Search

Your search keyword '"H. W. A. Biessels"' showing total 1 results
Start Over Author "H. W. A. Biessels" Publisher informa uk limited
1 results on '"H. W. A. Biessels"'

1. FISSION OF AS-AS BONDS IN ELEMENTAL ARSENIC BY ALKALI METALS IN LIQUID AMMONIA. A ROUTE TO MONOALKYL ARSINES

Author

O. Bj⊘rlo, H. W. A. Biessels, J. Schuring, Lambert Brandsma, H. D. Verkruijsse, and A. C. van der Kerk‐Van Hoof

Subjects
chemistry.chemical_classification, Organic Chemistry, Iodide, Inorganic chemistry, technology, industry, and agriculture, chemistry.chemical_element, Alcohol, Alkali metal, Biochemistry, Arsenide, Inorganic Chemistry, chemistry.chemical_compound, Arsine, chemistry, Yield (chemistry), lipids (amino acids, peptides, and proteins), Lithium, Arsenic
Abstract

Addition of two mol equivalents of t-butyl alcohol to a mixture of powdered arsenic and three mol equivalents of lithium in liquid ammonia gives a suspension of lithium arsenide LiAsH2. Subsequent addition of a large excess of t-butyl alcohol and n-octyl iodide at very low temperatures affords n-octyl arsine in -65% yield.

Published
2000
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results