Search

[Display omitted] • Our approach, for the first time, using melamine nitrate as precursor, sodium borohydride as B source and Na source, by controlling the heating rate and thermal post-treatment, B/Na co-doped porous carbon nitride nanosheets were successfully prepared. • The as-synthesized B/Na co-doped porous g-C 3 N 4 nanosheets obtained wonderful photocatalytic hydrogen generation properties, AQE value of 9.39% under the radiation of 430 nm wavelength, and high-efficiency photocatalytic removal of TC performance. • The energy saving LED is used as the light source for hydrogen production. g-C 3 N 4 has attracted wide concern owing to its function of photocatalytic degradation of pollutants and H 2 production. However, the bulk carbon nitride (BCN) has many shortcomings, such as poor light absorption ability, short life of photogenerated electrons and few reactive sites. In this study, element doping and morphology control strategies were used to enhance their activity. B/Na co-doped porous carbon nitride nanosheets (PNCN-BNa-3) were successfully prepared by controlling the heating rate and thermal post-treatment using melamine nitrate as precursor, sodium borohydride as B source and Na source. Thanks to the synergistic effect of the porous nanosheets structure and B/Na co-doped, the B/Na co-doped porous g-C 3 N 4 nanosheets obtained wonderful photocatalytic hydrogen generation properties (5971.51 μmol·g−1·h−1), AQE value of 9.39% under the radiation of 430 nm wavelength, and high-efficiency photocatalytic removal of TC performance (the removal efficiency reached 78.39% in 30 min). This provides a new idea for the preparation of semiconductor photocatalysts with good property. [ABSTRACT FROM AUTHOR]