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The lipid content of three cores from Lake Enol (Picos de Europa National Park, Asturias, Northern Spain) was studied. The n- alkane profiles indicated a major input from terrigenous plants [predominance of high molecular weight (HMW) alkanes] since ca. 1695 AD to the water body, although the uppermost cm revealed a predominance of organic matter (OM) derived from algae, as the most abundant alkane was C 17 . Three units revealing different environmental conditions were defined. Unit A (ca. 1695–1860 AD) in the lowermost parts of ENO13-10 (< 12 cm) and ENO13-15 (< 28 cm) was identified and was characterized by higher OM input and evidence of minimal degradation (high CPI values, predominance of HMW n- alkanoic acids and good correspondence between the predominant n- alkane and n- alkanoic acid chains). These findings could be linked to the Little Ice Age, when cold and humid conditions may have favored an increase in total organic carbon (TOC) and n -alkane and n -alkanoic acid content (greater terrigenous OM in-wash), and may have also reduced bacterial activity. In Unit B (ca. 1860–1980 AD) the lack of correspondence between the n -alkane and n -alkanoic acid profiles of ENO13-10 (12–4 cm) and ENO13-15 (28–8 cm) suggested a certain preferential microbial synthesis of long chain saturated fatty acids from primary OM and/or bacterial activity, coinciding with a decrease in OM input, which could be linked to the global warming that started in the second half of the 19th century. In ENO13-7 the low OM input (low TOC) was accompanied by some bacterial degradation (predominance of HMW n- alkanoic acids but with a bimodal distribution) in the lowermost 16–5 cm. Evidence of considerable phytoplankton productivity and microbial activity was especially significant in Unit C (ca. 1980–2013 AD) identified in the uppermost part of all three cores (5 cm in ENO13-7, 4 cm in ENO13-10 and 8 cm in ENO13-15), coinciding with higher concentrations of n- alkanes and n- alkanoic acids, which were considered to be linked to warmer and drier conditions, as well as to greater anthropogenic influence in modern times. Plant sterols, such as β-sitosterol, campesterol and stigmasterol, were significantly present in the cores. In addition, fecal stanols, such as 24-ethylcoprostanol from herbivores, were present, thereby indicating a continuous and significant pollution input derived from these animals since the 17th century, being more important in the last 20 years. [ABSTRACT FROM AUTHOR]

We reconstructed the palaeoenvironmental conditions of Cartagena Bay during the Holocene after a multidisciplinary study to identify natural variations and the anthropic processes of this coastal area. A total of 119 samples were recovered for amino acid racemization dating, 3 for radiocarbon dating (14C), and four sets of 80 samples for sedimentological and palaeontological determination, mineralogical content, biomarker and trace elements quantification. Two natural scenarios were identified from the variations of n -alkane indices and palaeobiological content. The first period (6650–5750 yr cal BP) was marked by the development of euhaline marine conditions with strong inputs from aquatic macrophytes and high biodiversity. After a hiatus, the area underwent a profound change, becoming a paucispecific brackish marsh environment with increasing inputs from land plants, with possible episodes of emersion with a greater presence from terrestrial gastropods (3600–300 cal yr BP). By combining trace element abundance and stanol distributions, our study also provides a novel approach to identify the predominant influence of anthropogenic factors in the last three millennia in the coastal record of Cartagena Bay. Findings confirmed that Pb mining and metallurgy began during the Bronze Age, with considerable inputs of this heavy metal into the atmosphere during Phoenician, Punic and particularly Roman times compared to the Middle Ages. Pollution by Cu and Zn was also observed during Punic and Roman times, and was first documented in the Middle Ages. In addition, faecal stanols, such as coprostanol, derived mainly from humans, and 24-ethylcoprostanol from herbivores were present, thereby indicating for the first time a continuous presence of human populations and significant pollution input since 3600 yr cal BP, this being greater in the late Bronze Age and Phoenician, Punic and Roman times than during Late Antiquity and the Middle Ages, when the city was in decline. [Display omitted] • Euhaline marine conditions and high biodiversity occurred at 6650–5750 yr. • A paucispecific brackish marsh environment occurred at 3400–300 yr after an hiatus. • Faecal sterols revealed pollution from herbivores and humans since Bronze Age. • Pb–Zn–Cu linked to regional mining-metallurgy since Bronze Age to Middle Ages. [ABSTRACT FROM AUTHOR]

The inorganic content of the well-preserved 3.2-m record of Las Conchas bog (NW Spain), covering 8000 cal yr BP., was analysed. To study natural vs. human contributions, we applied an innovative approach, namely the sequential study of multivariate statistics (factor analysis followed by clustering of the factor score matrix) and enrichment factors (EFs). The increasing weight of potentially toxic elements (PTEs) such as the geochemical association of Zn, Pb and Cd (EFs higher than 10, 20 and 40 in the last two centuries) was revealed, and corroborated by the contrast between the contents of anthropogenic Pb and total Rare Earth Elements (a suitable proxy for natural geogenic supplies). Furthermore, elements such as Hg, Tl and As also showed enrichment in the most recent samples of the study core. Some of them are commonly associated with global atmospheric transport; however, in this case, their increasing contents could also be explained by nearby industrial and mining activities. In summary, severe pollution was observed in the uppermost part of the record, thereby pointing to an important environmental concern. Given that local and regional sources of PTEs, such as mining and heavy industry, especially Zn smelting, were probably the main historical causes of this contamination and that some of these industries are still active, we consider that our findings deserve further attention. Image 1 • Las Conchas bog has a preserved inorganic record of more than 8000 years BP. • Multivariate statistics revealed a notable anthropic input in the last 225 years. • Cd–Zn–Pb and Hg-As high contents mainly related to regional mining & industry. Capsule: Regional industrial and mining sources dramatically accelerated PTEs deposition in the last 225 years in NW Spain. [ABSTRACT FROM AUTHOR]

Here we reconstructed the evolution of the Mazarrón Basin during the Pleistocene and Holocene. In this regard, we studied 9 cores with the aim to: 1) define a chronological framework; 2) obtain data on the palaeoenvironment; and 3) establish the relationship with recent tectonics. A total of 158 samples were recovered for amino acid racemization (AAR) dating, 4 for radiocarbon dating (14C), and 332 for sedimentological and palaeontological determination, and 110 for determination of the mineralogical content. These approaches allowed us to elucidate the evolutionary phases of the palaeo-landscape of the Mazarrón Basin, a fault-controlled graben affected by diverse faults, mainly those of Las Moreras and Rella. The ages of the records and the facies correlation indicate that Las Moreras Fault controlled sedimentation during Marine Isotope Stage (MIS) 7, whereas the Rella Fault was strongly active during the Middle Holocene. During MIS7, a brackish lagoon developed in the western area, overlying alluvial fan deposits. Later, the area was uplifted, thereby becoming exposed to erosion. The activity of the Rella Fault allowed sedimentation in the western part of the Mazarrón Basin during the Middle Holocene, while in the Upper Holocene sedimentation occurred in the eastern part. The Holocene transgression was reflected in a temporarily floodable marsh in the hinterland, with changing salinity conditions, from brackish to euhaline waters. Along the sea front, the marine influence was evident but not dominant. Thus, the Mazarrón Basin during the Holocene was brackish to highly euhaline, with variable biological diversity linked to a narrow and probably discontinuous communication with the sea, with restricted circulation and long flushing times, which was reflected by the significant presence of halite. The record ended with recent alluvial/anthropic sediments. [ABSTRACT FROM AUTHOR]

At the northern tip of the Betic realm (SE Iberian Peninsula), some troughs (synclines) and elevations (anticlines) alternate, marking the present-day coastal lobed morphology of cape-bounded bays, where subsidence and uplift conditions prevailed, respectively. In this study, we were able to establish a clear coastal evolution. To this end, we considered the sedimentological and palaeoenvironmental conditions, the palaeogeographical reconstruction, and recent tectonics until Middle Pleistocene times (MIS 5) through the interpretation of onshore cores, raised marine deposits and geophysical profiles. In this regard, as reflected by both onshore and offshore information, there seems to be a stratigraphical gap from the end of the Pliocene to MIS 15 (Middle Pleistocene). In areas under uplift conditions, linked to tardive Alpine tectonics, the deposits of ancient shorelines and raised beaches were located at different post-depositional elevations, which were dated from odd MIS 15 to MIS 5 using amino acid racemization. Only deposits aged MIS 7 and MIS 5 are roughly at the present-day sea level or some meters above. In the troughs, which remain mostly as lagoons and salt marshes, subsidence did not allow the sedimentary record to be discerned. However, many borehole cores were recovered, attesting lagoonal, marsh, sabkha, or alluvial environmental conditions, which were usually unconnected from the sea. Micropaleontological and amino acid racemization dating revealed these cores to be of MIS15 to MIS5 age. Offshore seismic research revealed five erosive-bounded deposits that are stacked accretionary prisms corresponding to highstands between odd MIS 15 and MIS 5. In contrast, even MISs can be correlated to the erosive horizons that separated the seismic units, reflecting lowstands. In this regard, some bars, at a range of distances from the present-day coastline, protected wetlands from marine influence, allowing the development of diverse sub-environments under changing paleogeographical and paleoclimatological conditions. • Deposits of ancient shorelines and raised beaches were AAR dated from odd MIS 15 to 5. • MIS 7 & MIS 5 deposits are roughly at the present-day sea level or some meters above. • Ancient bars protected wetlands from marine influence allowing some sub-environments. • Offshore erosive-bounded deposits (stacked accretionary prisms) ensued in highstands. • Subsidence and uplift prevailed during Quaternary in the Iberian Mediterranean realm. [ABSTRACT FROM AUTHOR]

• Based on alkane indices, three geochemical units (GU) were identified. • GUs represent major contribution of aquatic macrophytes or terrestrial plants. • Paleoenvironmental episodes (PE) produced oscillations in the marsh water level. • PEs were related to sea level and climatic changes, and recent tectonics. • Emersion led to increased amounts of short-chain and branched fatty acids. We reconstructed the paleoenvironmental conditions of the Mazarrón Basin during MIS 7 and MIS 1 based on their alkane and fatty acid contents, their mineralogy and the fossil content of an amino-acid-dated sediment sequence. The n- alkane and fatty acid indices proved to be excellent paleoenvironmental proxies for studying the paleo-hydrogeological and paleoclimatological evolution of this marshland. Three geochemical units (GUs) were identified from the abundance of the C 25 n -alkane and the ACL, TAR HC and P aq values, confirming the importance of phases with terrestrial plant input or aquatic macrophyte predominance. These GUs were used to define three paleoenvironmental episodes (PEs) during MIS 7. In PE7.1, the contribution of algal and aquatic macrophytes predominated in a temporarily flooded saline muddy plain. In PE7.2, the major contribution was from aquatic macrophytes (flooded marsh), although it was marked by episodes of emersion with greater terrestrial contribution. At the top of the MIS 7 record (PE7.3), there was a significant reduction in the water depth, with the main input deriving from terrestrial plants in a muddy alluvial plain. Six PEs were established during MIS 1 (Holocene), of which three predominately received organic matter derived from aquatic macrophytes, while the major contribution in the other three came from terrestrial plants. The two sets of PEs were linked to episodes of increased and decreased water level, respectively. This interpretation is consistent with the characteristics of the sediment facies, with PE1.1, 1.3 and 1.5 corresponding to a marsh with deeper water and a greater input of detrital materials, and PE1.2, 1.4 and 1.6 to a shallow environment with carbonates and gypsum deposits. Direct marine influence was limited, so the oscillations in the water level in the marsh were likely to be more related to climatic changes (drier/wetter phases) and recent tectonics than to large changes in sea level. Emersion led to degradation of the organic matter and enrichment in short-chain and branched saturated fatty acids. [ABSTRACT FROM AUTHOR]

We determined the lipid distributions ( n- alkanes, n- alkan-2-ones, n- alkanoic acids), total organic carbon (TOC), total nitrogen (TN), Ca/Mg and ash content in Las Conchas mire, a 3.2 m deep bryophyte-dominated mire in Northern Spain covering 8000 cal yr BP. Bog conditions developed in the bottom 20 cm of the profile, and good preservation of organic matter (OM) was inferred from n- alkanoic acid distribution, with the exception of the uppermost 20 cm (last ca. 200 yr). Microbial synthesis of long chain saturated fatty acids from primary OM likely produced a dominance of short chain n- alkanoic acids with a bimodal distribution, as well as the lack of correspondence between the n -alkane and n -alkanoic acid profiles in the upper 20 cm. This was accompanied by an increase in ash content, a decrease in TOC and variation in n- alkane ratios, thereby suggesting significant changes in the mire, namely drainage and transformation to a meadow, in the last ca. 200 yr. The distribution of n- alkan-2-ones indicated an increase in bacterial source from the bottom of the record to 94 cm, whereas their distribution in the upper part could be attributed mainly to plant input and/or the microbial oxidation of n- alkanes. The different n- alkane proxies showed variations, which we interpreted in terms of changes in vegetation (Sphagnum vs. non-Sphagnum dominated phases) during the last 8000 cal yr BP. C 23 was the most abundant homolog throughout most of the record, thereby suggesting dominant humid conditions alternating with short drier phases. However, such humid conditions were not linked to paleoclimatic variation but rather to geomorphological characteristics: Las Conchas mire, at the base of the Cuera Range, receives continuous runoff—even during drier periods—which is not necessarily accompanied by additional mineral input to peat, producing the development of Sphagnum moss typical of waterlogged ecotopes and damp habitats. Thus, although geochemical proxies indicated an ombrotrophic regime in the mire, geomorphological characteristics may make a considerable contribution to environmental conditions. [ABSTRACT FROM AUTHOR]