurements and verified to be the key factor of the high coulombic efficiency for NMTCr. An in-depth understanding of NMTNb and NMTMo can provide new insights for material design and exploitation. The composition-structure-property relationships behind the electrochemical performance can be comprehended profoundly by coupling the experimental verification with density functional theory calculations. • A new family of layered NaNi 0.45 Mn 0.3 Ti 0.2 M 0.05 O 2 (M = Nb/Mo/Cr) has been prepared. • The participation of Ni2+/Ni3+ and Cr3+/Cr4+/Cr6+ contributes greatly to the capacity. • The substitution of Cr provided a suitable path with low energy barrier for Na+ movement. • The Jahn-Teller effect of Mn3+/Ni3+ and second-order JT effect of Nb5+/Mo6+ are discussed. [ABSTRACT FROM AUTHOR]

An innovative and convenient method has been performed to stabilize the surface of O3-type NaNi 0.45 Mn 0.3 Ti 0.2 Zr 0.05 O 2 composited electrode by ultrathin MgO film. There are few reports on the modification on the fabricated electrode instead of the active material powder, especially by radio frequency magnetron sputtering. Besides, the surface stability and capacity retention of MgO coated cathode are superior compared to the bare one under the high rate. The protective effect could physically enhance electrochemical performance because the MgO coating has been identified strictly. Three main reasons are discovered by investigating the mechanisms. Firstly, the MgO layer suppresses the dissolution of the active material into electrolyte; this might be the origin for more stable electrode structure. Secondly, the MgO layer boosts sodium-ion and electron transport owing to its location of the deposition. Finally, the appropriate thickness of MgO can minimize transmission resistance and SEI formation. Particularly, the half-cell constructed with NaNi 0.45 Mn 0.3 Ti 0.2 Zr 0.05 O 2 –MgO cathode delivers a good rate performance (80.3 and 70.3 mA h g−1 at 1200 and 1920 mA g−1) and a long cycle life (71.6 mA h g−1 at 240 mA g−1 for 300 cycles) when sputtering time is 10 s; meanwhile, the reversible discharge capacity (140.7 mA h g−1 at 12 mA g−1) with a cut-off voltage of 2–4 V is also a considerable achievement. The work provides a broad idea to apply MgO as a protective coating. • MgO film is performed via magnetron sputtering on NaNi 0.45 Mn 0.3 Ti 0.2 Zr 0.05 O 2 electrode. • The surface stability and capacity retention of MgO coated cathode are superior at high rate. • MgO layer boosts sodium-ion and electron transport owing to its location of deposition. • The appropriate thickness of MgO can minimize transmission resistance and SEI formation. • The NaNi 0.45 Mn 0.3 Ti 0.2 Zr 0.05 O 2 –MgO cell delivers 80.3 and 70.3 mA h g−1 at 1200 and 1920 mA g−1. [ABSTRACT FROM AUTHOR]

Due to the low cost and abundance of sodium, sodium-ion batteries (SIBs) show great potential as energy storage devices. As far as the current research is concerned, cathode materials are still the bottleneck for boosting the performance of SIBs. O3-type layered NaNi 0.5 Mn 0.5 O 2 is considered as an important cathode material of SIBs, but its irreversible phase transition, poor stability in air, and sluggish kinetics usually lead to reduced capacity, poor rate performance and high cost for material storage, which largely limit the large-scale application. Herein, a remarkable O3-type layered material NaNi 0.5-x Mn 0.3 Ti 0.2 Zr x O 2 (NaNMTZ, x = 0.02, 0.05), with stable phase structure has been synthesized by the solid-phase method. The partial substitution of electrochemical inactive Ti/Zr brings about higher electronic delocalization and entropy of mixing leading to enhanced structural stability. In addition, the enlarged interlayer spacing and good conductivity contribute to better rate capability. The micro-nano structure leads to faster Na+ diffusion rates and shorter diffusion paths for both ions and electrons. Therefore, NaNi 0.45 Mn 0.3 Ti 0.2 Zr 0.05 O 2 exhibits an initial reversible capacity of 141.4 mAh g−1 with a coulombic efficiency of 98.8% and remarkable capacity retention of 70% after 200 cycles at 0.05C, presenting better electrochemistry performance than the conventional NaNi 0.5 Mn 0.5 O 2. This study provides a new angle to design high capacity cathode materials with high rate capability and cycling stability through crystal lattice modulation. Image 1 • A remarkable O3-type layered NaNi 0.45 Mn 0.3 Ti 0.2 Zr 0.05 O 2 is designed as cathode material for sodium ion batteries. • The structural stability and rate performance of NaNi 0.45 Mn 0.3 Ti 0.2 Zr 0.05 O 2 are superior. • The higher electronic delocalization and better conductivity of NaNi 0.45 Mn 0.3 Ti 0.2 Zr 0.05 O 2 are provided. • The difference value about entropy of mixing between NaNi 0.5 Mn 0.5 and NaNi 0.45 Mn 0.3 Ti 0.2 Zr 0.05 O 2 is calculated. • The enlarged interlayer spacing and micro-nano structure contribute to the high rate capability. [ABSTRACT FROM AUTHOR]

Bimetallic carbides have aroused wide attention for energy-storage applications recently. In this work, one-dimensional Fe 2 MoC/CNFs (Fe 2 MoC/C nanofibers) are successfully synthesized via a facile electrospinning method for the first time. To obtain the most integrated structure between the Fe 2 MoC nanoparticles and carbon nanofibers, we explore the optimal heating rate during the carbonization treatment. Fe 2 MoC/CNFs exhibits an integrated one-dimensional structure under 800 °C with a heating rate of 5 °C/min. As revealed in the experimental results, Fe 2 MoC/CNFs possesses a high specific surface area of 196.9 m2/g, a high specific capacitance of 347.8 F/g at the current density of 1 A/g, an excellent rate capability of 91% capacitance retention from 1 A/g to 40 A/g, and shows superior cycling stability with the capacitance retention of about 85.6% and Coulombic efficiency of about 100% after 5000 cycles. An asymmetric supercapacitor coin-cell device using Fe 2 MoC/CNFs as the positive electrode displays an energy density of 14.5 Wh/kg at a power density of 300 W/kg and an outstanding cycling life of 93% retention after 5000 cycles. The impressive electrochemical performance indicates that the Fe 2 MoC/CNFs composite is a promising material for efficient supercapacitors. Image 1 • Fe 2 MoC nanofibers can be prepared via a facile electrospinning method. • Fe 2 MoC/CNFs-5 exhibits a superior rate capability and cycle stability. • ASC coin-cell device shows a promising energy and power density. [ABSTRACT FROM AUTHOR]