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Start Over Author "Murali Rajagopalan" Publisher georg thieme verlag kg
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1. First Total Synthesis and Absolute Configuration of the Styryl Lactone Gonioheptolide A

Author

Richard A. Hudson, L. M. Viranga Tillekeratne, Mamoun M. Alhamadsheh, Shuchi Gupta, and Murali Rajagopalan

Subjects
chemistry.chemical_classification, chemistry.chemical_compound, chemistry, Stereochemistry, Organic Chemistry, Absolute configuration, Total synthesis, Specific rotation, Enantiomer, Two-dimensional nuclear magnetic resonance spectroscopy, Catalysis, Lactone
Abstract

Efficient asymmetric syntheses of both naturally occurring and non-naturally occurring enantiomers of gonioheptolide A are reported. The absolute configuration of (+)-gonioheptolide A was established by NOESY, Mosher ester analysis, and comparison with the specific rotation of the isolated (+)-gonioheptolide A.

Published
2007
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