1. Stabilizing electroluminescence color of blue perovskite LEDs via amine group doping
- Author
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Jizhong Song, Fengjuan Zhang, Xi Chen, Bo Cai, Changting Wei, Haibo Zeng, and Tao Fang
- Subjects
Multidisciplinary ,Materials science ,Dopant ,business.industry ,Doping ,Electroluminescence ,010502 geochemistry & geophysics ,01 natural sciences ,law.invention ,Formamidinium ,Quantum dot ,law ,Optoelectronics ,Quantum efficiency ,business ,0105 earth and related environmental sciences ,Light-emitting diode ,Perovskite (structure) - Abstract
Voltage loading-induced change in the electroluminescence (EL) wavelength of mixed halide perovskite light-emitting diodes (PeLEDs), so-called color-shift, has become an inevitable phenomenon, which is seriously unfavorable to their applications in lighting and display. Here, we achieve color-stable blue PeLEDs via a hydrogen-bonded amine-group doping strategy. Selecting guanidine (GA) or formamidinium (FA) as amine-group (−NH2) doping source for CsPbBrxCl3−x quantum dots (QDs), experimental and theoretical results reveal that the strong N−H⋯X (X = Br/Cl) bonding can be produced between −NH2 dopants and Pb−X lattices, thereby increasing the migration barrier of halide anions. Resultantly, color-stable sky-blue devices were realized with emission peaks fixed at 490.5 (GA) and 492.5 (FA) nm without any obvious shift as the voltage increases, in sharp contrast devices without N−H⋯X producing a 15 nm red-shift from 487 to 502 nm. Not only that, maximum external quantum efficiency is improved to 3.02% and 4.14% from the initial 1.3%. This finding offers a convenient boulevard to achieve color-stable PeLEDs with high efficiency.
- Published
- 2021
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