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This study examined the photocatalytic degradation efficiency under high UV photon flux (intensity normalized by photon energy) irradiation; the incident UV photon flux was 1.71×10−6−3.13×10−6 einstein cm−2 s−1 made by a super high-intensity UV apparatus. A comparative study between high photon flux photocatalytic process and routine low photon flux photocatalytic process for methylene blue degradation has been made in aqueous solution. The experimental results showed that under the best conditions of high UV photocatalytic reaction 99% decolorization and 95% TOC removal of 20 mg L−1 methylene blue could be achieved in 30 s and 120 s of UV irradiation time, respectively. To the best of our knowledge, photocatalytic decolorization and photocatalytic degradation of dyes in such a short time has not been reported. Aiming at the low photonic efficiency in high photon flux photocatalytic process, we found that reducing the density of excited electron-hole appropriately could improve initial apparent photonic efficiency effectively. The TOC experiments under high UV photon flux showed a faster mineralization rate and a different mineralization process compared to that under low UV photon flux.

In order to effectively solve a series of problems such as the difficulty of coal and rock interbed roadway support in Gaojiazhuang Coal Mine and get a scientific and reasonable optimization scheme of surrounding rock support, theoretical analysis, numerical simulation, ultrasonic detection, field-effect test, and other means are adopted to analyze the instability of coal and rock interbed roadway. The results show that the interbedded roadway has weak interbedded cementation, and its ore pressure is more intense due to the influence of its interbedded weak structural plane. Based on Mohr’s strength envelope principle, it is proposed that horizontal stress is the main factor that causes a wide range of shear displacement, penetration crack, and surrounding rock failure of the roof of this kind of roadway. Through the finite element numerical simulation analysis, the deformation and failure law, stress distribution characteristics, and failure area distribution characteristics of coal and rock interbedding roadway surrounding rock are theoretically revealed, and the control effect of different support schemes on roadway surrounding rock deformation is greatly different. Based on the ultrasonic detection technology, it is proved that the roadway side failure has strong zoning characteristics, and the failure range and stress distribution range of the surrounding rock of the belt roadway in the 2103 working face of Gaojiazhuang Coal Mine are detected. Finally, the coupling strengthening support scheme combining prestressed anchor cable and bolt is proposed. The engineering application and the observation of surrounding rock deformation show that the reinforced support technology can effectively enhance the stability of the surrounding rock of the interbed roadway in Gaojiazhuang Coal Mine, and it has a good reference for the surrounding rock conditions of this kind of roadway.

We introduce the weighted mixed almost unbiased ridge estimator (WMAURE) based on the weighted mixed estimator (WME) (Trenkler and Toutenburg 1990) and the almost unbiased ridge estimator (AURE) (Akdeniz and Erol 2003) in linear regression model. We discuss superiorities of the new estimator under the quadratic bias (QB) and the mean square error matrix (MSEM) criteria. Additionally, we give a method about how to obtain the optimal values of parameters k and w. Finally, theoretical results are illustrated by a real data example and a Monte Carlo study.