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In this paper, a detailed investigation with respect to the structural, cryogenic magnetic properties and magnetocaloric performances of RE 2 CuMnO 6 (RE = Gd, Dy, Ho and Er) double perovskite (DP) compounds has been performed. All the RE 2 CuMnO 6 compounds are confirmed to B -site disordered and crystallized in the GdFeO 3 -type structure (Pnma space group, N 62, oP20). The magnetic transition temperatures (T M) are found to be ~7.5 K for Gd 2 CuMnO 6 , ~12.1 K for Dy 2 CuMnO 6 , ~12.2 K for Ho 2 CuMnO 6 , and ~3.6 K for Er 2 CuMnO 6 , respectively. Moreover, for checking the magnetocaloric performances several vital parameters including -Δ S M max (peak value of magnetic entropy change, -Δ S M), TEC (3) (temperature averaged -Δ S M) and RCP (relative cooling powers) are evaluated to be 7.84, 7.73 J/kgK and 151.1 J/kg for Gd 2 CuMnO 6 , 5.69, 5.59 J/kgK and 180.9 J/kg for Dy 2 CuMnO 6 , 7.12, 7.05 J/kgK and 192.4 J/kg for Ho 2 CuMnO 6 , as well as 9.92, 9.60 J/kgK and 195.9 J/kg for Er 2 CuMnO 6 under the magnetic field change Δ H = 5 T, respectively. [ABSTRACT FROM AUTHOR]

Abstract It is well known that rare earth (RE) based intermetallic compounds reveal various interesting magnetic properties depending on the crystallized structures and the constituent elements, paving the way for potential applications in different fields. Recent progresses regarding magnetic properties and magnetocaloric effect (MCE) in ternary rare earth RE 2 T 2 X (RE = Gd-Tm; T = Cu, Ni, Co; and X = Cd, In, Ga, Sn, Al) intermetallic compounds are reviewed in this paper. Some of them exhibit excellent MCE performances which make them attractive in the field of magnetic refrigeration at low temperature. With the aim of understanding the magnetocaloric characteristics of RE 2 T 2 X compounds, the crystal structure, magnetism and magnetic phase transition are also focused. The origin of the MCE together with the physics behind and the potential application of RE 2 T 2 X compounds are thoroughly considered. Highlights • Magnetic and magnetocaloric properties in RE 2 T2X compounds are reviewed. • The RE 2 T2X compounds show four types of crystallize structures. • Some of them exhibit excellent cryogenic magnetocaloric performances. • The origin of magnetocaloric effect in RE 2 T2X compounds is discussed. [ABSTRACT FROM AUTHOR]

We herein provided a systematical determination of the structural and magnetic properties, especially of the magnetocaloric effect (MCE) and magnetocaloric performances of four rare-earth oxychlorides, i. e., the RE OCl (RE = Ho, Dy, Tb and Gd) compounds. The studied RE OCl compounds are all crystallized in the tetragonal matlockite structure (P 4/ nmm space group) and the RE , O, and Cl elements are with the RE 3+, O2−, and Cl− valence states, respectively. The DyOCl, TbOCl and GdOCl compounds reveal an antiferromagnetic transition at around approximate 9.5, 3.7 and 4.8 K, respectively. The magnetocaloric performances are checked by the maximum magnetic entropy change, relative cooling power, and temperature-averaged entropy change with 5 K lift, which are found to be 14.16 J/kgK, 375.55 J/kg and 13.89 J/kgK for HoOCl, to be 14.88 J/kgK, 488.14 J/kg, and 14.60 J/kgK for DyOCl, to be 14.59 J/kgK, 419.67 J/kg, and 14.42 J/kgK for TbOCl, and to be 16.16 J/kgK, 213.68 J/kg, and 14.39 J/kgK for GdOCl, with the magnetic field change of 0–7 T, respectively. [ABSTRACT FROM AUTHOR]

• The RE 2 Ga 2 Mg (RE = Tm, Er, Ho) compounds were fabricated. • The magnetic and magnetocaloric properties were investigated. • Large conventional and inverse magnetocaloric effects were observed. • The Tm 2 Ga 2 Mg is considerable for cryogenic magnetic cooling. The Mo 2 FeB 2 -type compounds RE 2 Ga 2 Mg (RE = Tm, Er, Ho) (space group P 4/ mbm) exhibit a large magnetocaloric (MC) effect which makes them promising for use in cryogenic magnetic cooling applications. They exhibit low temperature metamagnetic nature below their Néel temperatures of 6.8, 11.7 and 18.4 K for Tm 2 Ga 2 Mg, Er 2 Ga 2 Mg and Ho 2 Ga 2 Mg, respectively. The magnetic entropy change, the temperature-averaged entropy change (3 K-lift), and the relative cooling power under a magnetic field change of 0–7 T are 15.6, 15.4 J/kgK and 275.8 J/kg for Tm 2 Ga 2 Mg; 13.2, 13.0 J/kgK and 268.0 J/kg for Er 2 Ga 2 Mg; as well as 9.1, 9.0 J/kgK and 223.0 J/kg for Ho 2 Ga 2 Mg, respectively. [ABSTRACT FROM AUTHOR]

In this work, polycrystalline oxides viz., Ho 2 CrMnO 6 (HCMO) and Er 2 CrMnO 6 (ECMO), were prepared using the sol-gel process, and their crystal structure, magnetic properties, and magnetocaloric effects (MCEs) were studied. X-ray refinement results demonstrate that both oxides exhibited the B -site disordered perovskite type structure (Pbnm space group). A ferromagnetic-paramagnetic phase transition as well as large reversible MCEs was also observed at Curie temperatures (T C) of ~6.1 and ~5.2 K for HCMO and ECMO, respectively. For a magnetic field change (ΔH) of 0–7 T, the maximum magnetic entropy change (-Δ S M), temperature-averaged entropy change (TEC 3), and relative cooling power (RCP) were estimated to be 11.03 J/kgK, 11.02 J/kgK, and 322.7 J/kg for HCMO, and 12.94 J/kgK, 12.80 J/kgK and 277.5 J/kg for ECMO. [ABSTRACT FROM AUTHOR]

The magnetic properties and magnetocaloric effect (MCE) in dysprosium zinc binary DyZn compound were studied. The compound reveals a paramagnetic-to-ferromagnetic transition together with a spin reorientation phenomenon at Curie temperatures of T C ∼135 and T SR ∼50 K, respectively. A large reversible MCE was observed in DyZn around T C . For the magnetic field change of 0–7 T, the values of maximum magnetic entropy change (–Δ S M max ), relative cooling power ( RCP ), and refrigerant capacity ( RC ) were 12.2 J/kg K, 895 J/kg, and 672 J/kg, respectively. [ABSTRACT FROM AUTHOR]

The structural, magnetic, and magnetocaloric properties of Ni 44 Mn 45-x Sn 11 Fe x (x = 0, 1, 2 and 3) Heusler alloys have been studied detailly by means of X-ray diffraction, differential scanning calorimetry, and magnetization measurements. The martensitic transition temperature (T M) and austenite Curie temperature (T A C) increase gradually with increasing Fe content. Large differences in magnetization between the ferromagnetic austenite and weakly magnetic martensite phases and obvious thermal hysteresis have also been observed during the martensite transformation. With the magnetic field change up to 0–7 T, the maximum value of magnetic entropy changes reaches 26.7 and 23 J kg−1K−1 for x = 1 and 2, respectively, which are much larger than the undoped sample (9.8 J kg−1K−1). Whereas, the effective refrigerant capacity RC eff reduced due to Fe doping increased the hysteresis loss. The alloy for x = 1 has highest RC value of 172 (255) J kg−1 for a magnetic field change of 0–5 T (0–7 T), furthermore, a large magnetic entropy change and moderate RC eff has been obtained around room temperature. • Fe-doped Ni44Mn45-xSn11Fex (x = 0, 1, 2 and 3) Heusler alloys were fabricated. • Structural and magnetic properties of Ni44Mn45-xSn11Fex were investigated. • Considerable magnetocaloric performances in Ni44Mn44Sn11Fe were realized. [ABSTRACT FROM AUTHOR]

• The magnetism and magnetocaloric effect (MCE) were investigated in Er 4 CoCd compound. • A large magnetocaloric effect in Er 4 CoCd compound was observed. • The origin of MCE and its potential application in Er 4 CoCd were discussed. The Er-based compound Er 4 CoCd was synthesized successfully and its structural, magnetic together with magnetocaloric properties were investigated in detail. The Er 4 CoCd crystallized in a Gd 4 RhIn-type structure with the space group of F 4 ¯ 3 m , which was confirmed by Rietveld refinement. A ferromagnetic transition was observed around its Curie temperature (T C) of 12.5 K accompanied by a large magnetocaloric effect (MCE). The performance of MCE for Er 4 CoCd was evaluated by the isothermal maximal magnetic entropy (- Δ S M max) , the temperature averaged entropy change (TEC) at 10 K temperature lift [ TEC (10 K)], and the relative cooling power (RCP). The values of - Δ S M max , TEC (10 K), and RCP of Er 4 CoCd are 20.4 J/kg K, 19.2 J/kg K, and 503 J/kg under the magnetic field change (Δ H) of 0–5 T, respectively. [ABSTRACT FROM AUTHOR]