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Metal selenides of were synthesized for various weight percentage of Mn (0.05, 0.1, and 0.15 wt %). MnSe 2 -CoSe 2 emerged as the novel-energy storing material for the supercapacitor application and guaranteed the improved electrochemical performance in asymmetric configuration. As prepared metal selenide composite was explored for standard characterization studies. XRD reveals the highly crystalline in nature of the as prepared samples. Se bonding with Mn-Co is confirmed from the sharp peak obtained at 470 cm−1. The chemical elemental composition was evaluated by the XPS, hence the characterization outcome confirm the successful growth of the material. The specific capacitance of Mn3 (0.15 wt %) is 373 Fg-1 in 1 M KOH; Mn1 (0.05 wt %-184 Fg-1) and Mn2 (0.1 wt %-295 Fg-1). The electrode shows excellent capacity retention of 95.86% at 5 Ag-1 even after 5000 cycles. Furthermore, asymmetric configuration of Mn3 (0.15 wt %)//AC device delivered significant value of power density even at high energy density. Thus, the as-prepared asymmetric device easily illumines the green light emitting diode which indicates the Mn3 (0.15 wt %) is an acceptable product. [ABSTRACT FROM AUTHOR]

Glioblastomas are malignant tumors of the central nervous system hallmarked by subclonal diversity and dynamic adaptation amid developmental hierarchies. The source of dynamic reorganization within the spatial context of these tumors remains elusive. Here, we characterized glioblastomas by spatially resolved transcriptomics, metabolomics, and proteomics. By deciphering regionally shared transcriptional programs across patients, we infer that glioblastoma is organized by spatial segregation of lineage states and adapts to inflammatory and/or metabolic stimuli, reminiscent of the reactive transformation in mature astrocytes. Integration of metabolic imaging and imaging mass cytometry uncovered locoregional tumor-host interdependence, resulting in spatially exclusive adaptive transcriptional programs. Inferring copy-number alterations emphasizes a spatially cohesive organization of subclones associated with reactive transcriptional programs, confirming that environmental stress gives rise to selection pressure. A model of glioblastoma stem cells implanted into human and rodent neocortical tissue mimicking various environments confirmed that transcriptional states originate from dynamic adaptation to various environments. [Display omitted] • Five spatially distinct transcriptional programs are identified in glioblastomas • Hypoxia induces defined transcriptional and genomic responses, including CNAs • Immunosuppressive tumor-myeloid cell interactions are enhanced in segregated niches • Non-stress environments support subtype transition towards developmental stages Ravi et al. employ spatially resolved multi-omics in glioblastoma samples and identify segregated niches hallmarked by immunological and metabolic stress factors. These spatial niches are influenced by the tumor microenvironment and reflect transcriptional adaptations to inflammatory or metabolic stimuli and recapitulate neural developmental stages. [ABSTRACT FROM AUTHOR]

• A polycrystalline with dual phase in nature of cubic and monoclinic structure was observed. • The largest and lowest energy gap values are found to be 4.03 eV and 2.44 eV for Gd and metal copper. • White sponge, nanorods, nanoneedles and nanorice shaped morphology has observed by FESEM. • The MIS diode was achieved a minimum ideality factor values of 5.34. • The excellent opto-electronics properties of the developed photodetectors make it suitable for future nano-electronics. Here we are reporting the development of Gadolinium based copper oxide nanocomposites via a cost-effective low-temperature co-precipitation process. X-ray diffraction study approves the dual phase polycrystalline cubic and monoclinic structure with predominant orientations along (2 2 2) and (0 0 2) directions. A strong &sharp peak is positioned at ~512 cm−1in FT-IR is assigned to metal oxide (Cu-O/Gd-O) network terminal stretching & phonon band. Absorption study reveals strong absorption peaks for the samples prepared from pure copper (Cu) and gadolinium (Gd), however poor absorption was noticed from mixed CuO-Gd2O 3 nanocomposites.The largest and lowest energy gap values are found to be 4.03 eV and 2.44 eV for Gd and metal copper, respectively. White sponge, nanorods, nanoneedles and nanorice shaped morphology has observed from FESEM analysis. X-ray photoelectron spectroscopy (XPS) survey spectrum unveils the essential elements like Cu, Gd and oxygen. The peak fitting of Gd4d exhibits two major peaks at 143.6 and 155.8 eV binding energies correspond to spin orbit doublet splitting of 12.2 eV between 4d 5/2 and 4d 3/2 , respectively. From I-V study, we observed that the presence of CuO-Gd 2 O 3 nanocomposites at p-Si/Al interface improved the performance of the MIS diode. The excellent opto-electronics properties of the developed photo-detectors make it suitable for future nano-electronics. [ABSTRACT FROM AUTHOR]