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Abstract: In this paper a two-dimensional model of an annular cylindrical reactor filled with metal hydride suitable for hydrogen storage is presented. Comparison of the computed bed temperatures with published experimental data shows a reasonably good agreement except for the initial period. Effects of hydrogen pressure and external fluid temperatures on heat transfer and entropy generation are obtained. Results show that the time required for hydrogen charging and discharging is higher when the thermal capacity of the reactor wall is considered. The time required for absorption and desorption can be reduced significantly by varying the hydrogen gas pressure and external fluid temperatures. However, along with reduction in time the entropy generated during hydrogen storage and discharge increases significantly. Results also show that for the given input conditions, heat transfer between the external fluid and hydride bed is the main source of entropy generation. [Copyright &y& Elsevier]

Abstract: The metal hydride heat transformer shows great potential for the low-grade heat recovery. However, the heat output is variable, and these dynamics have to be taken into account in realistic applications. In this paper, a new index called true temperature boost is introduced together with conventional indices to assess the performance of the heat transformer system. Detailed analyses are carried out using a mathematical model that authors developed, investigating effects of key design and operating factors on the system’s performance. The amount of hydrogen transferred between coupled reactors is found to be crucial to obtain a high coefficient of performance, while specific heating power is very sensitive to the cycle time. On the true temperature boost, the driving force of reaction and the heat transfer conditions exert the most significant effects. [Copyright &y& Elsevier]

Abstract: This paper describes the design, fabrication and performance evaluation of a high efficiency, compact heater that uses the catalytic oxidation of hydrogen to provide heat to a hydrogen storage system. The heater was designed to transfer up to 30kW of heat from the catalytic reaction to the hydrogen storage system via a recirculating heat transfer fluid. The catalytic heater consists of three main parts: 1) the reactor, 2) the gas heat recuperator, and 3) oil and gas flow distribution manifolds. The reactor and recuperator are integrated, compact, finned-plate heat exchangers to maximize heat transfer efficiency and minimize mass and volume. Detailed, three-dimensional, multi-physics computational models were used to design and optimize the system. At full power the heater was able to catalytically combust a 10% hydrogen/air mixture flowing at over 80 cubic feet per minute and transfer 30kW of heat to a 30 gallon per minute flow of oil over a temperature range from 100°C to 220°C. The total efficiency of the catalytic heater, defined as the heat transferred to the oil divided by the inlet hydrogen chemical energy, was determined to exceed the design goal of 80% for oil temperatures from 60°C to 165°C. [Copyright &y& Elsevier]