1. Impact of Pressure-Induced Differential Refractive Index in Raman Spectroscopy using Hollow-Core Fibres
- Author
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M. Foster, William Brooks, Ian A. Davidson, Matthew Partridge, David J. Richardson, Natalie V. Wheeler, Francesco Poletti, G. T. Jasion, Shuichiro Rikimi, Peter Horak, and T. W. Kelly
- Subjects
Materials science ,Optical fiber ,business.industry ,Attenuation ,Cladding (fiber optics) ,Methane ,law.invention ,Core (optical fiber) ,chemistry.chemical_compound ,symbols.namesake ,chemistry ,law ,symbols ,Optoelectronics ,business ,Raman spectroscopy ,Refractive index ,Raman scattering - Abstract
Raman spectroscopy is an attractive technique for simultaneous analysis of multiple gas species. Exploiting hollow-core microstructured optical fibres (HC-MOFs) for enhanced gas-light interaction length allows for extremely low detection limits of, e.g., 0.2 ppm methane [1] . Recently, we reported that extremely small changes in the refractive indices of the gases inside the core and cladding regions (as induced by differential gas pressure) significantly impact the optical properties of these fibres [2] . Here we exploit this effect to almost double the Raman signal.
- Published
- 2021