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sawdust was valorized using acid-assisted hydrothermal carbonization and used in the removal of endocrine disruptor bisphenol A (BPA). The effect of acid addition on the hydrothermal carbonization of sawdust and removal of BPA was studied. Two different hydrochars were prepared using deionized water (HC D) and hydrochloric acid solution (HC AH) as feed water. The prepared hydrochars were characterized using FESEM, EDS, XRD, Raman spectroscopy, FTIR, TGA, and surface area analysis to study the structural and functional changes. Then they were compared in the removal of bisphenol A. Out of the two hydrochars prepared, acid-assisted hydrothermal carbonized hydrochar (HC AH) showed better removal efficiency. Hence, HC AH was used to study the influence of different parameters like pH, adsorbent dosage, and initial bisphenol A concentration by one variable at a time approach. Further, the study of interactive effects and optimization of adsorption of bisphenol A onto HC AH was carried out using RSM-CCD. The isotherm, kinetics, and thermodynamic studies revealed that the adsorption of bisphenol A could be explained by the Freundlich isotherm, pseudo-second-order kinetics fitted well in all the initial BPA concentrations, and the adsorption of bisphenol A onto HC AH was exothermic and spontaneous. [Display omitted] • The effect of acid-assisted hydrothermal carbonization of sawdust on the removal of bisphenol A was studied. • Various analytical techniques were used to compare the structural and functional changes with and without acid addition. • Acid-assisted hydrothermal carbonized hydrochar had higher aromaticity, aliphaticity, and oxygenated functional groups. • The optimization of adsorption of BPA onto acid hydrolyzed hydrochar was carried out using OVAT and RSM-CCD. [ABSTRACT FROM AUTHOR]

The rise in pharmaceutical pollutants due to their unregulated discharge in pharmaceutical wastewater has landed them as emerging contaminants that would gradually affect the aquatic ecosystem and human life. The current study emphasizes the adsorptive elimination of one such emerging pharmaceutical pollutant, i.e., Diclofenac (DIF), using a synthesized adsorbent vis. Activated carbon-chitosan beads (ACCB). The morphological and physicochemical properties of the prepared adsorbent, ACCB and its interaction with the DIF species were investigated. Process parameters influencing the adsorptive interactions between ACCB and DIF were optimised. DIF was efficiently adsorbed at optimised initial DIF pH of 6.0 and ACCB dosage of 1.5 mg/mL at an incubation temperature of 40 °C. Freundlich isotherm model showed the best fit (R2 = 0.98) with the experimental data to conclude that the adsorbent surface is heterogenous, promoting multilayer adsorption. As depicted from the Langmuir isotherm model, the maximum theoretical adsorption capacity was 99.29 mg/g. The seed toxicity assay confirmed the efficacy of ACCB in the adsorptive removal of DIF species from aqueous setups, making the post-treated solution fit enough for seed germination. [Display omitted] • Activated carbon-chitosan beads (ACCB) have been successfully synthesized. • The porous structure and frame network in ACCB were validated using scanning electron microscopy. • Recyclability and phytotoxicity analysis shows the efficacy of ACCB. • Spent ACCB was quickly and easily separated from the reaction mixture. [ABSTRACT FROM AUTHOR]