1. Investigation of iron adsorption on composite transition metal carbides in steel by first-principles calculation
- Author
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Hui-hui Xiong, Heng-hua Zhang, Lei Gan, Yang Zhou, and Zhi-Fang Tong
- Subjects
010302 applied physics ,Work (thermodynamics) ,education.field_of_study ,Materials science ,Composite number ,Population ,Analytical chemistry ,Nucleation ,02 engineering and technology ,General Chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Carbide ,Adsorption ,Transition metal ,0103 physical sciences ,Density of states ,General Materials Science ,0210 nano-technology ,education - Abstract
The nucleation potential of transition metal (TM) carbides formed in steel can be predicted by the behavior of iron adsorption on their surface. Therefore, Fe adsorption on the (001) surface of (A1-xmx)C (A = Nb, Ti, m = Mo, V) was investigated by the first-principles method to reveal the initialization of Fe nucleation. The Mulliken population and partial density of state (PDOS) were also calculated and analyzed in this work. The results show that Fe adsorption depends on the composition and configuration of the composite carbides. The adsorption energy (Wads) of Fe on most of (A1-xmx)C is larger than that of Fe on pure TiC or NbC. The maximum Wads is found for Fe on (Nb0.5Mo0.5)C complex carbide, indicating that this carbide has the high nucleation capacity at early stage. The Fe adsorption could be improved by the segregation of Cr and Mn atoms on the surfaces of (Nb0.5Mo0.5)C and (Ti0.5Mo0.5)C. The PDOS analysis of (Cr, Mn)-doped systems further explains the strong interactions between Fe and Cr or Mn atoms.
- Published
- 2018