1. Out-of-equilibrium thermodynamics analysis of lithium-ion batteries upon non-linear voltammetry fast charging.
- Author
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Li, Shiqi, Peng, Jimmy Chih-Hsien, and Yazami, Rachid
- Subjects
- *
OPEN-circuit voltage , *LITHIUM-ion batteries , *PHASE transitions , *THERMODYNAMICS , *NONLINEAR analysis - Abstract
We present an out-of-equilibrium thermodynamics method for lithium-ion batteries' (LIB) state-of-charge (SOC) assessment during ultra-fast charging using the non-linear voltammetry (NLV) algorithm. NLV consists of applying short constant voltage pulses followed by a very short relaxation period. The out-of-equilibrium open-circuit voltage during the relaxation period is addressed to as pseudo-open-circuit voltage (p-OCV). From the p-OCV temperature dependence, pseudo-entropy and pseudo-enthalpy are determined, denoted as p- Δ S and p- Δ H , respectively. It is found that the SOC follows the "Yazami theorem", which theorizes that SOC is a linear function of p- Δ S and p- Δ H. Out-of-equilibrium p- Δ S and p- Δ H together with incremental capacity (IC) analysis reveal different steps during the charging process, which are assigned to phase transitions in the LIB's anode and cathode materials. • Estimation of out-of-equilibrium thermodynamics during the fast charging process. • Analysis of non-linear voltammetry fast charging under various operating conditions. • High accuracy SOC assessment from out-of-equilibrium thermodynamics. • Battery temperature prediction during NLV ultra-fast charging. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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