1. The effect of chain rigidity and microstructure on gas separation performance of the cardo-based polyimides.
- Author
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Tong, Xiaohua, Wang, Shuli, Dai, Jiangnan, Wang, Shuai, Zhang, Ke, Zhao, Xiaogang, Wang, Daming, and Chen, Chunhai
- Subjects
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POLYIMIDES , *GAS separation membranes , *SEPARATION of gases , *PROTOGENIC solvents , *APROTIC solvents , *MOLECULAR structure , *MICROSTRUCTURE , *DIOXANE - Abstract
A series of aromatic polyimides were synthesized from three Cardo-based diamines, BAF, DDA, BAP, with different building blocks (ether linkage, dioxane linkage and C–C linkage), and commercially available dianhydride 6FDA. All polyimides were readily soluble in conventional aprotic and protic solvents, which guaranted the fabrication of self-standing membranes for gas separation applications. The Cardo-based polyimides also exhibited excellent thermal stability, with weight loss temperatures (T 5 %) of over 538 °C, and good mechanical properties, with tensile strength in the range of 41–64 MPa. Compared to 6FDA-BAF, the substitution of dioxane linkage for ether linkage resulted in increased chain rigidity, looser polymer chain packing, and larger fractional free volume. Consequently, as displayed by single gas permeation tests, 6FDA-DDA showed higher permeability coefficients without significantly sacrificing selectivity. In addition, the CO 2 permeability of 6FDA-BAP was around 2 times as high as that of 6FDA-BAF, while the CO 2 /CH 4 selectivity increased by 11%. This can be explained by the lower rotational mobility and the relatively higher imide content caused by the absence of the flexible ether linkage and dioxane linkage in polymer backbone. In short, fundamental insights into structure-property relationships of the Cardo-based polyimides observed in this study provided guidance for the molecular structure design of the gas separation membranes. [Display omitted] • Three Cardo-based polyimides containing different building blocks were successfully synthesized. • The effect of rigidity and microstructure on gas separation performance of the Cardo-based polyimides was elucidate. • The substitution of dioxane for ether linkage led to the increased chain rigidity and the looser chain packing. • The polyimide containing C–C linkage showed better combination of permeability and gas-pair selectivity. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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