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Abstract Trace element (As, Co, Cr, Cu, Ni, Pb, V and Zn) enrichment trends during the past century, were assessed in thirteen 210Pb-dated sediment cores from the southern Gulf of Mexico, with the purpose to evaluate the impact on the environment, and potentially on public health, of the offshore oil industry and of oil spills such as that of the Ixtoc1 well blowout in 1979. The trace element composition was quite homogeneous among cores; and the pre-industrial concentrations of Ba, Cr, Cu and Ni are naturally high in the region, as to reach levels of potential ecological concern. The influence of multiple and simultaneous processes (e.g. industrial activities, natural seeps, fluvial discharges) on the trace element concentrations is difficult to disentangle. Some cores suggested long-term preservation of putative oil spill traces, although it was not possible to attribute their origin. The Al-normalized redox element ratios, and the crude oil contamination ratio, suggested that these events occurred along almost four decades, and that the traces attributed to the Ixtoc1 spill were comparable to background conditions, most likely owing to active natural oil seeps in the area. In most cases there was a trend towards a lowering in the supply of trace elements; this might be associated with environmental controls in the region since the 1980s. This study highlights the relevance of using dated environmental archives to reconstruct the historical trends of trace metal contamination in areas where long-term environmental studies are scarce. Graphical abstract Unlabelled Image Highlights • Metal concentrations and enrichment trends were studied in southern Gulf of Mexico. • Metal enrichment evidenced weak to intense contamination within the past 100 years. • Metals result from simultaneous sources (oil industry, seeps, fluvial discharges). • Reducing metal concentrations since 1980s likely respond to environmental regulation. • Background and recent metal concentrations might be harmful to biota and humans. [ABSTRACT FROM AUTHOR]

Nutrient pollution causes environmental damages on aquatic ecosystems worldwide. Eutrophication produces impacts in coastal ecosystems, affecting biota and ecosystem services. The Urias coastal lagoon (SE Gulf of California) is a sub-tropical estuary under several environmental pressures such as nutrient inputs from shrimp farm effluents and dredging related to port operations, which can release substances accumulated in sediments. We assessed the water quality impacts caused by these activities and results showed that i) nitrogen was the limiting nutrient, ii) shrimp farm effluents increased particulate organic matter and chlorophyll a in the receiving stations, and iii) dredging activities increased nitrite and reduced dissolved oxygen concentrations. The co-occurrence of the shrimp farm releases and dredging activities was likely the cause of a negative synergistic effect on water quality which mainly decreases dissolved oxygen and increases nitrite concentrations. Coastal zone management should avoid the co-occurrence of these, and likely others, stressors in coastal ecosystems. [ABSTRACT FROM AUTHOR]

We present a study on the use of 239,240Pu as a chronostratigraphic marker to constrain 210Pb ages in young Holocene sediments from four coastal locations of Cuba (Caribbean Sea). The selected sites typify a variety of deposition environments such as a bay, a gulf, a coastal lagoon and a river estuary. The vertical distributions of 210Pb (and 226Ra), 239,240Pu and 137Cs in the sediment cores were determined in order to quantify the sedimentation processes. Mean activity ratios of 0.04 ± 0.01 for 238Pu/239,240Pu and 0.3 ± 0.2 for 241Am/239,240Pu indicated that atmospheric nuclear weapon tests (NWT) fallout was the main source of the anthropogenic radionuclides. Marine sites (Havana Bay and Gulf of Batabano) were characterized by low or negligible signals of 137Cs, which impeded its use as a chronostratigraphic marker. In the Sagua River Estuary and the Guanaroca Lagoon, where mixing of fresh and saline waters take place, depth profiles of 137Cs and 239,240Pu were in good agreement. A simple model that assumes a well-mixed reservoir in surface ocean waters and constant sediment accumulation was used to interpret the 239,240Pu profiles. The model corroborated the 210Pb ages, except in the case of the highly mixed sediment cores from the Gulf of Batabano. The apparent mean residence time of 239,240Pu in the well-mixed reservoir ranges from 5 to 50 years, with longer timescales for marine sites. 239,240Pu showed to be a useful time tracer in coastal sediments where the 137Cs signal is very low. [ABSTRACT FROM AUTHOR]

Abstract: Environmental archives, such as sediments, banded corals and tree rings, are widely used to reconstruct past environmental conditions of ecosystems. In particular, 210Pb has been used during more than 4 decades, through dating of undisturbed sediment cores, to study ecosystem changes during the last 100yr. Since its inception, diverse dating models have been proposed, developed, used and validated in numerous environments, but their nomenclature and formulation is not homogenous. In this work we emphasize that conceptual models used to date undisturbed sediment cores can be deduced from a single fundamental equation, which relates excess 210Pb concentration in sediment, its flux to the sediment surface and mass accumulation rate. From this equation, models were consistently named based on the main hypothesis used and, using a unified and logical nomenclature, dating equations were derived in detail. We applied in detail most of the described models to a sediment core from Mexico and uncertainty expressions were also included. Finally, some recommendations to use the models are proposed. We believe that this work can facilitate the use of 210Pb as a tool to date sediment cores in a more homogeneous way. [Copyright &y& Elsevier]

Abstract: During the reoccupation of the WOCE transect A10 at 30°S by the BEAGLE2003 cruise, the SHOTS project partners collected a large number of samples for the analysis of isotopic tracers. 137Cs was mostly deposited on the oceans surface during the late 1950s and early 1960s, after the atmospheric detonation of large nuclear devices, which mostly occurred in the Northern Hemisphere. The development of advanced radioanalytical and counting techniques allowed to obtain, for the first time in this region, a zonal section of 137Cs water concentrations, where little information existed before, thus constituting an important benchmark for further studies. 137Cs concentrations in the upper waters (0–1000m) of the south-eastern Atlantic Ocean are similar to those observed in the south-western Indian Ocean, suggesting transport of 137Cs labeled waters by the Agulhas current to the Benguela Current region. In contrast, bomb radiocarbon data do not show this feature, indicating the usefulness of 137Cs as a radiotracer of water mass transport from the Indian to the South Atlantic Ocean. [Copyright &y& Elsevier]

Abstract: The vertical distribution of Hg and Pb were determined in a sediment core collected from the Sagua estuary (North Cuba) that receives input from the Sagua river, one of the most polluted rivers discharging into the Cuban coastal environment. Depth profiles of metal concentrations were converted to time-based profiles using the 210Pb dating method and confirmed with the 137Cs fallout peak. The mean mass accumulation rate was estimated to be 0.17±0.04gcm−2 y−1 (mean sediment accumulation rate 0.52±0.13cmy−1) and the core bottom was estimated to date back about 130years. The historical sedimentary record showed a strong enrichment of mercury concentrations in the past decades, caused by the incomplete treatment of industrial wastes from a chlor-alkali plant with mercury-cell technology in the Sagua river basin. Lead fluxes to sediments showed a gradual increase from the 1920s to present, which agrees with a population increase in Sagua la Grande City. Fluxes of both metals have increased the past 25years, with values reaching a maximum of 0.5 and 3.9μgcm−2 y−1 for Hg and Pb, respectively. [Copyright &y& Elsevier]

Abstract: The DYFAMED site (Ligurian Sea, 43°25′N; 7°52′E) has been the subject of multidisciplinary research since 1987, including the study of atmospheric deposition of metals and their association with marine particles in the water column. On the other hand, the attention paid to the underlying sediments as the ultimate repository of elements, particularly pollutants, has been considerably lesser. Through the combined use of 210Pb chronologies and elemental analysis, we studied the concentrations and fluxes of trace metals (Zn, Pb, Ni, Cu, Cr) in a sediment core collected from ∼2300m water depth at the seafloor beneath DYFAMED. Surface metal enrichment during the 20th century is apparent in the case of Pb, Zn and Cu (maximum enrichment factors 1.5, 1.2 and 1.4, respectively). A comparison with published data suggests that atmospheric deposition is the main entrance route of anthropogenic trace metals accumulated in the recent sediments, while lateral advection of sediments by currents and sediment gravity flows is proposed to account for the pre-industrial concentrations of metals. Recent atmospheric inputs of Pb and Cu are more efficiently stored in sediments with respect to Zn, most of which is apparently advected elsewhere. [Copyright &y& Elsevier]

Abstract: A new Certified Reference Material (CRM) for radionuclides in sediment (IAEA-385) is described and the results of the certification process are presented. Eleven radionuclides (40K, 137Cs, 226Ra, 228Ra, 230Th, 232Th, 234U, 238U, 238Pu, 239+240Pu and 241Am) have been certified and information mass activities with 95% confidence intervals are given for seven other radionuclides (90Sr, 210Pb(210Po), 235U, 239Pu, 240Pu and 241Pu). Results for less frequently reported radionuclides (60Co, 99Tc, 134Cs, 155Eu, 224Ra and 239Np) and information on some activity and mass ratios are also reported. The CRM can be used for quality assurance/quality control of the analysis of radionuclides in sediment samples, for the development and validation of analytical methods and for training purposes. [Copyright &y& Elsevier]

Abstract: Society''s growing interest in environmental issues requires the production of reliable information for policy-makers, stakeholders and society in general. This information must be based on accurate data produced by qualified laboratories and data need to be comparable between numerous laboratories for joint assessments, e.g. in International Conventions. The Marine Environment Laboratories of the International Atomic Energy Agency has been providing Quality Assurance services to laboratories involved in marine radioactivity studies for the past 30 years. This has included training, organization of laboratory intercomparison exercises, production of Reference Materials (RMs) and more recently, production of Certified Reference Materials (CRMs) that comply with relevant ISO standards. Here, the overall process of Certification of Reference Materials is reviewed, past work summarized and future needs of marine radioactivity laboratories briefly discussed. [Copyright &y& Elsevier]

Abstract: A certified reference material (CRM) for radionuclides in fish sample IAEA-414 (mixed fish from the Irish Sea and North Seas) is described and the results of the certification process are presented. Nine radionuclides (40K, 137Cs, 232Th, 234U, 235U, 238U, 238Pu, 239+240Pu and 241Am) were certified for this material. Information on massic activities with 95% confidence intervals is given for six other radionuclides (90Sr, 210Pb(210Po), 226Ra, 239Pu, 240Pu 241Pu). Less frequently reported radionuclides (99Tc, 129I, 228Th, 230Th and 237Np) and information on some activity and mass ratios are also included. The CRM can be used for quality assurance/quality control of the analysis of radionuclides in fish sample, for the development and validation of analytical methods and for training purposes. The material is available from IAEA, Vienna, in 100g units. [Copyright &y& Elsevier]

210Pb was analysed in samples collected from (16) sediment traps, deployed during 1 year on the Northwestern Mediterranean continental margins, within the framework of the (MTP I)-EUROMARGE-NB programme. The traps were moored within (5) submarine canyons and their adjacent open slope, corresponding to contrasting conditions of particle inputs (fluxes and constituents). The major meso-scale observation (at the margin) is the variation in 210Pb fluxes along the slope, increasing by a factor of 2–3 between the entrance and the exit of the slope, in relation to the general (water) circulation. At a smaller scale (canyon), the 210Pb fluxes showed trends which were common to the various sites, i.e. a seaward decrease at 500 m depth and an increase, with depth, in the canyons. All these features are related to mass flux variations, except for periods with huge mass fluxes, when 210Pb fluxes reached a constant value. 210Pb activities decreased with increasing mass flux; then did not show clear relationship with the concentration of the major constituents of the flux.210Pb fluxes, obtained from the traps were mainly in excess of the theoretical 210Pb flux, available in the overlying water column. Since 210Pb inventories, measured on the basis of the shelf and slope bottom sediments, were also in excess in relation to the available flux. The margin, as a whole, appears as a sink for 210Pb. This boundary-scavenging process appears to be controlled completely by the mass flux of particles. Differences were observed between 210Pb fluxes in the near-bottom traps and in the underlying sediments; there can be linked to mass flux and/or morphobathymetry (the trap flux is higher than the sediment flux in the canyon, but lower on the open slope). Overall, the differences were not in excess of 50%, confirming good representation of data collected by the sediment traps. However, this finding must be taken into account when comparing organic carbon or other constituent fluxes, between the traps and the sediment. [Copyright &y& Elsevier]

Laboratories from 14 countries (with different levels of expertise in radionuclide measurements and 210Pb dating) participated in an interlaboratory comparison exercise (ILC) related to the application of 210Pb sediment dating technique within the framework of the IAEA Coordinated Research Project. The laboratories were provided with samples from a composite sediment core and were required to provide massic activities of several radionuclides and an age versus depth model from the obtained results, using the most suitable 210Pb dating model. Massic concentrations of Zn and Cu were also determined to be used for chronology validation. The ILC results indicated good analytical performances while the dating results didn't demonstrate the same degree of competence in part due to the different experience in dating of the participant laboratories. The ILC exercise enabled evaluation of the difficulties faced by laboratories implementing 210Pb dating methods and identified some limitations in providing reliable chronologies. • Interlaboratory comparison exercise (ILC) finds difficulties of the Pb-210 method. • ILC results indicate good analytical performance of the participants. • ILC dating results did not show the same degree of confidence. [ABSTRACT FROM AUTHOR]

The development of the Grijalva-Usumacinta river basin exerts modifications on its discharge area. A sediment core was studied to reconstruct environmental changes and trace element contamination status during the past 45 years. 210Pb-derived mass accumulation rates indicate higher sediment input to the area since 1995, related to increased precipitation and floodings in the catchment area. Sediments show finer particles from the late 1970s on, likely related to dams construction upriver and/or land use changes. Heavy metal enrichment factors (EF < 2) suggest minimum contamination. Benthic foraminifera and redox-sensitive - elements (As, Ba, Co, Cr, Cu, Ni, Pb, V and Zn) indicate the sediments before 2000 were deposited under oxygenated conditions. Afterwards, environmental conditions changed and benthic foraminifera and dinocysts assemblages changed suggesting eutrophication and lower oxygen conditions during the last 20 years. Monitoring should be continued to assess eutrophication/hypoxic/pollution trends that could become deleterious to the marine biota. • Sediments from past 45 years record environmental changes in the marine area off the largest river in southern Gulf of Mexico • Mass accumulation rates indicate higher sediment input to the area since 1995. • Higher sediment input related to increased precipitation and flooding in Tabasco City and the catchment area. • Grain size variation reflects land use change and damming since the 1980s. • Benthic Foraminifera and Dinocysts indicate a process of eutrophication in bottom waters during the last 20 years. [ABSTRACT FROM AUTHOR]

Spatial and temporal variability of mercury concentrations in sediments was evaluated in 210Pb-dated sediment cores from offshore and intertidal areas in the southern Gulf of Mexico. In offshore cores, mercury concentrations were comparable (11.2–69.2 ng g−1), and intermediate between concentrations in intertidal cores from the eastern (6.0–34.4 ng g−1) and the western (34.9–137.7 ng g−1) inlets of Términos Lagoon. The enrichment factor (EF) indicated minimal contamination (EF < 2) in most offshore cores, whereas in some intertidal cores steadily increasing mercury enrichment and fluxes were observed along the past century. No evidence of oil industry related mercury contamination was found, as the minor but increasing enrichment in intertidal cores is most likely related to land-derived sources such as catchment eroded soils and waste water runoff. Results highlight the importance to control catchment erosion and untreated sewage releases to reduce mercury loadings to the coastal zone. Unlabelled Image • Hg contamination trends were studied in sediment cores of southern Gulf of Mexico. • Null to minor Hg enrichment was observed during the past 100 years in the area. • Recent Hg concentrations in most offshore cores were close to preindustrial levels. • Minor Hg contamination in intertidal areas is likely associated to surface runoff. • Hg concentrations are not a risk to benthic biota in the region. [ABSTRACT FROM AUTHOR]

Coastal vegetated habitats can be important sinks of organic carbon (C org ) and mitigate global warming by sequestering significant quantities of atmospheric CO 2 and storing sedimentary C org for long periods, although their C org burial and storage capacity may be affected by on-going sea level rise and human intervention. Geochemical data from published 210 Pb-dated sediment cores, collected from low-energy microtidal coastal wetlands in El Salvador (Jiquilisco Bay) and in Mexico (Salada Lagoon; Estero de Urias Lagoon; Sian Ka'an Biosphere Reserve) were revisited to assess temporal changes (within the last 100 years) of C org concentrations, storage and burial rates in tropical salt marshes under the influence of sea level rise and contrasting anthropization degree. Grain size distribution was used to identify hydrodynamic changes, and δ 13 C to distinguish terrigenous sediments from those accumulated under the influence of marine transgression. Although the accretion rate ranges in all sediment records were comparable, C org concentrations (0.2–30%), stocks (30–465 Mg ha −1 , by extrapolation to 1 m depth), and burial rates (3–378 g m −2 year −1 ) varied widely within and among the study areas. However, in most sites sea level rise decreased C org concentrations and stocks in sediments, but increased C org burial rates. Lower C org concentrations were attributed to the input of reworked marine particles, which contribute with a lower amount of C org than terrigenous sediments; whereas higher C org burial rates were driven by higher mass accumulation rates, influenced by increased flooding and human interventions in the surroundings. C org accumulation and long-term preservation in tropical salt marshes can be as high as in mangrove or temperate salt marsh areas and, besides the reduction of C org stocks by ongoing sea level rise, the disturbance of the long-term buried C org inventories might cause high CO 2 releases, for which they must be protected as a part of climate change mitigation efforts. [ABSTRACT FROM AUTHOR]

Abstract: The accumulation, enrichment and provenance of selected trace metals (Ag, As, Cd, Cr, Cu, Hg, Ni, Pb, V and Zn) were studied in sediment cores collected from three lakes located in the Central Mexican Plateau, selected on the basis of their contrasting degree of urbanization: Santa Elena Lake, in a rural and remote area; El Tule Lake, in a rural and slightly urbanized area; and Chapala Lake, in a highly urbanized area. Grain size, magnetic susceptibility and sedimentary constituents such as organic carbon, calcium carbonate, as well as major (Al, Fe, Mn) and minor (Ca, Li, Rb, Sr, Th) elements were analyzed to explain the concentration trends of trace metals. Factor analysis (FA) was used to assess the provenance of the trace elements. The highest metal enrichment factor (EF) above natural concentration levels was found at Chapala Lake for Ag (EF=3.9), although other trace element EF in all lakes was <2.0, indicating slight contamination. However, the concentration levels of Cr and Ni in all lakes, Hg and Zn in Chapala Lake, Cu in El Tule Lake and As in Santa Elena Lake were above international benchmarks for which adverse effects are expected to occur frequently, even for those metals only slightly enriched (e.g. As, Cr). Through FA, the terrigenous contribution was identified as the most important source of trace metals to the three lakes, most likely related to deforestation and erosion of the surrounding areas, followed by atmospheric transport of volcanic ashes, rather than to direct sources. [Copyright &y& Elsevier]

• C org burial was evaluated in seagrass sediments at the northern Mexican Caribbean. • Thalassia testudinum seagrass meadows showed C org storage within ~ 40 to ~ 100 years. • C org stock increments were related with increasing sediment accumulation rates. • Seagrasses might be gradually impacted by population growth and land use changes. Carbon sequestration in seagrass meadows mitigates the currently rising CO 2 atmospheric levels, as these ecosystems are highly productive and preserve sediment organic carbon over long periods. Five 210Pb dated sediment cores, collected from seagrass meadows dominated by Thalassia testudinum in the northern Mexican Caribbean touristic corridor Cancun-Riviera Maya, were used to establish temporal trends of organic carbon (C org) content, burial rates and stock variation over the past 100 years. C org contents (0.17–1.94%) and burial rates (2.0–252 g m−2 yr−1) were generally within the lower end range reported for seagrass meadow sediments worldwide. C org stock gradually increased over the past decades, associated with increasing sediment accumulation, possibly caused by inland erosion promoted by agricultural and forestry activities and, in the recent decades, by a rapid increase of urban development due to a fast growth of the tourist industry and population, likely causing fertilization of coastal waters. Seagrass meadow sediments in the northern Mexican Caribbean coastline showed long-term C org storage and preservation, since ~ 40 to ~ 100 years depending on the core, which emphasizes the need to protect these ecosystems against impacts of global change, and their incorporation into climate change mitigation strategies should be considered. [ABSTRACT FROM AUTHOR]

The Campeche Sound is the major offshore oil producing area in the Southern Gulf of Mexico (SGoM). To evaluate the impact of oil related activities in the ocean floor sediments, we analyzed the geochemical (major and trace element, organic carbon and hydrocarbon concentrations) and biological (benthic foraminifera) composition of 62 superficial sediment samples, from 13 to 1336 m water depth. Cluster and Factor analysis of all the variables indicate that their distribution patterns are mainly controlled by differences between the terrigenous and carbonate platforms in the SGoM. Benthic foraminiferal assemblages were abundant and diverse, and their distribution patterns are mainly determined by water depth and sedimentary environment. However, most of the abundant species are opportunistic and/or low-oxygen tolerant, and many of their tests show oil stains and infillings, characteristic of oil polluted locations, suggesting the environment has been modified by natural seepage or oil-related activities. To determine if these conditions are natural or anthropogenic in origin, pre - industrial settings should be studied. Organic carbon (Corg) content (0.6–2.9%) and total hydrocarbon concentrations (PAHs 1.0–29.5 μg kg−1) were usually higher around the oil platforms area, the natural hydrocarbon seeps ("chapopoteras") area and offshore rivers, but there is no accumulation of oil related trace elements in these areas. However, the comparison with international sediment quality benchmarks indicates that Cd, Cr and Ni concentrations are above the threshold effect level, and also As, Ba and Cu are above the probable effect level benchmarks, which indicate that these element concentrations might be of potential ecological concern. Comprehensive studies involving different proxies, and assessing pre-industrial conditions, must be undertaken before assessing environmental health of marine benthic ecosystems. • Impact of oil related activities on ocean floor sediments was assessed. • Benthic Foraminifera (microbenthos) show impact of various oil derived sources. • Concentrations of As, Ba and Cu might be of potential ecological concern.. • Organic carbon and PAHs content are greater in oil exploitation and seep areas. • Campeche Bay is affected by multiple stressors, both natural and anthropogenic. [ABSTRACT FROM AUTHOR]

Abstract: The anthropogenic radionuclides such as 137Cs, 90Sr, 99Tc, 129I and some transuranics are important tracers of transport and biogeochemical processes in the ocean. 137Cs, with a half-life of 30years, a major fission product present in a dissolved form in seawater, is a good tracer of oceanic circulation at a time scale of several decades. At WOCE P6 line along 30°S during the BEAGLE cruise in 2003, surface seawater (around 80L) was collected a few meters below the ocean surface by a pumping system. Water column samples (from 5 to 20L) were collected using a Rosette multisampling system and Niskin bottles. 137Cs was separated from seawater samples using ammonium phosphomolybdate (AMP) and analysed for 137Cs in low-level HPGe gamma-ray spectrometers. Results allowed to draw a detailed picture of the distribution of 137Cs in the South Pacific Ocean along P6 line. A 137Cs depth section was depicted from about 160 samples. 137Cs concentrations in the subsurface layers ranged from 0.07±0.04Bqm−3 to 1.85±0.145Bqm−3, high in the Tasman Sea and very low in the eastern region where upwelling occurs. Water column inventories of 137Cs from surface to 1000dbar depth ranged from 270±104 to 1048±127Bqm−2. It was concluded that the source of higher 137Cs concentration and inventories in the Tasman Sea was 137Cs deposited in the mid latitude of the North Pacific Ocean and transported across the equator during four decades. [Copyright &y& Elsevier]

Abstract: Vertical profiles of dissolved plutonium activity concentration in South Pacific Ocean water columns were determined using ICP-SF-MS after Fe co-precipitation and radiochemical purification. The water samples were collected in the central South Pacific mid-latitude region (32.5°S) during the BEAGLE2003 expedition conducted in 2003–2004 by the Japan Agency for Marine-Earth Science and Technology. 239Pu concentrations in surface water were around 1mBqm−3. Concentrations reached a maximum (6mBqm−3) at 600–800m, and then decreased with increasing depth. The vertical profile pattern was similar to that observed in the North Pacific subtropical gyre, although concentrations of 239Pu in the deep South Pacific were significantly lower than those in the North Pacific subtropical gyre. The 239Pu/137Cs activity ratios, which reflect biogeochemical processes in seawater, increased exponentially from the surface to 1500m depth, whereas in deep waters they were almost constant. The estimated 239,240Pu inventories in the South Pacific water column (0–2300m) were of the same order of magnitude as previous estimates in 1996 (15°S, 148°W); however they were about one order of magnitude lower than those in the western North Pacific. [Copyright &y& Elsevier]

Abstract: The Japan Agency for Marine Earth Science and Technology conducted in 2003–2004 the Blue Earth Global Expedition (BEAGLE2003) around the Southern Hemisphere Oceans, which was a rare opportunity to collect many seawater samples for anthropogenic radionuclide studies. We describe here sampling and analytical methodologies based on radiochemical separations of Cs and Pu from seawater, as well as radiometric and mass spectrometry measurements. Several laboratories took part in radionuclide analyses using different techniques. The intercomparison exercises and analyses of certified reference materials showed a reasonable agreement between the participating laboratories. The obtained data on the distribution of 137Cs and plutonium isotopes in seawater represent the most comprehensive results available for the Southern Hemisphere Oceans. [Copyright &y& Elsevier]

Abstract: The distribution of 239Pu in Atlantic and Indian Ocean waters about four decades after their main injection from atmospheric nuclear weapons tests is discussed. Recent data obtained in the framework of the SHOTS (Southern Hemisphere Ocean Tracer Studies) projects are evaluated and compared with previous investigations. Seawater samples were collected during the round the globe BEAGLE2003 (Blue Ocean Global Expedition) along the 30°S transect in the Atlantic and the 20°S transect in the Indian Ocean. The results indicate transport of surface waters labelled with 239Pu from the western North Pacific via the Indonesian Seas to the South Indian Ocean and then to the South Atlantic Ocean. Along the whole BEAGLE2003 sampling route, the Atlantic Ocean has the lowest 239Pu content due to its particle scavenging on the long way from the western North Pacific. On the other hand, concentrations of the conservative 137Cs tracer are in all three oceanic basins comparable. The primary productivity reflected by the chlorophyll content in surface waters has similar longitudinal distribution as 239Pu. Radioactive and chlorophyll tracers revealed that the most important current system in each southern oceanic basin is represented by the Subtropical gyre. While the main streams of the gyres maintain high concentrations of tracers, inside the loops the tracer concentrations are the lowest. [Copyright &y& Elsevier]

Abstract: The measurement of plutonium isotopes, 239Pu and 240Pu, at 670kV on the compact accelerator mass spectrometry (AMS) system at the Centro Nacional de Aceleradores (CNA) in Seville, Spain, is now a reality. In this work, we present first Pu AMS results for environmental samples: a sediment core collected in a submarine canyon in the Mediterranean coast of the Spanish region of Palomares, affected by a nuclear accident in 1966. From the study of the 240Pu/239Pu atomic ratio profile, showing on average levels lower than 11%, we confirm that the weapon-grade plutonium released on land during the accident, with a characteristic 240Pu/239Pu atomic ratio of 5.8%, has found its way into the marine environment. A two-plutonium sources mixture model (Palomares and fallout) is used to elucidate the percentage of the plutonium coming from the accident. As a validation exercise of the Pu AMS measuring technique and in order to obtain the 238Pu/(239+240)Pu activity ratios, samples were also studied by alpha-spectrometry (AS). The obtained AS 239+240Pu activity concentration results fit in with the AMS ones in a wide dynamic range, thus validating the AMS technique. [Copyright &y& Elsevier]

Artificial radionuclides enter the Mediterranean Sea mainly through atmospheric deposition following nuclear weapons tests and the Chernobyl accident, but also through the river discharge of nuclear facility effluents. Previous studies of artificial radionuclides impact of the Mediterranean Sea have focussed on shallow, coastal sediments. However, deep sea sediments have the potential to store and accumulate pollutants, including artificial radionuclides. Deep sea marine sediment cores were collected from Mediterranean Sea abyssal plains (depth >2000 m) and analysed for 239,240Pu and 137Cs to elucidate the concentrations, inventories and sources of these radionuclides in the deepest areas of the Mediterranean. The activity — depth profiles of 210Pb, together with 14C dating, indicate that sediment mixing redistributes the artificial radionuclides within the first 2.5 cm of the sedimentary column. The excess 210Pb inventory was used to normalize 239,240Pu and 137Cs inventories for variable sediment fluxes. The 239,240Pu/210Pb xs ratio was uniform across the entire sea, with a mean value of 1.24×10−3, indicating homogeneous fallout of 239,240Pu. The 137Cs/210Pb xs ratio showed differences between the eastern (0.049) and western basins (0.030), clearly significant impact of deep sea sediments from the Chernobyl accident. The inventory ratios of 239,240Pu/137Cs were 0.041 and 0.025 in the western and eastern basins respectively, greater than the fallout ratio, 0.021, showing more efficient scavenging of 239,240Pu in the water column and major sedimentation of 137Cs in the eastern basin. Although areas with water depths of >2000 m constitute around 40% of the entire Mediterranean basin, the sediments in these regions only contained 2.7% of the 239,240Pu and 0.95% of the 137Cs deposited across the Sea in 2000. These data show that the accumulation of artificial radionuclides in deep Mediterranean environments is much lower than predicted by other studies from the analysis of continental shelf sediments. [Copyright &y& Elsevier]

The present plutonium and 137Cs concentrations in South Pacific Ocean surface waters were determined. The water samples were collected in the South Pacific mid-latitude region (32.5 °S) during the BEAGLE expedition conducted in 2003–04 by JAMSTEC. 239,240Pu concentrations in surface seawater of the South Pacific were in the range of 0.5 to 4.1 mBq m−3, whereas 137Cs concentrations ranged from 0.07 to 1.7 Bq m−3. The observed 239,240Pu and 137Cs concentrations in the South Pacific were almost of the same level as those in the North Pacific subtropical gyre. The surface 239,240Pu in the South Pacific subtropical gyre showed larger spatial variations than 137Cs, as it may be affected by physical and biogeochemical processes. The 239,240Pu/137Cs activity ratios, which reflect biogeochemical processes in seawater, were generally smaller than that observed in global fallout, except for the most eastern station. The 239,240Pu/137Cs ratios in the South Pacific tend to be higher than that in the North Pacific. The relationships between anthropogenic radionuclides and oceanographic parameters such as salinity and nutrients were examined. The 137Cs concentrations in the western South Pacific (the Tasman Sea) and the eastern South Pacific were negatively correlated with the phosphate concentration, whereas there is no correlation between the 137Cs and nutrients concentrations in the South Pacific subtropical gyre. The mutual relationships between anthropogenic radionuclides and oceanographic parameters are important for better understanding of transport processes of anthropogenic radionuclides and their fate in the South Pacific. [Copyright &y& Elsevier]

Discusses a study which assessed the sediment, carbon and nitrogen accumulation rates along a high-productivity area, Gerlache Strait, Antarctica. Sample collection and analytical methods; Results; Discussion.