Search

Abstract Concentration polarization and surface fouling may be two of the most remarkable features in the pressure-driven membrane filtration process. A new numerical simulation model is proposed in this paper to study the concentration polarization (CP) and the inorganic fouling growth. The numerical study is based on the lattice Boltzmann method (LBM), which allows a simultaneous solution of the Navier–Stokes equations and the convection-diffusion equation. Simulation results are verified by comparisons with published CP and permeate flux data under the same operating conditions. Then the model is extended to predict CP in a spacer filled desalination channel. The prediction result indicates that there is a higher fouling potential near the spacer filaments due to higher CP values in that area. Coupling of the CP prediction model with gypsum growth kinetics provides an approach to study the inorganic fouling growth on the membrane surface at a single crystal level, with respect to a given solution supersaturation near the membrane surface. Predicted equivalent radius and accumulated mass of the growing gypsum crystal, under the effects of growth retardation by bicarbonate, agree with published test data and analytical results. The presented numerical model enables a direct evaluation of the impacts on the surface crystal development in the presence of antiscalants. This numerical model can be applied to identify suitable operating conditions, assist in dose selection of antiscalants when required properties are available, and predict the fouling mitigation effects in the pressure-driven membrane filtration process. Highlights • Proposed an LBM CP prediction model for membrane filtration channel with spacer filaments considered; • Proposed an LBM inorganic fouling growth model for a direct simulation of the surface fouling formation; • Formed an integrated numerical model to identify effects of operating conditions on the fouling mitigation. [ABSTRACT FROM AUTHOR]

The performance of a vibration enhanced reverse osmosis membrane module for desalination of artificial seawater was investigated with computational fluid dynamics (CFD) simulations and experiments. The computational model couples fluid dynamics with solutes transport inside the full length domain containing ‘zigzag’ spacers using a two dimensional, transient Large Eddy Simulation turbulence model. Both the local concentration dependent solute properties and variation of permeate flux over the membrane surface were predicted with the model. Membrane local permeate flux, concentration polarization, shear rate, and mass transfer were also calculated. The results suggest concentration polarization in the seawater desalination process could be reduced by imposing vibration on the reverse osmosis membrane. It was determined that the higher the vibration frequency the higher the membrane permeate flux while keeping the vibration amplitude constant. The CFD simulation predictions are validated against experimental data of permeate fluxes with good agreement. [ABSTRACT FROM AUTHOR]

The subject of this work is the development of a novel vibration assisted seawater desalination approach which changes thermodynamic (mass transfer coefficient) and hydrodynamic (cross-flow velocity) properties to mitigate the inorganic fouling for RO membranes. A classical mass transport model and experimental measurements showed that an increased cross-flow velocity in the feed channel enhances the near membrane mass transfer coefficient, which promotes the back-diffusion of inorganic salts and reduces the concentration polarization (CP). Then a theoretical CP Finite Element Method (FEM) model incorporating increased cross-flow velocity reveals that a lower CP modulus forms near the membrane surface with a higher vibration frequency, which results in less fouling on the membrane surface. The vibration assisted desalination process was demonstrated using a linear motor driven, periodically oscillating desalination cell. A smaller flux decline was observed while using a higher vibration frequency (with a constant sinusoidal amplitude) and a higher vibration velocity (in multiple vibration forms). Process simulations and experimental observations validated that the proposed vibration assisted desalination process helps enhance the permeate flux and mitigate the formation of inorganic fouling on the RO membrane surface. [ABSTRACT FROM AUTHOR]