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To construct the network organizational structure of college students' educational management and realize the informatization development of college students' educational management, the construction method of network organizational structure of college students' educational management is proposed based on the distributed network. MySQL and PostgreSQL are used as the bottom data structure models of the network-based organizational structure of college students' education management, and the multisource information scheduling method, which is used to construct the transaction identifier (TID) labeling tuple model of college students' education management network. The initial topological structure model of the network-based organizational structure nodes of college students' education management network is constructed by the 4-tuple model, and the linear structure decomposition of the construction nodes of the network-based organizational structure of college students' education management is carried out. The correlation characteristics of the transmission channel of the network organization structure of college students' education management are extracted; the three-layer architecture system of data layer, network layer, and application layer is adopted; the architecture model of the network organization structure of college students' education management is established; the multinode distributed network transmission technology is used to build a tree structure model, so as to realize the design of the network organization structure model of college students' education management and the scheduling of multi-source information parameters; and the fuzzy multi-attribute decision-making method to realize the adaptive scheduling of the network organization structure of college students' education management is adopted, so as to improve the storage management, fault tolerance, and safe access ability of the network organization structure of college students' education management. The test results show that the network organizational structure of college students' educational management is designed by this method, which improves the ability of information transmission and scheduling and improves the informatization level of college students' educational management. [ABSTRACT FROM AUTHOR]