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The Late Cretaceous Marilia Formation located in the central-southern portion of Brazil is characterized by a succession of sandstones, conglomerates, and paleosols. The paleosols constitute more than 60% of this formation, providing significant information about pedogenetic processes as well as paleoenvironmental and paleoclimate implications. The paleosols of the Marilia Formation have been studied principally from a stratigraphical, sedimentological and paleopedological point of view; however, there are no studies addressing in detail the geochemical behavior of the paleosols. Therefore, we used a robust geochemical dataset combined with stratigraphical and macromorphological interpretations as well as clay mineralogy to conduct a paleoenvironmental and paleoclimate analysis of the Marilia Formation in the western portion of the state of Minas Gerais in Brazil. The results indicate that the paleosols of the Marilia Formation can be divided into three pedotypes and pedochemical units based on their geochemical variations and are limited at the base and top by pedochemical markers. Moreover, X-ray diffraction identified quartz and calcite as primary minerals associated with montmorillonite, smectite, illite and palygorskite, indicating wet periods combined with dry stages associated principally with dry and arid environments. The paleosol distribution and weathering index allow us to interpret the paleoenvironmental evolution of the Late Cretaceous Marilia Formation, suggesting an increase in humidity from east to west in the study area.

The Eastern Marlim oilfield, located in the northeastern offshore of the Campos Basin, is a portion of the Marlim Complex, one of the most important oil accumulations ever found in Brazil. This paper presents findings from lithofacies, sequence stratigraphy and petrophysical analyses for the Oligocene-Miocene section of the Eastern Marlim oilfield. Here, we evaluate at least four main lithofacies associations and three major zones recognized in the latter section, presenting sedimentological and stratigraphical interpretations based on stratigraphic correlations, distribution and sand proportion maps, and accompanying petrophysical analysis. Our findings suggest at least two bipartite turbiditic flows representing different stages of deposition associated with a deep-water turbidite sequence, composing the elements of a submarine lobe complex. Massive unconsolidated amalgamated sandstone bodies, displaying very good porosity, lateral and vertical continuity, reflecting excellent reservoirs. The final depositional model of the studied Oligocene-Miocene interval in this work is part of the first-order Highstand System Tract (HST) of the Campos Basin, which in turn represents a second-order, exploration-scale depositional sequence. Finally, the sequence stratigraphic model of the Oligocene-Miocene section of the Eastern Marlim oilfield has an architecture similar to those that have been developed from Oligocene-Miocene global sea level changes.

Rhizoliths are organosedimentary structures produced by plants and are an important proxy for paleoenvironmental reconstructions because the differences in the morphology of rhizoliths and their rooting depths can be used to interpret soil humidity regimes, overall biomass at the soil surface, and the behavior of the water table. With the objective of advancing knowledge on rhizoliths, a study was performed on the macromorphological and micromorphological characterizations of the rhizoliths preserved in the thirty-one paleosols of the Marilia Formation in Minas Gerais, southeastern Brazil. Based on the topological and architectural attributes of rhizoliths, and on their possible functional adaptations, such as mycorrhizal associations, three different types of rhizoliths are described in this study and represent at least three different plants: rhizohaloes, root casts and rhizocretions. Well-developed paleosols with nodular horizons contain the higher density of long root casts, indicating a seasonally dry environment, because the root casts present two meters in length. These adaptations are associated with an exploitation of a lowered water table during most times of the year. The higher density of rhizoliths indicates an area with agglomerated arboreous arbustive vegetation cover. Paleosols with chalky horizons also show a high density of root casts, indicating a landscape with high plant density that is adapted to drained soils, but with a seasonally elevated water table or the influence of ephemeral flows, given the proximity to the flow channels. The poorly drained paleosols with redoximorphic features show the lowest density of rhizoliths, thus indicating an incipient vegetation in response to near-surface water table and waterlogged soils in a distal floodplain. The rhizogenic laminar horizons have developed near fluvial channels with frequent sedimentary input, resulting in a sequence of laminar horizons composed of rhizocretions that are separated by sandy deposits or poorly developed pedogenic horizons. The micromorphological analysis on the rhizogenic laminar calcretes showed biogenic features, such as alveolar septal structures, calcified filaments, microcodium, calcified cells and pisoliths. Despite the scarce paleobotanical findings in the Marilia Formation, the results obtained indicate an ecosystem that was composed of plants varying from herbaceous to arboreous, with an environment similar to modern semiarid shrublands.

The current research was performed in the eastern portion of the Marlim oilfield to identify the hydrocarbon-generating potential of the Albian-Oligocene sequences (Macae Group, Ubatuba and Carapebus formations) in the Campos Basin, Brazil. On the basis of petroleum geochemical proxies, an integrated approach was developed using source rock characterizations to establish the distribution of source rock properties, such as organic matter content, hydrocarbon-generating potential, thermal maturity and stratigraphic thickness. The outcomes of a comprehensive petroleum geochemical characterization were integrated with cuttings and core sample descriptions, biostratigraphic controls, well log analyses and 2-D/3-D seismic interpretations. Our results reveal that for the Albian-Oligocene deposits, the key geochemical properties required to develop hydrocarbon source kitchens converge in specific locations, demonstrating a variable hydrocarbon potential ranging from poor to excellent and suggesting the existence of local generation pods in the central and principally northern portions of the research area. The accumulation and preservation of the organic matter were influenced by the paleo-topography and tectonic controls, and the lowest concentrations of organic carbon were attributed to significant siliciclastic dilution taking place mostly toward the middle and southern portions of the Eastern Marlim oilfield. Lateral variations in both the lithofacies and organic facies are the main conditions controlling the behavior of the petroleum potential in the investigated sediments. Our results indicate that the Macae Group has sufficient source-rock potential, maturation patterns, and hydrocarbon-generating potential to be considered as an active source rock in the Eastern Marlim oilfield, where the petroleum geochemical properties converge and are adequate to generate hydrocarbon compounds. In addition, the Ubatuba and Carapebus formations are also likely to generate oil and/or gas, but due to their relatively low maturity, it is difficult to establish that these rocks can be active source rocks in the study area.

This is the first report of trace fossils potentially associated with insect social behavior in sandy and well-drained paleosols of the Upper Cretaceous continental sequence of Brazil. The trace fossils consist of dozens of lobed and vertical structures cemented by CaCO 3 and preserved mainly in full relief in paleosols of the Marilia Formation (Bauru Basin) in the state of Minas Gerais. The described ichnofossils are predominantly vertical, up to 2 m long, and are composed of horizontal lobed structures connected by vertical tunnel-like structures that intersect in the center and at the edges. The lobed structures range from 3 to 15 cm long and 2–6 cm thick. Two different hypotheses are analyzed to explain the origin of the trace fossils; the less probable one is that the structures are laminar calcretes associated with rhizoliths and rhizoconcretions. The hypothesis involving social insects was considered because the trace fossils described herein partially resemble a modern ant nest and the ichnofossil Daimoniobarax. The micromorphological analysis of the lobed and tunnel-like structures indicates modifications of the walls, such as the presence of inorganic fluidized linings, dark linings and oriented grains, supporting the hypothesis that they are chambers and shafts. The architecture and size of the reported nests suggest the possibility that social insect colonies existed during the Maastrichtian and are direct evidence of the social behavior and reproductive strategies of the Cretaceous pedofauna.

An organic geochemical investigation combined with sequence stratigraphy was performed in the Ceara Basin, an offshore basin located in Northeastern Brazil. The information available from 30 well logs (gamma-ray, resistivity, density), besides geochemical (TOC, and pyrolysis indexes) and isotopic (δ13C) data, aided the preparation of a dataset for this study. The application of sequence-stratigraphic methods helped classify and correlate seismic and organic facies. Four key petroleum source-rock units were identified, from the oldest to the youngest: (1) Mundau Formation – top of the Rift Sequence (Berriasian-Aptian); (2) Paracuru Formation – Breakup Sequence (Aptian-Albian); (3) Itapaje Member of the Ubarana Formation – Continental Drift Sequence (Albian-Turonian), and (4) Uruburetama Member of the Ubarana Formation – Continental Drift Sequence (Turonian-Maastrichtian). The geochemical characteristics of the Mundau Formation (high total organic carbon (TOC), hydrogen index (HI), relative hydrocarbon potential (RHP = (S1 + S2)/TOC)) point to a typical transgressive sequence. Six transgressive-regressive (T-R) cycles were recognized in the entire Paracuru Formation. The best geochemical marker is related to the top of the Paracuru Formation. This stratigraphic unit can be correlated to a major anoxic event and is the best source rock of this basin. Evaporitic facies found in this top section, maximum RHP values (anoxic conditions), and maximum flooding surfaces related to transgressive events characterize this interval. Moreover, the wide spatial cover of organic-rich rocks, carbon isotopic data, and the recognition of favorable characteristics for anoxia in other basins of the Equatorial Margin are suggestive of the Aptian-Albian Oceanic Anoxic Event (OAE-1b) occurring in the Ceara Basin. The Ubarana Formation represented by the Uruburetama Member and the Itapaje Member yields the least promising source rocks. However, high TOC values suggest the occurrence of the late Cenomanian–early Turonian Oceanic Anoxic Event (OAE-2), when organic-rich strata started to deposit in deep-water regions. The predominance of a regressive interval in the Uruburetama Member points to oxic or sub-oxic conditions. Additionally, the correlations between the Brazilian Equatorial Margin and its African counterpart, and the organic geochemical characterization allied to the definition of depositional systems for these regions proved to be useful for oil exploration.

The Mundau sub-basin composes the western segment of the Ceara Basin, which is one of a series of basins of the Brazilian Equatorial Margin that resulted from the breakup of Western Gondwana. This study investigates the origin and maturation of the organic matter preserved in the rocks of the middle and outer shelf of the Mundau sub-basin, in order to assess the source-rock potential for oil and gas generation. The samples selected for this study are representative of the Mundau, Paracuru, and Ubarana formations, which correlate with the rift, transition, and drift phases of the Western Gondwana breakup. The results indicate moderate to good potential for oil generation and good potential for gas generation for the Mundau Formation. Fault activity during the rift phase favored sediment supply. Kerogen type III predominates in shallower portions and probably reflects the contribution from the continent. Good to excellent potential for oil and gas generation is indicated for the Paracuru Formation. Kerogen types I and II predominate, having the marine organic matter been deposited in reducing conditions. The most promising interval for hydrocarbon generation is limited by the top of the Trairi Member and the top of the Paracuru Formation. Moderate to good potential for oil and gas generation is suggested for the Uruburetama Member of the Ubarana Formation. The source rocks located in the middle shelf were deposited under reducing conditions in a transgressive marine environment. Kerogen varies from type II, to a mixture of types II and III, and to subordinate type III. Poor to fair potential for oil generation is indicated for the Itapaje Member of the Ubarana Formation. Kerogen type IV (inert or degraded) is typical in the middle shelf, and kerogen type IV and subordinate type III are typical on the outer shelf. The presence of inert kerogen is related to high-energy, oxidizing depositional environments. The hydrocarbon expulsion threshold estimated for the outer shelf is at 2106-m, for the middle shelf at 1635-m, and for the deep waters at 3632-m depths. Source rocks of the middle and outer shelves occur between 561 m and 4080 m, whereas those in deep waters occur between 2754 m and 5007 m of depth. The Active Source Rock Depth Limits (ASDL) estimated for the outer shelf is below 4500 m, whereas for deep waters, this limit is close to 6000 m. These organic geochemical constraints are important guidelines for oil and gas exploration in the Ceara and adjacent basins.

With the breakup of the supercontinent Gondwana, the South American Plate has undergone an intense process of tectonic restructuring that led to the genesis of the interior basins that encompassed continental sedimentary sequences. The Brazilian Bauru, Sanfranciscana and Parecis basins during Late Cretaceous have had their evolution linked to this process of structuring and therefore have very similar sedimentary characteristics. The purpose of this study is to establish a detailed understanding of alluvial sedimentary processes and architecture within a stratigraphic sequence framework using the concept of the stratigraphic base level or the ratio between the accommodation space and sediment supply. The integration of the stratigraphic and facies data contributed to defining the stratigraphic architecture of the Bauru, Sanfranciscana and Parecis Basins, supporting a model for continental sequences that depicts qualitative changes in the sedimentation rate (S) and accommodation space (A) that occurred during the Cretaceous. This study discusses the origin of the unconformity surfaces (K-0, K-1 and K-1A) that separate Sequences 1, 2A and 2B and the sedimentary characteristics of the Bauru, Sanfranciscana and Parecis Basins from the Aptian to the Maastrichtian, comparing the results with other Cretaceous Brazilian basins. The lower Cretaceous Sequence 1 (Caiua and Areado groups) is interpreted as a low-accommodation systems tract compound by fluvial and aeolian systems. The upper Cretaceous lacustrine, braided river-dominated alluvial fan and aeolian systems display characteristics of the evolution from high-to low-accommodation systems tracts (Sequences 2A and 2B). Unconformity K-0 is related to the origin of the Bauru Basin itself in the Early Cretaceous. In Sanfranciscana and Parecis basins, the unconformity K-0 marks the contact between aeolian deposits from Lower Cretaceous and Upper Cretaceous alluvial systems (Sequences 1 and 2). Unconformity K-1, which was generated in the Late Cretaceous, is related to an increase of the A/S ratio, whereas Unconformity K-1A is the result of the decrease in the A/S ratio. Unconformity K-1A bound Sequence 2A (lacustrine and fluvial systems) and Sequence 2B (alluvial deposits) in Bauru Basin whereas in the Sanfranciscana and Parecis basins this unconformity marks the transition from alluvial system to aeolian system (Sequences 2A and 2B). Changes in depositional style in both basins correspond to two distinct tectonic moments occurring within the South American plate. The first associated with post-volcanic thermal subsidence of the Early Cretaceous (Serra Geral and Tapirapua volcanismos), and the second moment associated with the uplift occurred in the Late Cretaceous (Alto Paranaiba, Vilhena and Serra Formosa Arcs).

Paleosols are soils that were formed on an ancient landscape. They may be buried soils and/or soils incorporated into the sedimentary sequences, exhumed soils, or soils developed on ancient relief surfaces (relict soils). Exposed on the surface and influenced by later environmental changes, paleosols reveal ancient environments and contain records regarding the climate, vegetation, landforms, organisms, parent material, time, intensity of pedogenesis, and sedimentation rates in effect during their training. In the Marilia Formation, the paleosols, exhumed and buried, developed on sandstones have argic (Btk, Bt and Bss), hydromorphic (Cg) and calcic (Bk) horizons with different degrees of cementation, forming mainly calcretes. The objective of this study was to characterize the genesis of the paleosols of the Marilia Formation, addressing the dynamics of their formation factors and processes at local and regional levels in order to reconstitute the conditions of environmental evolution of the Maastrichtian of the Bauru Basin. Eleven sections (S1, S2, S3, S4, S5, S6, S7, S8, S9, S10 and S11) of the Marilia Formation were described and collected on nine sample profiles. Micromorphological, mineralogical and geochemical analyses were performed according to the specialized literature. In the Marilia Formation, sedimentation, erosion and pedogenesis are processes that occurred together, concomitantly or subsequently, in view of the fluvial paleoenvironmental dynamics. The paleosols indicate the end of depositional cycles, with differentiated rates, intensities and duration. The paleosols of the Marilia Formation comprise well-drained (Bt-horizon) and poorly drained or hydromorphic (Cg-horizon) pedotypes, of drier conditions (Bkm-horizon) and pedotypes indicative of drier periods alternated with periods of higher humidity (Bss-horizon). The profiles were classified as Luvisols (Bt and Btk horizons), Calcisols (Bk and Ck horizons), Arenosols (C-horizons) and Vertisols (Bss-horizons). Paleosols developed on the flatter and lower portions of the slopes and floodplains and were commonly influenced by the oscillation of the groundwater and the seasonality of the climate. Sandstone with allochthonous and autochthonous carbonate cementation constituted the main parent material of the paleosols. The predominant climate during the Maastrichtian was semi-arid, with seasonality and variations in precipitation patterns and a precipitation-evapotranspiration relationship that provided conditions for the formation of paleosols with Bk, Btk, Bss, Bg and Bt horizons. The time of formation of these diagnostic horizons was dependent on climatic and edaphic factors. However, the time factor lasted until approximately 200,000 years, allowing paleosols to develop with Bt-horizons and prismatic and block structures. Calcification and argilluviation were the formation processes responsible for the genesis and evolution of paleosols during the Maastrichtian of the Bauru Basin. Weathering indexes have shown that paleosols with Bt-horizons are more weathered than are those with Btk and Bk horizons. The paleosols with Bk-horizons reflect periods with more arid conditions in the general context of the semi-arid paleoclimate of the Maastrichtian of the Bauru Basin.

In this work, oil-sand outcrops of the Anhembi deposit located in the Parana Basin, Brazil, were investigated using multi-scale imaging spectroscopy. The study incorporated VNIR–SWIR (400–2500 nm) spectroscopic data from imaging (i.e. sisuCHEMA) and nonimaging (i.e. FieldSpec-4) instruments in the lab, an AisaFENIX hyperspectral system on the ground and from the air, and WorldView-3 multispectral instrument. The aim was to assess the usefulness of emerging remote sensing technologies in characterizing hydrocarbon-bearing targets and understand the spatial variability of oil-sands at different scales using multi-source spectroscopic data. The bitumen content of the sands, estimated to be as high as 12 wt. %, was revealed to be unevenly distributed at all scales. Its distribution was shown to be controlled mainly by the clay proportion and permo-porosity of the strata, with the sand sheet facies corresponding to the highest bitumen contents. The ubiquitous clays, identified to be dominantly montmorillonite, were found to be intimately mixed with bitumen at all studied scales. The mean bitumen content was estimated to decrease from ˜ 6 to 4.5% while moving from small-, to deposit-scale as a consequence of the pixel aggregation effect and incremental clay contribution. The study showed that bitumen determination on the ground requires an imaging system with a high signal-to-noise ratio and good illumination conditions. Spectral denoising is also a crucial prerequisite for the extraction of coherent spectral information from the data. WV-3 data was proved capable of resolving HC’s feature at 1700 nm wavelength by its SWIR band-4 over targets encompassing >30% of the 7.5 m SWIR pixel; albeit it was not successful in determining the total bitumen content of the sands. This work indicated that HC signatures, particularly the one centered at 2300 nm, is consistent and comparable among scales, and upon employing properly calibrated data, could be used to confidently map the bitumen content of oil-sands at all imaging scales. A multi-scale spectroscopic approach can provide a complete picture of the variations in geologic targets and is able to fill the gap in scale differences across scales that when integrated, would add synergy and help reduce the uncertainties associated with ore grade estimation.