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This article explores the use of Sn nanoparticles to enhance the optical properties of PEDOT: PSS thin films. The study focuses on the impact of Sn concentration on the films' optical characteristics, particularly in relation to organic solar cells. The results indicate that incorporating Sn nanoparticles improves the energy bandgap values and decreases the dielectric constant of the films, resulting in improved transmittance velocity and increased efficacy of microelectronic devices. The findings suggest that Sn-incorporated PEDOT: PSS thin films have potential applications in the field of optoelectronics and microelectronics. [Extracted from the article]

Stokes parameters (S) on the Poincaré sphere are very useful values to describe the polarisation state of photons. However, the fundamental principle on the nature of polarisation is not completely understood, yet, because we have no concrete consensus on how to describe spin of photons, quantum-mechanically. Here, we have considered a monochromatic coherent ray of photons, described by a many-body coherent state, and established a fundamental basis to describe the spin state of photons, in connection with a classical description based on Stokes parameters. We show that a spinor description of the coherent state is equivalent to Jones vector for polarisation states, and obtain the spin operators (Ŝ) of all components based on rotators in an SU(2) group theory. Polarisation controllers such as phase-shifters and rotators are also obtained as quantummechanical field operators to change the phase of the wavefunction for polarisation states. We show that the Stokes parameters are quantummechanical average of the spin operators, S = ⟨Ŝ⟩. [ABSTRACT FROM AUTHOR]

The speed of light (c) in a vacuum is independent of the choice of frames to describe the propagation, according to the theory of relativity. We consider how light is characterised in a material, where the speed of light is different from that in a vacuum due to the finite dielectric constant. The phase velocity in a material is smaller than c, such that the speed of a moving frame can be larger than the phase velocity, such that the frame can move faster than the speed of light in a material. Consequently, an unusual Doppler effect is expected, and the wavelength in the moving frame changes from the red-shift to the blue-shift upon increasing the speed of the frame. The corresponding energy of the light also changes sign from positive to negative, while momentum is always positive, leading to the changes of signs for the phase velocity and the helicity. In a graded index fibre, where the exact solution is available, even more complicated phenomena are expected, due to the finite effective mass of photons. Upon the increase of the energy gap, generated by optical confinements and optical orbital angular momentum, the effective mass of photons increases. If the gap is large enough, momentum starts to change the sign upon increasing the frame velocity, while the energy of photons is always positive. In this case, the phase velocity diverges if momentum is in agreement with the fame velocity. Contrary to the unusual behaviours of the phase velocity, the group velocity is always below c. This thought experiment might be useful for considering insight into the polarisation state of light.

Lie algebra is a hidden mathematical structure behind various quantum systems realised in nature. Here, we consider SU(2) wavefunctions for polarisation states of coherent photons emitted from a laser source, and discuss the relationship to spin expectation values with SO(3) symmetry based on isomorphism theorems. In particular, we found rotated half-wave-plates correspond to mirror reflections in the Poincaré sphere, which do not form a subgroup in the projected O(2) plane due to anti-hermitian property. This could be overcome experimentally by preparing another half-wave-plate to realise a pristine rotator in SU(2), which allows arbitrary rotation angles determined by the physical rotation. By combining another 2 quarter-wave-plates, we could also construct a genuine phase-shifter, thus, realising passive control over the full Poincaré sphere.