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1. Microbial asymmetric reduction of α-hydroxyketones in the anti-Prelog selectivity

Author

Takeshi Sugai, Hiromichi Ohta, and Toshikuni Tsujigami

Subjects
Stereochemistry, Organic Chemistry, Optically active, Ring (chemistry), Yamadazyma farinosa, Carbonyl group, Catalysis, Inorganic Chemistry, chemistry.chemical_compound, Enzyme system, chemistry, Reactivity (chemistry), Physical and Theoretical Chemistry, Selectivity
Abstract

Yamadazyma farinosa IFO 10896 was found to reduce α-hydroxyketones bearing a phenyl ring to give optically active diols with anti-Prelog selectivity. The distance between the carbonyl group and the phenyl ring was shown to have an interesting effect on the reactivity and selectivity of the enzyme system.

Published
2001
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