1. Sources of dissolved carbon in large rivers: Insights from coupled 13C-14C in the upper Changjiang (Yangtze) River.
- Author
-
Zhong, Jun, Galy, Albert, Zolkos, Scott, Xu, Sheng, Liu, Cong-Qiang, and Li, Si-Liang
- Subjects
- *
ATMOSPHERIC carbon dioxide , *CHEMICAL weathering , *CARBON cycle , *RIVER channels , *CHEMICAL reactions - Abstract
• Carbon cycling in the upper Changjiang River was investigated using major ions, δ13C DIC and Δ14C DIC. • Downstream changes in [DIC] and isotopes in the mainstem were driven by hydrochemical inputs from tributaries. • Low Δ14C DIC and high δ13C DIC were observed in high-elevation areas, and vice versa. • System openness is highly modulated by physiographic conditions (e.g. climate, hydrology, geology, land-use change). Export of dissolved carbon from rivers connects terrestrial and oceanic carbon cycling, and represents a key component of global carbon budgets. In this study, we measured the concentrations of major ions, the sulfur isotopic composition of sulfate, and the stable (δ13C DIC) and radioactive (Δ14C DIC) isotopic composition of the dissolved inorganic carbon (DIC) in the upper Changjiang (Yangtze) River, China. Their spatio-temporal variabilities give constrains on carbon cycling across catchments with diverse physiographic conditions (e.g. climate, hydrology, geology, land-use change). Daily DIC fluxes were modeled using a hydro-chemical approach and showed significant temporal variations agreeing with the measured data, and supporting a conservative mixing behavior in river channel, similar to variations in anions and cations concentrations. However, the modeled (δ13C DIC) were always higher (up to 3.1‰, and 0.8‰ on average) than the measured values. In addition, Δ14C DIC would suggest a much lower carbonate contribution (8 to 33%) than concentration mixing relationship (40 to 64%). From the chemical weathering reaction front to the riverine transport, DIC can be processed with little net change in concentration but isotopic exchange and it can also exchange with the soil and/or atmospheric CO 2 as an open system. The openness parameter (ψ) uses the Δ14C DIC to estimate the extent of such exchange, ranging from 0 (fully closed system) to 1 (fully open system) and varied from 0.26±0.10 to 0.86±0.06. ψ showed a strong relationship with drainage mean elevation, likely to represent the elevation-induced climate variation (i.e. precipitation and temperature) but also the proportion of cropland in the drainage area. All of these parameters are correlated and point toward a biological impact on ψ. In addition, modern DIC yield, estimated from Δ14C DIC , is positively correlated to ψ. This study demonstrates that Δ14C DIC measurements can greatly underestimate the contribution of carbonate-derived carbon because of exchange (estimated by ψ) especially in high biological-productivity areas. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF