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Photonic additives have been investigated as a means to enhance the efficiency of thermal protection systems (TPS) against the adverse effects of thermal radiation. State-of-the-art TPS consist of carbon fibers embedded in a phenolic resin matrix. During operation, the TPS is consumed because it is exposed to an excess heat flux, a large fraction of which is due to thermal radiation. Here, we show that a properly modeled and designed additive-impregnated TPS can block a considerable part of this heat influx and quantify how different control parameters, in particular the additives’ amount, placement and alignment, influence the achieved photonic enhancement. More specifically, the intrinsic reflectivity of 8.5% of a conventional TPS can been improved to values exceeding 85% by controllably inserting additives, consisting of a Ta/[SiO2/TiO2]6 heterostructure, here referred to as Type 1, an ideal, optimized, high and broadband reflector. Nevertheless, even simple, commercially available additives composed of TiO2/Al2O3/TiO2, here referred to as Type 2, provide a high reflectivity enhancement with values of up to 76%, when used in larger quantities. The simulations of this work are based on the Monte Carlo Ray Tracing (MCRT) method. The MCRT simulation method has been validated against experiment, using the structure and experiments from a literature reference. Our analysis method allows one to design and model the performance of photonically enhanced TPS that operate in high-flux, radiative conditions, like those expected in future aerospace re-entry missions or next-generation, gas turbines and thermophotovoltaic plants and provides a viable option for efficiently enhancing a TPS., International Journal of Thermal Sciences, 170, ISSN:1290-0729, ISSN:1778-4166

The microstructural and optical reflectivity response of photonic SiO2/TiO2 nanomultilayers have been investigated as a function of temperature and up to the material system’s melting point. The nanomultilayers exhibit high, broadband reflectivities up to 1350 °C with values that exceed 75% for a 1 μm broad wavelength range (600–1600 nm). The optimized nanometer sized, dielectric multilayers undergo phase transformations from anatase TiO2 and amorphous SiO2 to the thermodynamically stable phases, rutile and cristobalite, respectively, that alter their structural morphology from the initial multilayers to that of a scatterer. Nonetheless, they retain their photonic characteristics, when characterized on top of selected substrate foils. The thermal behavior of the nanometer sized multilayers has been investigated by differential thermal analysis (DTA) and compared to that of commercially available, mm-sized, annealed powders. The same melting reactions were observed, but the temperatures were lower for the nm-sized samples. The samples were characterized using X-ray powder diffraction before DTA and after annealing at temperatures of 1350 and 1700 °C. The microstructural evolution and phase compositions were investigated by scanning electron microscopy and energy-dispersive X-ray spectroscopy measurements. The limited mutual solubility of one material to another, in combination with the preservation of their optical reflectivity response even after annealing, makes them an interesting material system for high-temperature, photonic coatings, such as photovoltaics, aerospace re-entry and gas turbines, where ultra-high temperatures and intense thermal radiation are present., Journal of Materials Science, 56, ISSN:0022-2461, ISSN:1573-4803