1. Ellipsometry and magnetooptical Kerr effect study of nanocrystalline zinc ferrite thin films
- Author
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Petr Siroky, Subasa C. Sahoo, Murtaza Bohra, Eva Lišková-Jakubisová, Shiva Prasad, Stefan Visnovsky, David Hrabovsky, and Jaromír Pištora
- Subjects
Zinc ferrite ,Materials science ,Kerr effect ,Magnetic moment ,Ferrimagnetism ,Ellipsometry ,Spinel ,Analytical chemistry ,engineering ,Thin film ,engineering.material ,Nanocrystalline material - Abstract
Laser ablated zinc ferrite (ZnFe 2 O 4 ) films deposited at O 2 pressure of 0.16 mbar onto fused quartz substrates are nanocrystalline and display net magnetic moment dependent on the substrate temperature (T s ) during deposition. At T s = 350 °C, the room 4πM s reached the maximum of 3 kG. The films were studied by spectral ellipsometry and magnetooptical (MO) Kerr effect spectroscopy at photon energies between 1 and 5 eV at room temperature in the longitudinal magnetic flux density 1.14 T. The optical and MO spectra show structural details typical for inverted spinels. Our ZnFe 2 O 4 samples display amplitudes somewhat reduced with respect to those in other ferrimagnetic oxides with the exchange coupled Fe3+ pairs, i.e., in Li 0.5 Fe 2.5 O 4 and MgFe 2 O 4 spinel ferrite and magnetoplumbite, PbFe 12 O 19 . The lower amplitudes are probably due to the interplay of nanocrystalline nature and lower degree of spinel inversion in the ZnFe 2 O 4 laser ablated films.
- Published
- 2015