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Many nations have pledged to reach carbon neutrality by 2050. Embarking on the decarbonization journey, they posited geological carbon storage (GCS) as a pivotal technology within the carbon capture, utilization, and storage (CCUS) framework. The CCUS chain operates to reduce "hard-to-abate" emissions at key sectors by capturing carbon dioxide (CO 2), reusing it, transporting it, or disposing of it via injection into underground geological formations for permanent storage. Despite the global success of GCS ventures, mainly driven by the oil and gas industry, GCS initiatives are still in their early stages in several developing countries. In Brazil, for instance, a full setup covering precise storage capacity databases, potential CCUS clusters, national regulatory structure, and auxiliary computer-aided engineering is underway. Intended to push the frontier in the latter subject, this paper introduces mathematical models for qualifying underground CO 2 storage sites. Our research explores a family of multivariate functionals endowed with underlying reservoir features and distinct weighting functions, thus envisioning two primary objectives. Firstly, it clarifies non-linear interactions between rock and fluid properties using quality indicators. Secondly, it evaluates geographical regions considering structural traps/caprocks settings. Backed by the Matlab Reservoir Simulation Toolbox (MRST) capabilities, the methodology is a subsidiary resource for identifying suitable injection and storage sites. A case study using the UNISIM-I-D model generated dozens of volumetric quality maps that point to unique potential storage sites. Numerical simulation experiments of injection comparing legacy and novel wells reveal storage surpluses improved by up to 50%. The paper seeks to establish foundational knowledge in GCS efficiency for general underground settings. One expects that these outcomes leverage well-repurposing perspectives and stimulate field appraisal actions to scale up GCS projects both in Brazil and worldwide. • Introduction of a family of mathematical functionals for site qualification. • Trap analysis and supercritical gas injection over a Brazilian offshore reservoir model. • Comparison of storage surplus in theoretically-proposed and legacy well locations. [ABSTRACT FROM AUTHOR]

In this study, projections and current status of municipal solid waste generation worldwide and its collection, final destination, and waste-to-energy technologies are reviewed. Firstly, an overview of waste generation worldwide is presented comparing income levels and the material composition of residues in several regions. This paper focused on contrasting Brazil and Portugal in terms of waste production and its management from generation to disposal or treatment. Furthermore, it is presented a summary of leading waste-to-energy technologies such as incineration, anaerobic digestion, gasification, pyrolysis, co-combustion, co-gasification, among others. Technical aspects of these thermo-chemical, biological, and physic-chemical processes for the production of biofuels such as biogas, syngas, biodiesel, and hydrogen-enriched gases are presented. Additionally, current aspects of the waste-to-energy market are exposed regarding the major players, investments, and expectations for the future of this activity with the elaboration of SWOT analyses. Finally, a review of greenhouse gases emissions worldwide is presented, specifically from Brazil and Portugal, as well as some consequences of these pollutant gases on the society and the environment and which are the main technologies for carbon dioxide capturing and sequestration as promising solutions for lower pollutant gases concentration in the atmosphere. This review paper aims to provide information for the management of municipal solid waste in Brazil and Portugal considering the mutual objective of meeting sustainable development goals. [ABSTRACT FROM AUTHOR]

Enhanced silicate rock weathering for long-term carbon dioxide sequestration has considerable potential, but depends on the availability of suitable rocks coupled with proximity to suitable locations for field application. In this paper, we investigate the established mining industry that extracts basaltic rocks for construction from the Paraná Basin, Sao Paulo State, Brazil. Through a Life Cycle Assessment, we determine the balance of carbon dioxide emissions involved in the use of this material, the relative contribution of soil carbonation and enhanced weathering, and the potential carbon dioxide removal of Sao Paulo agricultural land through enhanced weathering of basalt rock. Our results show that enhanced weathering and carbonation respectively emit around 75 and 135 kg carbon dioxide equivalent per tonne of carbon dioxide equivalent removed (considering a quarry to field distance of 65 km). We underline transportation as the principal process negatively affecting the practice and uncover a limiting road travel distance from the quarry to the field of 540 ± 65 km for carbonation and 990 ± 116 km for enhanced weathering, above which the emissions offset the potential capture. Regarding Sao Paulo State, the application of crushed basalt at 1 t/ha to all of the State's 12 million hectares of agricultural land could capture around 1.3 to 2.4 Mt carbon dioxide equivalent through carbonation and enhanced weathering, respectively. This study suggests a lower sequestration estimate than previous studies and emphasizes the need to consider all process stages through a Life Cycle Assessment methodology, to provide more reliable estimates of the sequestration potential of greenhouse gas removal technologies. • First assessment of the burdens associated with enhanced weathering and carbonation. • Transportation of the material greatly impacts the sequestration potential. • The quarry to field offsetting distance is 550 ± 65 km for carbonation. • On Sao Paulo average, the practice emit 0.110 kg CO 2 eq per kg of CO 2 removed. • The setup burdens of the practice reduce previous sequestration estimates. [ABSTRACT FROM AUTHOR]

Due to its low global share of direct energy consumption and greenhouse gas emissions (1–2%), the implications of technological transitions in the agricultural and forestry sector on the energy system have been overlooked. This paper introduces the Agriculture and Land Use Sector module part of the ModUlar energy System Environment (MUSE), a novel energy system simulation model. The study presents a generalisable method that enables energy modellers to characterise agricultural technologies within an energy system modelling framework. Different mechanisation processes were characterised to simulate intensification/extensification transitions in the sector and its wider implications in the energy and land use system aiming at providing reliable non-energy outputs similarly to those found in dedicated land use models. Additionally, a forest growth model has been integrated to explore the role of reforestation alongside decarbonisation measures in the energy system in achieving carbon mitigation pathways. To illustrate the model's capabilities, Brazil is used as case study. Outputs suggest that by 2030 under a 2 °C mitigation scenario, most of Brazil agricultural production would move from 'transitional' to 'modern' practices, improving productivity and reducing deforestation rates, at the expense of higher energy and fertiliser demand. By mid-century Brazil has the potential to liberate around 24.4 Mha of agricultural land, where large-scale reforestation could have the capacity to sequester around 5.6 GtCO 2 , alleviating mitigation efforts in the energy system, especially reducing carbon capture and storage technology investments in the industry and power sector. • A novel energy-oriented agriculture and land use systems model has been developed. • Mechanisation levels are characterised using cluster analysis and linear optimisation. • Role of reforestation alongside measures in the energy sector in Brazil are studied. • By 2050, modern mechanisation could represent 54–63% of agricultural production. • Brazil has the potential to sequester around 5.6 GtCO 2 through reforestation. [ABSTRACT FROM AUTHOR]

• The questionnaire assessed environmental awareness and knowledge about CCS technology. • The interviews were conducted using a face-to-face approach. • A structured research was employed using an ordinal qualitative scale. • Respondents were aware of the climate change. • Climate change mitigation actions are not a priority for respondents. Carbon Capture and Storage (CCS) is considered an important option to mitigate climate change. However, the success of the new technology does not only depend on engineering practices and techniques but also involves social, political, and economic factors, as well as public acceptance. The discussion about CCS in Brazil is recent and few papers addressing Brazilian public perception and engagement with CCS were found. In this sense, this paper aims to analyze the environmental awareness about climate change and the citizens' perception of CCS technology. A public perception survey was conducted with 800 people in two Brazilian cities. Descriptive statistical techniques combined with hypothesis tests were performed to depict the results and to verify associations between different demographic groups to climate change issues and support for the development of CCS technology in Brazil. The results show that the public is aware of climate change and its consequences. However, despite public support for governmental development and investments in CCS technology, investments to mitigate climate change are not a priority for the population. Only 2% and 5% of interviewed citizens in the cities of São Mateus and Vitória, respectively, considered investments in climate change mitigation as a priority. More than 70% of respondents considered that other social elements, as health, public safety, and job creation, should be prioritized by the Brazilian government. The results suggest that the population needs more information about CCS technology and its impacts. [Display omitted] [ABSTRACT FROM AUTHOR]

• BECCS assessment of a power system based on biomass gasification (BIG-CC), integrated into a sugarcane plant. • CO 2 capture by the pre-combustion route has less impact on the sale of surplus electricity. • The CO 2 mitigation cost was estimated at 60 €/tCO 2 for pre-combustion and 52 €/tCO 2 for post-combustion. • The feasibility of CO 2 capture is impacted by the scale and cost of electricity generation. • Conventional cogeneration systems (CEST) are suggested for the first BECCS units. In order to make feasible the efforts that would limit the rise of Earth's temperature to no more than 2 °C, profound changes are required in the energy systems. In this sense, BECCS are considered instrumental to attain possible negative emissions. This draws attention to the sugarcane industry in Brazil, where it is possible to produce fuel ethanol at a relative low cost and a large amount of relatively cheap biomass is available. This paper is part of a research that aims to study the combined production of liquid fuels and electricity, using sustainable sources of biomass and maximizing carbon capture. Two cases related to an innovative technology were evaluated and in both the capture is based on amine technology: pre-combustion capture of CO 2 from the fuel gas derived from biomass gasification, and post-combustion capture from gas turbine exhaust gases. Information from the scientific literature was used in modelling the systems, as well as estimating energy penalties and costs associated with capturing, transporting and storing CO 2. The results indicate technical feasibility of both capture options, but difficulties in setting the full integration of the power unit (BIG-CC) with the sugarcane mill and the CCS system, due to the high demand for thermal energy as low-pressure steam. The estimated CO 2 abatement cost is in the range 60–71 €/tCO 2 for pre-combustion capture, and 52–63 €/tCO 2 in the case of post-combustion. Feasibility results are impacted by the scale of CO 2 capture (0.82–1.44 MtCO 2 /year), particularly in the pre-combustion case, and the relatively high cost of electricity generation. [ABSTRACT FROM AUTHOR]

Stabilization at concentrations consistent with keeping global warming below 2 °C above the pre-industrial level will require drastic cuts in Greenhouse Gas (GHG) emissions during the first half of the century; net negative emissions approaching 2100 are required in the vast majority of current emission scenarios. For negative emissions, the focus has been on bioenergy with carbon capture and storage (BECCS), where carbon-neutral bioenergy would be combined with additional carbon capture thus yielding emissions lower than zero. Different BECCS technologies are considered around the world and one option that deserves special attention applies CCS to ethanol production. It is currently possible to eliminate 27.7 million tonnes (Mt) of CO 2 emissions per year through capture and storage of CO 2 released during fermentation, which is part of sugar cane-based ethanol production in Brazil. Thus, BECCS could reduce the country’s emissions from energy production by roughly 5%. Such emissions are additional to those due to the substitution of biomass-based electricity for fossil-fueled power plants. This paper assesses the potential and cost effectiveness of negative emissions in the joint production system of ethanol and electricity based on sugar cane, bagasse, and other residues in Brazil. An important benefit is that CO 2 can be captured twice along the proposed BECCS supply chain (once during fermentation and once during electricity generation). This study only considers BECCS from fermentation because capturing such CO 2 is straightforward, thus potentially representing a cost-effective mitigation option for Brazil compared to other alternatives. The assessment shows that fuel prices would increase by less than 3.5% due to the adoption of BECCS from fermentation, while increasing investors’ revenues are sufficient to compensate for the investment required. With appropriate government subsidies, or by sharing BECCS costs between all car fuels and all electricity supplied by hydro and bioelectricity, the increment in ethanol and electricity prices could be less than 1% for the final consumer. Meanwhile it would supply 77.3% of all cars’ fuel (private cars) and 17.9% of all electricity in Brazil. [ABSTRACT FROM AUTHOR]

Soil and climatic conditions allied to advanced forestry technologies have enabled the development of planted forests in some regions of Brazil with some of the highest productivity rates in the world. However, the intense use of agricultural inputs and mechanization of production and wood transportation imply significant environmental impacts, such as the emission of carbon and nitrogen compounds. The purpose of this paper is to compare a model of an Integrated Crop-Livestock-Forestry System with more conventional eucalyptus forestry using a Cleaner Production approach to demonstrate the economic and environmental advantages of such a system. This is based on an environmental, energy, and economic analysis integrating Life Cycle Assessment and Cleaner Production approaches. Life Cycle Inventories consist of primary data obtained from the states of Bahia, Espírito Santo and Minas Gerais in Brazil, in partnership with Forestry Producers and a Forestry Company, which is the largest producer of hardwood pulp in the world. The inventories of conventional short-cycle eucalyptus production systems to supply the Forestry Company were quantified from seedling preparation to harvesting operations. The following production systems were evaluated: Reference system – Planting + Replanting (S1); Planting + Regrowth (S2), and Crop-Livestock-Forestry (S3). The adoption of CP measures in S3 reduced the use of inputs by 35% and increased gross revenue compared to S1. The processes that most contributed to the impact categories analyzed were soil preparation, emissions of inputs used in the field, and mechanized harvesting. However, biogenic carbon sequestration included −783 kg CO 2 eq/m3 of wood for S1. The S2 system had lower impacts compared to S1. Integrated Crop-Livestock-Forestry System - S3 showed a better environmental performance for most of the impact categories analyzed and presented a better financial return compared with S1 and S2. The implementation of the CP measures in S3 provides an immediate payback. Based on the conditions of this study, the CP strategy for silviculture is an economically viable option to increase the net CO 2 sequestration of forest production. This research intends to promote the study of eucalyptus forest production under tropical conditions, using the combined use of LCA and CP approach presented in this study from primary data. The CP and LCA integration provided methodological advances and more detailed information on the environmental performance of short-cycle eucalyptus production by identifying operational practices for the analyzed systems yielding environmental and financial gains. CP proved to be effective in providing information for decision-making at the process level without losing the broader view of the environmental performance of the analyzed product systems. [ABSTRACT FROM AUTHOR]

• The Technology Readiness Levels (TRL) approach is employed for estimating the maturity of CCS System. • A Technology Readiness Assessment (TRA) for a new Carbon Capture and Storage (CCS) concept using offshore salt caverns. • A concept system that allows the monetization of the separated natural gas. • A salt cavern for the storage of 1 billion Sm3 (Standard cubic meter) of a natural gas stream with high CO 2 content. This article presents a Technology Readiness Assessment (TRA) of a new concept called the Salt Cavern Hybrid Subsea Carbon Capture and Storage (CCS) System, which performs all the offshore natural gas and CO 2 separation process with subsequent storage in offshore underground salt caverns. Currently there is a demand for CCS of large quantities of CO 2 associated with CH 4 in the pre-salt offshore oil fields in Brazil. The pre-salt reservoirs have as caprock 2000 m of continuous rock salt. This hybrid system is expected to perform, at the same time, the separation between the natural gas and CO 2 , and Carbon Capture and Storage of CO 2 , allowing the monetization of the separated natural gas. The Technology Readiness Levels (TRL) approach is discussed in this paper for estimating the maturity of the CCS System. The TRL analysis concluded that no technological gaps were identified that would made the project unfeasible and the TRL level enables the project to advance to the field test stage within a reasonably short time horizon. Once implemented it could be one of the largest CCS projects in the world. Also, this paper describes the conceptual design of this hybrid system and presents the results of a TRA showing the methodology that was employed in the process, the technology critical items that were analyzed and the results obtained for each of them and the design of a salt cavern for the storage of 1 billion Sm3 (Standard cubic meter) of a natural gas stream with high CO 2 content. [ABSTRACT FROM AUTHOR]

Brazil is one of the largest producers of eucalyptus that is used for manufacturing pulp and paper; this contributes directly to the issue of carbon emissions. Reforestation of eucalyptus appears as a viable alternative for mitigating these carbon emissions, leveraging their high productivity to that of other leading countries in the market, such as Finland and Sweden. This study aims to develop a model for monitoring and evaluating forest growth and quantifying wood stocks and sequestered carbon. System dynamics was used to simulate forest growth. Forest growth was modeled from eight regions with dissimilar edaphoclimatic characteristics, in the state of Minas Gerais, in Brazil. The model was sensitive enough to the characteristics of the regions, where the difference in forest stocks was 45.1% at the end of 30 years in a harvest cycle of 7 years. It was found that the typical harvest cycle in practice by leading companies did not always yield a higher sequestered CO 2 accumulated stock. By shortening the harvest cycle, it was possible to obtain a gain of up to 21.0% in the sequestered CO 2 stock. [ABSTRACT FROM AUTHOR]

Abstract: This paper presents the results of the EX-Ante Carbon-balance Tool (EX-ACT) application on two rural development projects in Brazil. The analysis provides an estimate of project impact on GHG emissions and C sequestration indicating net mitigation potential: results show that the Santa Catarina Rural Competitiveness Project has the potential to mitigate 12.2Mt CO2e and the Rio de Janeiro Sustainable Rural Development Project 0.85Mt CO2e. Both projects are successful at promoting activities aimed at reducing rural poverty and also contribute to climate change mitigation, demonstrating the potential importance of sustainable agriculture (improved cropland and grassland management, expansion of agro-forestry systems and protection of forested areas) in delivering environmental services. EX-ACT has also been used as a tool to guide project developers in refining components and activities to increase project environmental benefits. Cost–benefit analysis shows that while both projects generate environmental benefits associated with climate change mitigation, the Santa Catarina Rural Competitiveness Project has significantly higher potential due to the size of the project area and the nature of activities, thus a higher likelihood of potential co-financing from climate finance sources. [Copyright &y& Elsevier]

Abstract: This paper presents an overview of the current status of the main CCS initiatives in the major emerging economies: China, India, Brazil, Mexico, Russia, and South Africa. This study first covers all six countries as a group and describes their natural resources. The second part of this study embraces each country individually and includes current initiatives and current legal and technological status of CCS. At the end, this study summarizes the main findings in the emerging economies and the potential of including CCS as part of the CDM. [Copyright &y& Elsevier]

Abstract: This paper reviews current knowledge on changes in carbon stocks upon land use conversion in the Brazilian Cerrado. First, we briefly characterize the savanna ecosystem and summarize the main published data on C stocks under natural conditions. The effects of increased land use pressure in the Cerrado and current uncertainties of estimations of changes in land cover and land use are reviewed next. Thereafter, we focus on soil organic carbon (SOC) dynamics due to changes in land use, particularly conversion to pastures and soybean-based cropping systems, and effects of management practices such as soil fertilization, crop rotations and tillage practices. Most studies considered here suggest that more intensive agriculture, which include no-till practices and the implementation of best or recommended management practices (RMP), reduces SOC losses after land use conversion from conventional tillage-based, monocropping systems; however, these studies focussed on the first 0.3m of soil, or less, and seldom considered full carbon accounting. To better estimate possible global warming mitigation with agriculture in the Cerrado more comprehensive studies are needed that analyse fluxes of the biogenic greenhouse gases (GHG; CO2, N2O and CH4) to determine the net global warming potential (GWP). Follow up studies should include the application of an integrated modelling system, comprised of a Geographic Information System (GIS) linked to dynamic modelling tools, to analyse SOC dynamics and make projections for possible changes in net C flows in the Cerrado region upon defined changes in soil use and management. [Copyright &y& Elsevier]

Abstract: Economically optimal rotations are not frequently employed in Eucalyptus plantations management despite eucalypts’ economic importance to the pulp industry. The coppice regeneration method used to manage eucalypts leads to a simultaneous optimization problem. In such cases, the manager has to simultaneously define the optimal age in each coppice rotation and the optimal number of coppice rotations for each plantation full cycle. The dynamic nature of the problem of looking for the optimal set of coppice rotations for Eucalyptus plantations obliges managers to use the dynamic programming technique. In order to evaluate the economic loss occasioned when optimal rotations are not considered, two plantations are shown, one with Eucalyptus urophylla S.T. Blake in Brazil and another with Eucalyptus globulus Labill in Spain. Different clearcut ages are established in each country, 5–9 years in Brazil, and 13–18 years in Spain. A multiple products context (wood and carbon) is considered in this paper. The results show different rotations and optimal number of coppice rotations for each site index and case considered. To repeat the seedling rotation in the following coppice rotations usually is not the best option. Besides, the optimal cycle and the land expectation value vary when carbon sequestration is evaluated for the two plantations considered. Finally, on some occasions the results are very sensitive to changes in parameters like the carbon price and discount rate. [Copyright &y& Elsevier]

This article describes a new concept to reduce carbon dioxide emissions of offshore oil production of high gas-to-oil ratio reservoirs and high content of CO2, denominated Offshore Salt Cavern Ultra-deep Water CCS (Carbon Capture and Storage) System. This hybrid system is intended for natural gas storage, the gravitational separation between CO 2 /CH 4 , and CO 2 confinement for final destination. This development emerged from a current demand of some Brazilian pre-salt reservoirs to destinate a gas stream with high CO 2 contamination, produced during the oil extraction. These reservoirs have a continuous salt rock layer of 2000 m as caprock making the construction possible of salt caverns by leaching using seawater. In the first stage of technology development, the system will only store a gas stream contaminated with a high concentration of CO 2. In the second stage of its development, it will allow not only the separation of natural gas from the CO 2 but also its storage and the monetization of CH 4. This paper presents the conceptual design of this technology, showing the steps from the parametric study to select the best relation between flowrate, leaching time, structural stability, and the volume of gas with the high content of CO 2 storage, up to the final geomechanical design using the set of parameters selected. [ABSTRACT FROM AUTHOR]