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Start Over Author "Tatsuaki Nakanishi" Publisher elsevier bv
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1. Synthesis, structures and magnetic properties of trinuclear M(II)A(II)M(II) complexes (M = Cu, Ni, Co; A = Pb, Ba) derived from 2,6-bis(acetoacetyl)pyridine

Author

Masaaki Ohba, Hisashi Ōkawa, Tatsuaki Nakanishi, and Takuya Shiga

Subjects
chemistry.chemical_classification, crystal structure, magnetic interaction, Solid-state chemistry, Chemistry, Inorganic chemistry, heterometal complex, Salt (chemistry), Crystal structure, metallaazacrown, Ion, Inorganic Chemistry, trinuclear complex, Crystallography, chemistry.chemical_compound, Pyridine, Materials Chemistry, Diamagnetism, Antiferromagnetism, magnetic properties, Physical and Theoretical Chemistry, Magnetic interaction
Abstract

A series of trinuclear compounds [M2A(L)2(NO3)2] · n(sol) (M = Cu(II), Ni(II), Co(II); A = Pb(II), Ba(II), H2L = 2,6-bis(acetoacetyl)pyridine, sol = H2O or MeOH), has been systematically prepared by one-pot reaction of a M(II) nitrate salt, an A(II) nitrate salt and H2L in 2:1:2 ratio. They form a linear M(II)A(II)M(II) trinuclear core structure and show an antiferromagnetic interaction between the two terminal M(II) ions through the diamagnetic A(II) ion.

Published
2005
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