1. Influences of FeF3 coating layer on the electrochemical properties of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode materials for lithium-ion batteries
- Author
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Xiong Xin, Ji-Sheng Xia, Zheng Zhu'an, Cheng-Dong Li, Jin Xu, and Wei Liu
- Subjects
Materials science ,Scanning electron microscope ,Inorganic chemistry ,chemistry.chemical_element ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Electrochemistry ,01 natural sciences ,Lithium-ion battery ,Cathode ,0104 chemical sciences ,law.invention ,Chemical engineering ,chemistry ,law ,Transmission electron microscopy ,General Materials Science ,Lithium ,Cyclic voltammetry ,0210 nano-technology ,Faraday efficiency - Abstract
The FeF3-coated Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode materials were synthesized via a wet chemical process followed by a solid state reaction. The physical properties of the as-prepared samples were conducted using X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The results indicated that the surface of cathode particles was covered by FeF3 film (about 5–15 nm thick). Compared with the bare cathode, the FeF3-coated Li[Li0.2Mn0.54Ni0.13Co0.13]O2 one delivered the higher coulombic efficiency, better rate capability, longer cycle life, and better structure stability. A high capacity retention of 95% (190 mAh g− 1) after 100 cycles at 0.5 C rate was obtained for the FeF3-coated Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode. Besides, the results from cyclic voltammetry and electrochemical impedance spectra revealed that the noteworthy enhanced electrochemical properties of the surface-modified sample were due to the presence of FeF3 coating layer, which suppressed the side reaction between the Li[Li0.2Mn0.54Ni0.13Co0.13]O2 particles with electrolyte and further stabilized the Li[Li0.2Mn0.54Ni0.13Co0.13]O2 structure with cycling.
- Published
- 2016
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