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The terms "bimrocks", "bimsoils" and "soil-rock mixtures" indicate different and very common types of geological units with a block-in-matrix fabric that are also "geotechnically complex formations" and are characterized by an internal heterogeneity, and spatial variability of mechanical parameters and lithological compositions. Due to this internal complexity, the understanding of their geomechanical behavior presents a key challenge in geotechnical engineering. However, the lack of a standardized and clear terminology complicates the discrimination of different types of complex formations and their internal mechanical properties, which leads to inconsistency in the literature and research studies. This inconsistency causes misunderstandings, with possible practical implications for the characterization, analysis, design and construction of engineering works. By a combination of geological and geotechnical observations, we propose a new classification for geotechnically complex formations, with particular attention to those with a block-in-matrix internal fabric. Four properties are at the base of this new classification and have a primary role in controlling the geotechnical behavior of block-in-matrix units (bimunits): (i) the composition (i.e., lithology, degree of lithification/consolidation, nature, and rheology) of blocks and the matrix that affects the water sensitivity, (ii) the degree of internal anisotropy (DA) of the block-in-matrix fabric, (iii) the degree of stratal disruption and mixing, and (iv) the volumetric block proportion (VPB). As a result, we classified bimunits in those with "anisotropic", "isotropic", and "mixed" (i.e., different behavior depending on the DA of the matrix) textures and, each of these types, into block-in-matrix rocks and block-in-matrix soils (bimrocks and bimsoils in the following). According to the water sensitivity of the matrix, bimrocks are also differentiated into "hard" and "soft". The novelty of the classification is that it is not limited to few types of geotechnically complex formations (e.g., flysch) but it can be easily applied to all field-based investigations of the different types of complex formations, regardless of their internal degree of stratal disruption, composition, and mechanical response to water sensitivity. [Display omitted] • Bimrocks and bimsoils are geotechnically complex formations. • Understanding their internal complexity is challenging for geotechnical engineers. • We propose a new practical classification of complex formations to aid comprehension. • Properties presented are composition, anisotropy/disruption degree, and block content. [ABSTRACT FROM AUTHOR]

The geological term "mélange" is used to indicate a vast group of "chaotic rock" units with a block-in-matrix internal arrangement exhumed in orogenic belts. Geotechnically such units are often defined as "complex formations", and are commonly associated with flysch-type formations. Such units range from coherent, bedding-concordant broken-formations to fully disrupted, discordant block-in-matrix rock assemblages. Mélanges derive from the progressive disruption and mixing of flysch-type successions from their earliest phases of development to their complete lithification and exhumation. They are the product of sedimentary (submarine mass transport), tectonic (thrust-related shearing) and mud-diapiric (fluid/gas driven remobilization of mud/shales) processes. Throughout a review of geological data, we show that the different intrinsic anatomical features and relationships with the host rocks shown by these various units allow differential internal anisotropy of the lithological properties, and, depending on their origin, size and distribution, they can variably influence the overall mechanical behavior of the host flysch-type formation. The review of geological data thus provides useful observations to distinguish different types of "complex formations" and block-in-matrix rocks with different geotechnical and mechanical characteristics, and then potentially suggesting the application of different rock or soil mechanics procedures. • Mélanges can be sedimentary, tectonic or diapiric in origin, or a combination thereof • These 3 types of mélanges are characterized by different internal architectures and relationships with the host flysch formation • Such characteristics deeply impact on their overall geotechnical behavior at different scales, for instance in controlling the orientation of the mechanically weak zones [ABSTRACT FROM AUTHOR]

Abstract: The Hamburg Klippe of the Central Appalachian orogenic belt exposed in eastern Pennsylvania displays a complex record of poly-phase mélange and broken formation development in a convergent margin setting. It includes an imbricate stack of tectonic slices, which consist of upper Cambrian to Upper Ordovician deep-water and continental slope sedimentary rocks, emplaced by gravity sliding onto the Laurentian passive margin during deposition of the Upper Ordovician Martinsburg Formation. Based on their internal structure and stratigraphy, the block-matrix ratios and relations, and the inferred tectonic settings of origin, we have differentiated the following mélanges and broken formations, whose evolutionary stages coincide with specific deformational phases in a complete orogenic cycle from subduction to collision: (i) sedimentary broken formations without exotic blocks, formed by in situ and local down-slope remobilization during the early stages of closure of the Octoraro Sea basin in the Early Ordovician; (ii) two types of sedimentary mélanges with exotic blocks, formed at the front of the advancing accretionary wedge during the Middle Ordovician subduction of the Laurentian continental margin beneath a microcontinent–magmatic arc tectonic assembly; (iii) layer-parallel, extensional broken formation and a diapiric mélange, formed in the outer trench and at the toe of the accretionary wedge, respectively, during the early–Late Ordovician; (iv) precursory olistostromes, formed during the Late Ordovician collisional episodes as the Hamburg Klippe was emplaced in the Martinsburg Formation on the downgoing Laurentian continental margin; and, (v) contractional deformation-related broken formations, formed at the base of main thrust faults overprinting the previously formed mélanges and broken formations. This sequential development of different mélange types in the Central Appalachians was strongly controlled by the degree of consolidation of the layered strata and their rheological differences, the structural level of mélange formation within the accretionary wedge, and the kinematics of deformational processes. [Copyright &y& Elsevier]

Abstract: The Argille varicolori (Varicolored scaly clays) of the External Ligurian Units of the Northern Apennines have been widely described as a typical unmetamorphosed broken formation (i.e., a chaotic unit without exotic blocks), produced by offscraping and tectonic imbrication during the evolution of the Ligurian accretionary wedge. Geological mapping and integrated structural and stratigraphic observations show that the Argille varicolori consist of diverse types of small-scale mélanges (non-mappable at a 1:25,000 scale) forming a composite chaotic unit, in which the superposition of tectonic, sedimentary and diapiric processes resulted in the occurrence of polygenetic chaotic bodies at different scales. These mélange units record the evolution of the Ligurian accretionary wedge from subduction to collision and intracontinental deformation. Tectonically Disrupted Body 1 (TDB1) comprises boudinage and pinch-and-swell structures formed by layer-parallel extension/contraction at the wedge front of the Ligurian accretionary complex during the late Cretaceous–middle Eocene. It is interleaved with non-mappable Gravity-driven Chaotic Bodies (GCB) developed during alternating episodes of accretion and removal of material at the wedge front. The late Oligocene–early Miocene out-of-sequence thrusting related to the collisional episodes in the Apennines overprinted the previously formed chaotic bodies and formed a polygenetic tectonic mélange (Tectonically Disrupted Body 2, TDB2). This unit is characterized by a structurally ordered block-in-matrix fabric and by the gradual decrease of stratal disruption away from the regional thrust. Overpressurized fluids concentrated along the shear surfaces, and the scaly cleavage planes facilitated the diapiric upward movement of unconsolidated sediments in the early Miocene. This process produced non-mappable shale dike injections (DDB1) and mappable Diapirically Disrupted Bodies (DDB2), which show an internal zonation of deformation. This deformation reworked the previously formed chaotic bodies. Although some of these polygenetic mélanges cannot be mapped at a 1:25,000 scale, their careful documentation provides a better understanding of time-progressive, scale-independent mélange-forming processes. [Copyright &y& Elsevier]

• 3 component gasoline surrogates are usually made from toluene, isooctane and n - heptane. • Gasoline surrogates with toluene, isopentane and n-heptane (THIP) are proposed. • THIP surrogates capture RON/ MON and Ignition Delay (measured in RCM) of a real fuel. • THIP surrogates are better able to represent a realistic DVPE and density. • Chemical kinetic mechanisms exist to model THIP surrogates with reasonable accuracy. Simple surrogate formulations for gasoline are useful for modelling purposes and for comparing experimental results using a carefully designed fuel. Simple three component surrogate fuels based on toluene, n-heptane and isooctane, called toluene primary reference fuels (TPRF), are frequently used to match the RON and MON of actual gasoline fuels. In this work the main advantages of using an alternative three-component surrogate formulation, based on toluene, n-heptane and isopentane (THIP) are presented. Given a reference gasoline, good representations of RON and MON are achieved as well as better matching density, distillation properties and other volatility parameters associated with the lighter end of gasoline fuels. In particular, THIP surrogates can replicate Dry Vapour Pressure Equivalent (DVPE) values ranging from 10.4 kPa to 138.9 kPa, fully covering the EN228 Summer and Winter gasoline specifications. Moreover, Rapid Compression Machine (RCM) results demonstrate that THIP surrogates can reproduce the essential characteristics of the reference gasoline in terms of ignition delay time versus temperature. An existing chemical kinetic mechanism is shown to be able represent THIP surrogate well. [ABSTRACT FROM AUTHOR]