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Start Over Author "Strelkova, Tatyana V." Publisher georg thieme verlag stuttgart

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1. Synthesis of N,N'-Dialkylated Cyclohexane-1,2-diamines and Their Application as Asymmetric Ligands and Organocatalysts for the Synthesis of Alcohols.

Author

Tsygankov, Alexey A., Man-Seog Chun, Samoylova, Alexandra D., Seongyeon Kwon, Kreschenova, Yuliya M., Suhyeon Kim, Euijin Shin, Jinho Oh, Strelkova, Tatyana V., Kolesov, Valerii S., Zubkov, Fedor I., Semenov, Sergei E., Fedyanin, Ivan V., and Chusov, Denis

Subjects
*CHEMICAL alcohol synthesis, *LIGANDS (Chemistry)
Abstract

A series of N,N'-dialkylated derivatives of (1R,2R)-cyclohexane-1,2-diamine were synthesized, and a new approach to the one-pot preparation of this type of amine was demonstrated. The prepared diamines were used as organocatalysts for the two-step synthesis of α-hydroxy γ-keto esters from arenes, chlorooxoacetates, and ketones; they were also used as chiral ligands for Meervein-Ponndorf-Verley reductions and Henry reactions. [ABSTRACT FROM AUTHOR]

Published
2017
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