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Start Over Author "Amna N. Khan" Publisher georg thieme verlag kg
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1. A New Simplified Protocol for Copper(I) Alkyne–Azide Cycloaddition Reactions Using Low Substoichiometric Amounts of Copper(II) Precatalysts in Methanol

Author

Amna N. Khan, Harry Heaney, Maria M. P. Figueres, and Benjamin R. Buckley

Subjects
chemistry.chemical_classification, chemistry.chemical_compound, chemistry, Organic Chemistry, Triazole, chemistry.chemical_element, Alkyne, Methanol, Azide, Copper, Combinatorial chemistry, Cycloaddition, Catalysis
Abstract

Copper(II) carboxylates are reduced efficiently by methanol in the presence of alkynes and form yellow alkynylcopper(I) polymeric precatalysts that are involved with azides, in the absence of added ligands, in the catalytic cycles that result in the formation of 1,4-disubstituted 1,2,3-triazoles.

Published
2015
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