1. Nano-modified feather keratin derived green and sustainable biosorbents for the remediation of heavy metals from synthetic wastewater.
- Author
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Zubair M, Roopesh MS, and Ullah A
- Subjects
- Adsorption, Animals, Cadmium analysis, Chromium analysis, Cobalt analysis, Feathers chemistry, Graphite, Hydrogen-Ion Concentration, Ions analysis, Keratins, Lead analysis, Nickel analysis, Wastewater chemistry, Water analysis, Zinc analysis, Arsenic analysis, Metals, Heavy analysis, Selenium, Water Pollutants, Chemical analysis
- Abstract
In this study, we employed a facile method to synthesize feather keratin derived biosorbents using water dispersed graphene oxide. The successful cross-linking of feather keratin with graphene oxide was investigated through X-ray photoelectrons spectroscopy (XPS), scanning and transmission electron microscopy, and Brunauer-Emmett-Teller (BET) analysis. The modifications resulted in increased surface area of the keratin proteins with substantial morphological changes including the development of cracked and rough patches on the surface. The chicken feather keratin/graphene oxide based biosorbents exhibited excellent performance for the simultaneous removal of metal oxyanions including arsenic (As), selenium (Se), chromium (Cr) and cations including nickel (Ni), cobalt (Co), lead (Pb), cadmium (Cd) and zinc (Zn) up to 99%, from polluted synthetic water containing 600 μgL
-1 of each metal concentration in 24 h. The insights into the biosorption mechanism revealed that the electrostatic interaction, chelation and complexation primarily contributed to the removal of multiple heavy metal ions in a single treatment. This study has demonstrated that modification of chicken feather keratin with graphene oxide is an effective way to improve its sorption capacity for removing multiple trace metal ions from contaminated water., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)- Published
- 2022
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