A novel planar micro-combustor with four-corner entrances is proposed by considering high and uniform outer wall temperature distribution used in micro thermo-photovoltaic generator. For this, a three-dimensional numerical model with detailed chemical mechanism, transport, and heat transfer and a thermo-photovoltaic energy conversion model are developed to examine its performance. Results show that the proposed micro-combustor has excellent wall temperature uniformity because a uniform distribution of high-temperature zones of four individual flames is formed in the combustion chamber. Thermal performance and energy efficiency of the proposed micro-combustor are better than conventional micro-combustor at a low flow rate (m) and large equivalence ratio (φ). Additionally, the implemented plate-insertion strategy effectively overcome the deterioration of combustor performance under higher m or lower φ. Proposed micro-combustor with plates insertion has the largest wall temperature and energy efficiency, no matter what φ and m are adopted. Plates extend the fluid ravel path and produce some recirculation zones, which promotes heat transfer, preferential diffusion, and flame anchoring, while its pressure loss is larger. Of all the tested cases, the system efficiency reaches a maximum of 6.39%, corresponding to 12.1 W electricity output. This work provides effective combustor design and research insights to develop high-efficiency micro-power system. • A novel micro-combustor with four entrances is proposed for micro-TPV system. • Excellent performance of wall temperature uniformity is obtained. • Inserting plates boosts thermal performance and energy conversion efficiency. • A maximum system efficiency of 6.39% is achieved with 12.1 W electric output. [ABSTRACT FROM AUTHOR]