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Abstract: Detailed hydrothermal alteration investigations, including petrography, infrared reflectance spectroscopy (IRS) and XRD of the low sulfidation epithermal Co–O mine, located in Eastern Mindanao (Philippines) revealed that both distal and intermediate hydrothermal alteration zones contain dominantly illite and chlorite, whereas the proximal alteration zone comprises mainly illite, chalcopyrite and pyrite. The gold-bearing veins and the proximal hydrothermal alteration zone display a distinct absence of K-rich hydrothermal alteration minerals such as K-feldspar (adularia). Gold mineralization in the Co–O mine is controlled by an extensive quartz-breccia vein system, which is characterized by three distinct stages of vein (incl. breccias) formation. Gold is mainly observed in stages 2 and 3 veins. Stage 1 veins appear as fragments in stage 2 veins and display boiling textures such as quartz pseudomophs after bladed calcite. These veins further display colloform to crustiform banding and contain pyrite, chalcopyrite and minor gold located in the colloform bands and between bladed quartz pseudomorphs. Stage 2 veins comprise mostly banded to massive quartz and contains sulfides parallel to bands or disseminated. These veins are fine-grained with mosaic/jigsaw quartz and contain calcite blebs and/or fragments of stage 1 veins. Gold is in textural equilibrium with chalcopyrite, sphalerite, and locally pyrite. Stage 3 veins consist of quartz and carbonate (locally Mn-rich), and display irregular banded and comb textures. In auriferous veins of this stage gold is in textural equilibrium with chalcopyrite and pyrite (with local abundance of sphalerite). Other sulfide minerals observed with gold in stages 2 and 3 are galena, acanthite and locally jalpaite. The XRD and IRS provide inconsistent results regarding the abundance of K-rich clays (e.g., illite) associated with auriferous veins. Illite, with possibly interlayered swelling clays, such as Al-smectite, was identified in auriferous vein stages 2 and 3 using IRS, but could not be confirmed by XRD. Comparative analysis of the results of these techniques with respect to the ordering of micaceous minerals, suggest less ordered white mica proximal to the veins. Vein textures such as banded quartz, the absence of K-feldspar and the abundance of illite (interlayered Al-smectite) suggest relatively low temperatures of formation of the hydrothermal alteration system and point to a potential boiling horizon located deeper or marginal to the currently exploited levels of the Co–O mine. The absence of K-feldspar may also be related to relatively low temperatures of the hydrothermal fluid, the medium potassium-rich magma series of the host rocks, and/or a relatively low oxidation state of the hydrothermal fluid. [Copyright &y& Elsevier]

Abstract: A simple quadratic method is proposed for estimating the wavelengths of absorption features in the short wave infrared spectral region from hyperspectral instruments ranging from 2 to 18nm sampling intervals. The method uses a direct substitution of the three spectral reflectance bands to achieve an estimate of the wavelength of the point of maximum absorption. The method is shown to be stable across different sampling regimes and therefore across different hyperspectral instruments. The results show it is possible to accurately estimate the wavelength of spectral absorption features to an RMSE of ±3.8nm in the 2000–2500nm spectral region over multiple sampling intervals and resolutions in sensors with signal-to-noise greater than 500:1. [Copyright &y& Elsevier]

Remotely sensed hyperspectral datasets were integrated with petrographic data to map the distribution of sedimentary rocks in order to infer grain size variations within the siliciclastic, Paleoproterozoic Bresnahan Group in Western Australia. Finer sandstones have greater compositional variation compared to coarser sandstones, with higher modal proportions of mudstone intraclasts, K-feldspar, and muscovite laths, and lower modal quartz. Partial Least Squares modelling indicates a link between visible to shortwave infrared spectral data collected on samples and their average grain size. Specific electronic absorptions are important for defining this relationship, particularly in the blue-green visible spectra, wavelengths related to water or hydroxyl bonds, along with certain wavelengths in the shortwave infrared (SWIR) spectra. The results from field samples were compared to airborne hyperspectral datasets which showed broad scale regional variations in composition could be discerned from processed white mica abundance maps and images that use spectral bands 2350 nm and 2200 nm. The remotely sensed compositional variations are relatable to changes in sandstone grain size. Diagenetic alteration and surface weathering may influence the absorption spectra, although the effect of the latter can be reduced by using processed white mica abundance maps. Overall, the results show that airborne hyperspectral datasets, particularly the SWIR part of the spectra, can be useful to remotely map spatial compositional variations associated with sandstone grain size. This shows the method can be used to remotely map siliciclastic successions in other sedimentary basins by aiding recognition of grain size trends and significant stratal surfaces associated with changes in composition. However, the important wavelengths may differ due to other controls on sandstone composition such as uplift history of the source region, changes in sediment dispersal, and transport mechanisms. • Sample spectral data detect compositional change linked to sandstone grain size. • Compositional change with grain size is detected in airborne spectral data. • Study indicates grain size of siliciclastic successions can be remotely inferred. [ABSTRACT FROM AUTHOR]

Abstract: Determining the spatial relationships between various geological features and mineralisation is not only important for understanding the ore genesis of mineral deposits, but can also help to guide mineral exploration by providing predictive mineral maps. In this GIS-based study, we quantify the spatial relationships between gold mineralisation and plausible controlling factors in the central part of the St Ives area, Western Australia. We weigh plausible control factors including rock types, lithological boundaries and faults, using gold occurrences in drill-cores, and then apply the weights to the geological data to generate a predictive map for the entire St Ives area. The three major findings of this study are: (1) all major gold deposits are controlled by faults, and small-scale fault systems have a stronger correlation with gold mineralisation than large faults; (2) felsic to intermediate intrusive rocks show strong correlations with gold mineralisation, whereas metamorphic mafic rocks (greenstones) possibly acted as part of the broad regional environment for the mineral province rather than as a factor controlling the exact locations of the deposits; and (3) our predictive mapping indicates that the southeast part of the St Ives goldfield has a high potential for discovering new gold mineralisation. [Copyright &y& Elsevier]

Abstract: The zinc silicate willemite (Zn2SiO4) is the main carrier of zinc in a number of high-grade, carbonate-hosted nonsulfide deposits located in the southern hemisphere that have been recently reinterpreted to be of hypogene–hydrothermal origin. The timing of willemite mineralization in these deposits is only poorly constrained. In this pilot study, willemite has been evaluated as a potential Rb–Sr geochronometer that can be used to directly date nonsulfide ore deposits. We have analyzed samples of economic-stage willemite from the Berg Aukas and Abenab West deposits, Otavi Mountainland (Namibia), which are hosted by Neoproterozoic, dolomitized and tectonized carbonate rocks. Rb–Sr elemental concentration levels and ranges of 87Rb/86Sr and 87Sr/86Sr ratios in these willemite samples are comparable to those observed for the Zn sulfide sphalerite, which has been already successfully used for direct Rb–Sr dating of carbonate-hosted (MVT) deposits. This reflects similar Rb–Sr partitioning mechanisms into Zn ore minerals that precipitate either as sulfides from reduced or as silicates from oxidized hydrothermal fluids, respectively. The Rb–Sr results on willemite presented here reflect mostly low, but variable 87Rb/86Sr ratios, sufficient to generate radiogenic 87Sr over time. This clearly shows that willemite is suitable as an Rb–Sr geochronometer and should be further evaluated for direct Rb–Sr dating of nonsulfide Zn deposits. Isochron regressions combining samples from Berg Aukas and Abenab West willemites yield Rb–Sr ages in the range of ca. 500 to 560 Ma. These values are geochronologically doubtful at first sight due to high excess data scatter (MSWD=2000 to 3000). Massive, fine-grained willemite samples from Abenab West alone (n =3) give a – still statistically unacceptable (MSWD=60) – isochron regression corresponding to an Rb–Sr age of 574±84 Ma. More reliable ages are obtained from two statistically adequate small-scale Rb–Sr isochron regressions for samples of coarse-grained, well-crystallized Berg Aukas willemite, which yield 499±63 Ma (MSWD=2.6) and 493±2 Ma (MSWD=1.2), respectively. Regardless of the quality of isochron regressions in terms of MSWD, the Rb–Sr ages obtained in this study are fully compatible with other available geochronological data that reflect distinct tectonothermal events in the study area. Therefore, on a regional scale, they appear to be at least geologically reasonable, which has yet to be verified by further studies. Comparable mineralization ages in the range of ca. 490 to 550 Ma are also reflected by the few other known economic, hypogene willemite deposits in the southern hemisphere, for which direct geochronological information is mostly lacking. This may point to a global period of hydrothermal activity in the Cambrian to Lower Ordovician under conditions that favored the formation of hypogene nonsulfide Zn mineralization. [Copyright &y& Elsevier]

Abstract: Quantitative iron (oxyhydr-)oxide (Fe-Ox), AlOH-clay and carbonate abundance maps of the Rocklea Dome in Western Australia have been derived from hyperspectral visible-near to shortwave infrared (VNIR–SWIR) airborne data that were compensated for the influence of vegetation cover. The quantitative mineral maps were validated against field data, including ~5500 VNIR–SWIR spectra and ~300 portable X-ray fluorescence measurements. The error on these airborne mineral abundance estimates averages 13.4wt.% Fe for the Fe-Ox abundance, 4.0wt.% Al2O3 for the AlOH-clay abundance and 0.025 for the 2320D parameter used to quantify the carbonate abundance. The unmixed quantitative mineral abundance maps improve geological mapping, including characterisation and exploration for channel iron deposits (CID). In particular, some areas with outcropping CID, which appear subeconomic from the airborne Fe-Ox abundance map without vegetation removal, show as potentially economic CID resources when the influence of vegetation cover is unmixed from the airborne hyperspectral data. These results show that seamless maps of mineral contents can be achieved using data collected from both proximal (drill core and field) and remote (airborne and satellite) hyperspectral sensing systems. [Copyright &y& Elsevier]