7 results on '"Duca, Daniele"'
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2. Mitigation strategies in the agro-food sector: The anaerobic digestion of tomato purée by-products. An Italian case study.
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Bacenetti, Jacopo, Duca, Daniele, Negri, Marco, Fusi, Alessandra, and Fiala, Marco
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ANAEROBIC digestion , *FOOD industry , *TOMATOES , *FOOD industrial waste , *RENEWABLE energy sources , *GREENHOUSE gas mitigation - Abstract
Tomato processing involves a significant production of residues, mainly constituted by discarded tomatoes, skins, seeds and pulp. Often, these residues are not valorized and represent an added cost for manufacturing companies because of disposal processes, with environmental issues due to the difficult management. The exploitation of these residual materials results complex as their availability is mainly concentrated in few months. A possible solution is the production of biogas employed in a Combine Heat and Power engine for energy production, in line with the 2020 targets of European Union in terms of promotion of energy from renewable resources and greenhouse gas emission reduction. The tomato by-product utilization for energy production as a strategy to reduce the environmental load of tomato purée was evaluated by means of Life Cycle Assessment. Two scenarios were considered: Baseline Scenario — tomato by-products are sent back to the tomato fields as organic fertilizers; Alternative Scenario — tomato by-products are employed in a nearby biogas plant for energy production. Methane production of tomato by-products was assessed by means of specific laboratory tests. The comparison between the two scenarios highlighted reductions for all the impact categories with the Alternative Scenario. The most important reductions are related to particulate matter (− 5.3%), climate change (− 6.4%) and ozone depletion (− 13.4%). Although small, the reduction of the environmental impact cannot be neglected; for example for climate change, the anaerobic digestion of by-products allows a saving of GHG emissions that, over the whole year, is equal to 1.567 tons of CO 2 eq. The results of this study could be up-scaled to the food industries with high heat demand producing considerable amounts of fermentable by-products employable as feedstock for biogas production. [ABSTRACT FROM AUTHOR]
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- 2015
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3. Evaluation of cradle to gate environmental impact of frozen green bean production by means of life cycle assessment.
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Ilari, Alessio, Duca, Daniele, Toscano, Giuseppe, and Pedretti, Ester Foppa
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GREEN bean , *HERBICIDE resistance , *PLASTIC scrap , *HERBICIDE application , *AGRICULTURAL productivity , *COMMERCIAL products , *MANUFACTURING processes , *EFFECT of herbicides on plants - Abstract
The main objective of this study is to assess the impact of frozen green bean production and processing. The analysis and relative information collected regards a medium industry located in the south of Marche region (Italy) and the whole production system, from field to industry, is in a range of about 100 km between Marche and Abruzzo regions. The aim of this study is to assess the impact of 1 kg of frozen green bean for two different cultivation protocols for herbicides and pesticides application in order to assess the possible advantages due to shifting to different field treatments. The baseline scenario (A) considers the application of two herbicides (Pendimethalin and Linuron) and two pesticides (Altacor and Azoxystrobin), the alternative scenario (B) considers one herbicides application (Clomazone) and two pesticides (Emamectine and Azoxystrobin). The analysis has been conducted following ISO 14040 and 14044 on Life Cycle Assessment (LCA) and Product Category Rules for arable crops v. 2.0. LCI (Life Cycle Inventory) and LCIA (Life Cycle Impact Assessment) phase have been performed using LCA software SimaPro® v. 8.2.3.0 with updated databases. The most used databases for this study are Ecoinvent 3 and Agri-footprint, LCI data have been collected through interviews, consulting official documents and company management programs. The system boundaries considered includes crop production, transport to industry plant and industry processing and all the data are referred to 2014 crop season. Crop production LCI considers seeds, fertilizers, pesticides, field activities, yield and relative emissions. Transportations covers distances and payload with empty return. Industry phase considers transformation efficiency, energy, fuels, water. The function of the production chain is to provide frozen green bean, no coproduct or by-product were produced. Residues and product losses from industry processing are managed by anaerobic digestion as waste. Plastics and other wastes from field and industry has been treated by landfill. Data regarding field phase were collected by interviews and consulting official management documents from 43 farms. Data regarding industrial phase have been gathered from automated management systems hardware/software AS/400 (IBM). The LCIA results for 1 kg of frozen green been show an impact of about 0.7 kg of CO2 eq for GWP, 1.9E-4 kg of C2H4 eq kg for PCOP, 3.5E-3 kg of SO2 eq for AP and 1.7E-3 kg of PO43- for EP. The analysis conducted comparing two different solutions of plant protection and herbicides application shows how solution A has a lower impact on ADP, ADP fossil, GWP 100yr, ODP, MEP, PCOP, AP and EP from 0.04% to 11% about. On the other hand, solution B has a lower impact on HTP, FEP, MEP and TEP between 4 and 40%. The analysis conducted shows the impact of frozen green been at industry level representative of medium size processing plant with average technology. The only information available in literature are limited to open field production impact assessment of raw green bean without any kind of industry transformation.. Simply replacing herbicide treatment and one pesticide application, for preventing weed and pest resistance, there is a consistent reduction of impact on different categories for ecotoxicity group without increasing too much the impact on other categories considered. The only exception can be found for ADP category in which the impact of alternative scenario (B) is higher than baseline (A). The reason lies in the lower active ingredient concentration and higher amount of commercial product used for solution B. From the analysis remains evident the contribution on ADP fossil, GWP and ODP due to energy used in industrial phase. On the other side field phase contributes more on ADP, HTP, FEP, AP and EP. • Life cycle assessment of two scenarios for frozen green bean production have been calculated. • Cradle to industry gate approach for a Functional unit of 1 kg of frozen product. • A detailed processes description and relative Inventory have been produced. • A reduction of impact on ecotoxicity is possible replacing pesticides application. • A consistent impact increment was found for abiotic depletion potential resources. [ABSTRACT FROM AUTHOR]
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- 2019
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4. Analysis of the characteristics of the tomato manufacturing residues finalized to the energy recovery
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Rossini, Giorgio, Toscano, Giuseppe, Duca, Daniele, Corinaldesi, Fabrizio, Foppa Pedretti, Ester, and Riva, Giovanni
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TOMATO yields , *REFUSE as fuel , *BIOMASS energy , *PHYSICAL & theoretical chemistry , *COMPOSITION of tomatoes - Abstract
Abstract: Tomato manufacturing industry originates substantial amounts of residues. If left without control these residues can constitute an environmental problem. Their energetic use can solve this problem and give added value to the process. In this research physical-chemical characteristics of this biomass and its components are studied to evaluate the possibility of an energy recovery. In general, the dry residues of tomato processing industry are suitable as solid biofuel for energy purposes in large size power plants. The separation of components that constitute tomato residues (peels and seeds) makes sense in case of production and exploitation of oil from tomato seeds. The results can be useful for developing standards on these materials. [Copyright &y& Elsevier]
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- 2013
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5. Adaptability of sunflower (Helianthus annuus L.) high oleic hybrids to different Italian areas for biodiesel production.
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Del Gatto, Andrea, Mengarelli, Chiara, Foppa Pedretti, Ester, Duca, Daniele, Pieri, Sandro, Mangoni, Lorella, Signor, Marco, Raccuia, Salvatore Antonino, and Melilli, Maria Grazia
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COMMON sunflower , *OLEIC acid , *BIODIESEL fuels , *GENETIC testing , *GENOTYPES , *AGRICULTURAL wastes - Abstract
Currently the biodiesel chain is promoted by the European energy policy. For the Italian scenario the sunflower is one of the most important crop to be considered for biodiesel production but the chain is not fully profitable. This problem could be solved with the increase of farm incomes through a proper valorization of by-products. From this point of view the oilseed crop is not considered only for oil production but also for producing multiple products with the same economic value. This is the main inspiring concept of the Extravalore project. The sub-project “Raw Materials” investigated about the possible influence of different agro-technics performed in three distinct geographical environments (Northern, Central and Southern Italy) on the characteristics of by-products obtained from sunflower crop. A national net of experimental tests was set during the 2010–2013 period in order to evaluate the adaptability and the potential production of high oleic sunflower hybrids. 7 seed companies supplied the 20 genotypes assessed in total (18 high oleic hybrids and 2 as control), 11 of them were evaluated all the three years. Achene yields of tested high oleic hybrids were extremely variable: from 2.05 t ha −1 to 4.04 t ha −1 in Northern Italy, from 2.50 t ha −1 to 4.24 t ha −1 in Central Italy and from 2.09 t ha −1 to 2.68 t ha −1 in Southern Italy. For this reason, it was necessary a precise characterization of varieties before their cultivation. The cultivar screening showed general difficulty for high oleic hybrids to reach the performances of achene and oil yields of the conventional ones. In particular, LG55.57HO and PR64H31 resulted the best high oleic cultivars for Northern Italy; many of the high oleic tested cultivars performed well for Central Italy and also for Southern Italy but with a higher variability. The highest potential production was registered in Central Italy; Northern Italy gave decreased but similar results, despite the different latitude; in Southern Italy the productions were 20–30% lower, even with the irrigation support. All high oleic tested cultivars showed oleic acid content in lipid fraction always above the 84% in Central Italy, meaning a stability of the character, very important for the biodiesel production. [ABSTRACT FROM AUTHOR]
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- 2015
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6. A comparative study of oilseed crops (Brassica napus L. subsp. oleifera and Brassica carinata A. Braun) in the biodiesel production chain and their adaptability to different Italian areas.
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Del Gatto, Andrea, Melilli, Maria Grazia, Raccuia, Salvatore Antonino, Pieri, Sandro, Mangoni, Lorella, Pacifico, Daniela, Signor, Marco, Duca, Daniele, Foppa Pedretti, Ester, and Mengarelli, Chiara
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OILSEEDS , *BIODIESEL fuels , *GENOTYPES , *BRASSICA , *AGRONOMY - Abstract
The Extravalore project aims to give added value to oilseed crops, considering them also for producing multiple products with the same economic value and being interesting for the market thanks to their various utilizations. An evaluation of the main cultivars of Brassica napus subsp. oleifera and Brassica carinata has been performed within the project, analyzing them in three Italian locations with different climatic conditions (Palazzolo dello Stella – North Italy, Osimo – Central Italy, Cassibile – South Italy) to assay their adaptability and production potential. During the 2010–2013 period, 43 varieties of rapeseed were evaluated, but only 13 of them for all the period considered; moreover, also 4 varieties of B. carinata were tested. The seed yields of tested cultivars of rapeseed varied a lot among locations, depending also by the seasonal trend. Central Italy was the less disadvantaged by climatic conditions: on average, it was reached a seed yield of 4 t ha −1 , a theoretical oil production of 1.63 t ha −1 and more than 8 t ha −1 of crop residues. In Northern and Southern Italy, if compared with Central Italy values, the seed yields were both lower than 30% and theoretical oil productions lower than 60%; moreover, crop residues in Northern Italy were 12% lower than in Central Italy while in Southern Italy 65% lower. The agronomic behavior of varieties differed a lot among the three experimental areas: DK Expower was the best at North; Albatros, Artoga, Exagone and Excalibur in Central Italy; Excalibur, Zoom and PR46W14 at South Italy but none of them reached a seed yield of 2 t ha −1 . Concerning B. carinata , the cultivars did not give good productions in any of the experimental areas, mainly because of the low oil content in the seeds. Even in Central Italy, where the best results were registered, the seed yield was on average 28% lower than in rapeseed and oil production 10% lower; the crop residues were double than rapeseed. In any case, the valorization of the crop residues is important with a wide range of possible utilization from the direct energetic use to the biochemicals extraction with consequent environmental advantages due to the substitution of dedicated or fossil feedstock with crop residues. [ABSTRACT FROM AUTHOR]
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- 2015
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7. Engineered solid biofuel from herbaceous biomass mixed with inorganic additives.
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Toscano, Giuseppe, Feliciangeli, Gabriele, Rossini, Giorgio, Fabrizi, Sara, Foppa Pedretti, Ester, and Duca, Daniele
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BIOMASS , *BIOMASS energy , *WOOD pellets , *FORAGE , *ALFALFA , *PELLETIZING - Abstract
This study focuses on verifying the influence of some additives in the ash melting process of herbaceous biomass, developing a pelletized biofuel from the mixture of herbaceous biomass and various inorganic substances through a series of experimental tests. Therefore, different materials were sampled, chemically characterized and combined in mixtures of low-melting biomass materials. Tests were performed with various inorganics products added directly on the relative ashes to verify the interaction between the two systems. Subsequently, herbaceous biomass pellets containing growing amounts of additive were produced, verifying their effectiveness by analyzing the ash melting temperatures and adopting the PASSA test, that investigates the size of the ashes after incinerating the biomass in a muffle. The same method was then used to evaluate the ashes of an industrial boiler. Results show that the addition of inorganic additives in the extent of 3–5% by weight determines an increase in deformation temperatures over 547 °C for several biomass materials and additives. Tests carried out on forage pellets made with alfalfa and CaO as additive brought instead to an increase in deformation temperature between 43 and 107 °C. This work could be of interest in the evaluation of the energy reuse of herbaceous materials that would otherwise be considered as waste, and also it suggests the possibility of using egg shells as inorganic additives in accordance to the circular economy approach. Furthermore, the additivation level of these pelletized biofuel is perfectly in line with the provisions of ISO 17225-6 for non-woody pellets (≤5% weight). [ABSTRACT FROM AUTHOR]
- Published
- 2019
- Full Text
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