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Start Over Author "Serusi, Lorenzo" Publisher georg thieme verlag stuttgart
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1. Synthesis of Tryptamines through a Novel Brønsted Acid Mediated Tandem Reaction Initiated by α-Iminol Rearrangement of Transient 2-Substituted 2-Hydroxycyclobutylimines.

Author

Serusi, Lorenzo, Cuccu, Federico, Secci, Francesco, Aitken, David J., and Frongia, Angelo

Subjects
*BRONSTED acids, *CONDENSATION reactions, *TRYPTAMINE, *ANILINE
Abstract

A novel Brønsted acid promoted condensation reaction between a primary aniline and 2-hydroxycyclobutanone provides access to diverse tryptamine derivatives in moderate to good yields. The proposed mechanism involves an α-iminol rearrangement, ring expansion, ring closure, and a depart-and-return rearrangement process. [ABSTRACT FROM AUTHOR]

Published
2021
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