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Dolomite nodules are widespread within the Tortonian marls of Fortuna and Lorca basins in southern Spain. They occur as large bodies of various forms (round, ovoid, tabular) that are parallel or secant relative to the stratification. They are massive and present sometimes internal conduits that are considered as drains used for the migration of fluids. This study brings new results on the mineralogy and elemental and isotopic geochemistry of these dolomite nodules to better describe the processes that were occurring during their formation. The diagenetic reactions that have driven authigenic dolomite precipitation within the sediments involved on the one hand methanogenesis that produced 13C-poor CH4 and 13C-rich CO2, on the other hand carbonate and silicate weathering by the CO2-rich solutions, that released respectively alkalinity and cations in pore solutions. Moreover, the distribution of the major elements (Si, Al, K, Na, Ca, Mg, Fe) in the marls and dolomite nodules indicates that these elements were redistributed within the sedimentary formation during the diagenetic reactions without external inputs by the circulating fluids. These observations thus confirm the link between authigenic dolomite formation and clay minerals diagenesis in sediments where methanogenesis was active.

Dolomite nodules are widespread within the Tortonian marls of Fortuna and Lorca basins in southern Spain. They occur as large bodies of various forms (round, ovoid, tabular) that are parallel or secant relative to the stratification. They are massive and present sometimes internal conduits that are considered as drains used for the migration of fluids. This study brings new results on the mineralogy and elemental and isotopic geochemistry of these dolomite nodules to better describe the processes that were occurring during their formation. The diagenetic reactions that have driven authigenic dolomite precipitation within the sediments involved on the one hand methanogenesis that produced 13C-poor CH4 and 13C-rich CO2, on the other hand carbonate and silicate weathering by the CO2-rich solutions, that released respectively alkalinity and cations in pore solutions. Moreover, the distribution of the major elements (Si, Al, K, Na, Ca, Mg, Fe) in the marls and dolomite nodules indicates that these elements were redistributed within the sedimentary formation during the diagenetic reactions without external inputs by the circulating fluids. These observations thus confirm the link between authigenic dolomite formation and clay minerals diagenesis in sediments where methanogenesis was active.

Dolomite nodules are widespread within the Tortonian marls of Fortuna and Lorca basins in southern Spain. They occur as large bodies of various forms (round, ovoid, tabular) that are parallel or secant relative to the stratification. They are massive and present sometimes internal conduits that are considered as drains used for the migration of fluids. This study brings new results on the mineralogy and elemental and isotopic geochemistry of these dolomite nodules to better describe the processes that were occurring during their formation. The diagenetic reactions that have driven authigenic dolomite precipitation within the sediments involved on the one hand methanogenesis that produced 13C-poor CH4 and 13C-rich CO2, on the other hand carbonate and silicate weathering by the CO2-rich solutions, that released respectively alkalinity and cations in pore solutions. Moreover, the distribution of the major elements (Si, Al, K, Na, Ca, Mg, Fe) in the marls and dolomite nodules indicates that these elements were redistributed within the sedimentary formation during the diagenetic reactions without external inputs by the circulating fluids. These observations thus confirm the link between authigenic dolomite formation and clay minerals diagenesis in sediments where methanogenesis was active.

A joint industrial project with IFREMER and Total provides insights into the tectonic setting and the geochemistry of a large active pockmark offshore W-Africa in the Niger Delta. The study combines both geophysical (seismic) and geochemical data to infer the dynamics of a 300 m wide pockmark located at 667 m water depth. Two Calypso cores, one at the centre and one outside the pockmark, along with three box-cores, two inside the pockmark and one outside, were collected to study the geochemistry of gas hydrates, carbonates and pore waters. Two seismic lines, a 3D high resolution random line and a 2D high resolution seismic line, provide a good description of the plumbing of the system. The integrated results depict a very active pockmark characterized by several gas charged-bodies, a well identified BSR marking a hydrate accumulation zone, charged from deeper sources via a network of faults. Hydrates and carbonate concretions have been detected inside the pockmark while only the latter has been found outside. The hydrate analyses show that the hydrate-forming gases are of thermogenic origin, albeit overwhelmingly composed of methane. Pore-water analyses reveal the occurrence of anaerobic oxidation of methane coupled with sulphate reduction at shallow depth (∼200 cm). The chloride concentration profile exhibits both values lower than that of seawater which is inherent to hydrate dissociation after core recovery and positive anomalies (values 7% higher than that of seawater background) at the lowermost part of the core. The latter evidence suggests current or recent hydrate formation at this area. The carbonate dating provides additional temporal information and indicates that this pockmark has been active since ∼21 kyr.

A joint industrial project with IFREMER and Total provides insights into the tectonic setting and the geochemistry of a large active pockmark offshore W-Africa in the Niger Delta. The study combines both geophysical (seismic) and geochemical data to infer the dynamics of a 300 m wide pockmark located at 667 m water depth. Two Calypso cores, one at the centre and one outside the pockmark, along with three box-cores, two inside the pockmark and one outside, were collected to study the geochemistry of gas hydrates, carbonates and pore waters. Two seismic lines, a 3D high resolution random line and a 2D high resolution seismic line, provide a good description of the plumbing of the system. The integrated results depict a very active pockmark characterized by several gas charged-bodies, a well identified BSR marking a hydrate accumulation zone, charged from deeper sources via a network of faults. Hydrates and carbonate concretions have been detected inside the pockmark while only the latter has been found outside. The hydrate analyses show that the hydrate-forming gases are of thermogenic origin, albeit overwhelmingly composed of methane. Pore-water analyses reveal the occurrence of anaerobic oxidation of methane coupled with sulphate reduction at shallow depth (∼200 cm). The chloride concentration profile exhibits both values lower than that of seawater which is inherent to hydrate dissociation after core recovery and positive anomalies (values 7% higher than that of seawater background) at the lowermost part of the core. The latter evidence suggests current or recent hydrate formation at this area. The carbonate dating provides additional temporal information and indicates that this pockmark has been active since ∼21 kyr.

A joint industrial project with IFREMER and Total provides insights into the tectonic setting and the geochemistry of a large active pockmark offshore W-Africa in the Niger Delta. The study combines both geophysical (seismic) and geochemical data to infer the dynamics of a 300 m wide pockmark located at 667 m water depth. Two Calypso cores, one at the centre and one outside the pockmark, along with three box-cores, two inside the pockmark and one outside, were collected to study the geochemistry of gas hydrates, carbonates and pore waters. Two seismic lines, a 3D high resolution random line and a 2D high resolution seismic line, provide a good description of the plumbing of the system. The integrated results depict a very active pockmark characterized by several gas charged-bodies, a well identified BSR marking a hydrate accumulation zone, charged from deeper sources via a network of faults. Hydrates and carbonate concretions have been detected inside the pockmark while only the latter has been found outside. The hydrate analyses show that the hydrate-forming gases are of thermogenic origin, albeit overwhelmingly composed of methane. Pore-water analyses reveal the occurrence of anaerobic oxidation of methane coupled with sulphate reduction at shallow depth (∼200 cm). The chloride concentration profile exhibits both values lower than that of seawater which is inherent to hydrate dissociation after core recovery and positive anomalies (values 7% higher than that of seawater background) at the lowermost part of the core. The latter evidence suggests current or recent hydrate formation at this area. The carbonate dating provides additional temporal information and indicates that this pockmark has been active since ∼21 kyr.