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• The types and challenges of PVC waste management are discussed. • Dehydrochlorination and dechlorination of PVC are reviewed. • Recent progress in the chemical recycling technologies of PVC is summarized. • The dechlorination principles of different technologies are explained. • Chemical recycling treatments of PVC-containing plastic waste are summarized. The extensive production and consumption of plastics has resulted in significant plastic waste and plastic pollution. Polyvinyl chloride (PVC) waste has a high chlorine content and is the primary source of chlorine in the plastic waste stream, potentially generating hazardous chlorinated organic pollutants if treated improperly. This review discusses PVC synthesis, applications, and the current types and challenges of PVC waste management. Dechlorination is vital for the chemical recycling of PVC waste and PVC-containing plastic waste. We review dehydrochlorination and dechlorination mechanisms of PVC using thermal degradation and wet treatments, and summarize the recent progress in chemical treatments and dechlorination principles. This review provides readers with a comprehensive analysis of chemical recycling technologies for PVC waste and PVC-containing plastic waste to transform them into chemicals, fuels, feedstock, and value-added polymers. [ABSTRACT FROM AUTHOR]

Suction embedded plate anchors (SEPLAs) have been applied extensively in deepwater projects due to their high efficiency and low cost. In this paper, a new plasticity model was developed to simulate the keying behavior of SEPLAs. The model was based on three groups of yield envelopes, which considered three different states between the flap and the main plate. Thus, the plasticity model can consider the flap rotation relative to the fluke. The anchor shank was also considered to investigate the three dimensional (3D) effects of the actual SEPLA shape when deriving the yield envelops. A three dimensional large deformation finite element (3D-LDFE) model with flap rotation and shank considered was also set up. Then 3D-LDFE analysis was carried out to verify the plasticity model. The results given by 3D-LDFE analyses agree well with those by plasticity analyses. The effects of the flap on the embedment loss and pullout capacity, and the effects of loading eccentricity and pullout angle on diving behavior are investigated. Optimal padeye offset and pullout angle to drive the anchor diving are proposed. [ABSTRACT FROM AUTHOR]

[Display omitted] • H 2 production of seaweed hydrolysate was studied with C. tyrobutyricum. • Acetate assimilation significantly promotes mannitol digestion and H 2 evolution. • Mannitol generates more reducing power for hydrogen evolution pathway. • Mannitol evolves 42.02% higher H 2 and 40.82% higher butyrate than glucose. • High H 2 yield (2.33 mol/mol) and energy recovery (41.20 %) were obtained from seaweed. In this study, mannitol and mannitol-rich seaweed were fermented to investigate the relationship between substrate reduction degree and hydrogen production performance. The results showed that acetate was required in mannitol fermentation with an optimum acetate/mannitol mass ratio of 1:5. Hydrogen production and yield of mannitol fermentation reached 123.76 mL and 2.12 mol/mol-mannitol, respectively, 42.02 % and 26.95 % higher than that of glucose, respectively. The acetate was fully assimilated and the butyrate selectivity reached 100 % in the effluent. Redox potential and electron distribution showed that mannitol increased the overall electron input from mannitol and acetate, leading to the increase in hydrogen and butyrate generation. Hydrogen yield reached 2.33 mol/mol-mannitol with brown algae hydrolysate, which was the highest ever reported. This study demonstrated that substrate with a higher reduction degree could yield higher hydrogen and showed the great application potential of brown algae fermentation for the co-production of hydrogen and butyrate. [ABSTRACT FROM AUTHOR]

Gravity installed plate anchor (GIPLA) is made mainly of steel plates. It features a swivel mooring arm located close to the anchor tip. Its more complex geometry inevitably complicates the prediction of its keying behavior, hence its capacity. This paper investigated the development of GIPLA׳s movements during its keying and its pullout capacity in NC clay. A plasticity model of yield envelops was constructed and used to predict anchor keying behaviors and its capacities. The plasticity model was validated by 3D large deformation finite element analysis based on remeshing and interpolation technique with small strain model. A parametric study on the keying and capacity development of a deeply embedded GIPLA in NC clay was performed by the plasticity model due to its simplicity and efficiency. The effects of anchor loading angle, anchor padeye eccentricity and soil strength profile were investigated. To encourage anchor “diving” behavior after keying and to keep anchor capacity reasonably high, it was recommended that the anchor loading angle to the horizontal at mudline should be 30° or less and the anchor padeye offset angle be in the range of 15°~25°. The soil non-homogeneity due to the linearly varying strength profile also affect anchor keying trajectory. [ABSTRACT FROM AUTHOR]

Effective detection of pollutant gases is vital for protection of natural environment and human health. There is an increasing demand for sensing devices that are equipped with high sensitivity, fast response/recovery speed, and remarkable selectivity. Particularly, attention is given to the designability of sensing materials with porous structures. Among diverse kinds of porous materials, metal-organic frameworks (MOFs) exhibit high porosity, high degree of crystallinity and exceptional chemical activity. Their strong host-guest interactions with guest molecules facilitate the application of MOFs in adsorption, catalysis and sensing systems. In particular, the tailorable framework/composition and potential for post-synthetic modification of MOFs endow them with widely promising application in gas sensing devices. In this review, we outlined the fundamental aspects and applications of MOFs for gas sensors, and discussed various techniques of monitoring gases based on MOFs as functional materials. Insights and perspectives for further challenges faced by MOFs are discussed in the end. [Display omitted] • The classifications and functions of MOFs in gas monitoring are provided. • This review emphasizes the techniques of MOFs for monitoring gas interactions. • Roles of MOFs in gas sensors are classified into three items. [ABSTRACT FROM AUTHOR]

Abstract: A double-variable decoupling control scheme was proposed for GMAW-P process of aluminum helping to efficiently develop welding procedure. Weld pool width and arc length were both measured through vision sensing in welding process. Weld bead shape was improved by changing the current waveforms to adjust the heat input while the arc length was controlled to stabilize the welding process. An experimental system was developed to sense, observe and control the welding process real-timely. Experiments were conducted to verify the effectiveness of the scheme. The results show that good weld bead shape and stable welding process can be obtained through the double-variable decoupling control scheme without complex metal transfer control and considerable trial and error to identify suitable combinations of welding parameters in GMAW-P. This control scheme provides an alternative to obtain proper weld quality for GMAW-P. [Copyright &y& Elsevier]

The diastereoselective synthesis and biological activity of piperidine-3,4-diol and piperidine-3-ol-derived pyrrolotriazine inhibitors of anaplastic lymphoma kinase (ALK) are described. Although piperidine-3,4-diol and piperidine-3-ol derivatives showed comparable in vitro ALK activity, the latter subset of inhibitors demonstrated improved physiochemical and pharmacokinetic properties. Furthermore, the stereochemistry of the C3 and C4 centers had a marked impact on the in vivo inhibition of ALK autophosphorylation. Thus, trans -4-aryl-piperidine-3-ols ( 22 ) were more potent than the cis diastereomers ( 20 ). [ABSTRACT FROM AUTHOR]

Abstract: The synthesis and biological evaluation of potent and selective anaplastic lymphoma kinase (ALK) inhibitors from a novel class of 2,4-diaminopyrimidines, incorporating 2,3,4,5-tetrahydro-benzo[d]azepine fragments, is described. An orally bioavailable analogue (18) that displayed antitumor efficacy in ALCL xenograft models in mice was identified and extensively profiled. [Copyright &y& Elsevier]