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Providing high-resolution monitoring data is essential in promoting decision-making activities for surface water quality protection such as scientific modeling and data analysis. In this study, statistical models using multiple linear regression (MLR) were developed to estimate Chlorophyll-a (Chl-a) and total suspended solid (TSS) concentrations in a mesotrophic reservoir, the Yeongam Reservoir in Korea, from satellite observations. Two types of satellite data that covered different spectral regions, for wavelengths in 412–865 nm (for the Geostationary Ocean Color Imager) and those in 405–14,385 nm (for the Moderate Resolution Imaging Spectroradiometer), were used as inputs for statistical models, after bias correction. The MLR models for Chl-a and TSS were initially constructed and evaluated with 39 image data-sets obtained during 2011–2014. Subsequently, they compared with their corresponding algorithms that were developed under different environmental settings as well as the CE-QUAL-W2 model, a...

Reverse osmosis (RO) desalination of 35,000 ppm seawater consisting of sodium and chlorine ions with water was simulated using molecular dynamics. In this study, RO simulations were performed at different pressures using carbon nanotube (CNT) membranes having varying pore diameters (8–14 A). Results showed that a CNT membrane allowed high water fluxes because of the presence of a low energy barrier for water–carbon interactions, with continuous and ordered water chains observed inside the CNTs. The investigations into the ion rejection capability of CNT membranes revealed that (6, 6) CNTs could provide high rejection rates (>95%). The rejection of ions was mainly due to the presence of a high energy barrier caused by removing the hydrating water molecules necessary for ions to pass through the narrow CNT pore. The desalination performance of (6, 6) CNT membranes and conventional polymeric membranes was then compared. It was found that CNT membranes have a higher normalized flux and comparable ion ...

Statistical models play an important role in elucidating the dynamic behaviors of surface water quality, given limited data on a large scale. In this study, we examine alternative approaches to develop regression models that predict fecal coliform (FC) concentrations in a river using different methods for selecting important variables provided by a self-organizing map (SOM). The raw data used as input to the SOM included 11 water quality, 6 meteorological, and 7 land use parameters that were monitored along the Yeongsan River in Korea on various time scales (from daily to half a decade) during 1996–2008. In both test and validation data sets, (multiple) regressions using backward elimination were compared against regression models via forced entry, which included a set of ranked variables simultaneously based on four indices in the SOM (i.e. structuring index, relative importance, cluster description, and Spearman’s rank correlation). Results showed that the SOM effectively illustrated the complex...

A transient model of seawater reverse osmosis (SWRO) system enables systematic assessment of membrane performance in response to changes in time-series parameters, operating conditions, or ancillary equipment. In this study, we describe the effects of energy recovery device (ERD) and feed pressure control on the SWRO plant in terms of energy consumption (reduced) and water quantity (increased) using a numerical model at pilot scale. In the simulation, two types of isobaric ERD, i.e. pressure exchanger (PX) and dual work exchanger energy recovery (DWEER), were used to quantify changes of the mass flow rates of inflow and outflow in the system. Also, temporal variation in the raw feedwater quality was addressed in the model with adaptive feed pressure control to maintain the amount of produced water under fouled membrane conditions. Results showed that the observed recovery and rejection rates in the pilot-scale plant had an excellent agreement with their predicted values under different seawater fe...

Groundwater contamination with arsenic (As) is one of the major issues in the world, especially for Southeast Asian (SEA) countries where groundwater is the major drinking water source, especially in rural areas. Unfortunately, quantification of groundwater As contamination is another burden for those countries because it requires sophisticated equipment, expensive analysis, and well-trained technicians. Here, we collected approximately 350 groundwater samples from three different SEA countries, including Cambodia, Lao PDR, and Thailand, in an attempt to quantify total As concentrations and conventional water quality variables. After that, two machine learning models (i.e. artificial neural network (ANN) and support vector machine (SVM)) were applied to predict groundwater As contamination using conventional water quality parameters. Prior to modeling approaches, the pattern search algorithm in MATLAB software was used to optimize the ANN and SVM model parameters, attempting to find the best param...

Pressure retarded osmosis (PRO) is a promising membrane-based process for producing clean and renewable energy. Since the major driving force is the salinity gradient between the feed and draw solutions, PRO can operate without a large environmental footprint. However, the performance of PRO can be severely limited by fouling, with organic fouling commonly deemed the main factor influencing PRO performance, since even a small amount of organic foulants can cause a significant flux decline. In spite of its importance, however, few studies have focused on PRO fouling. Therefore, the objectives of this study were to investigate the effect of hydraulic pressure as an influencing factor and to adjust the feed solution pH in order to alleviate fouling in the PRO process. Alginate was chosen as the model foulant due to its common existence in feed water. Based on our results, a higher hydraulic pressure caused an increase in the reverse solute flux, such that organic fouling became aggravated. In additio...

This paper presents a desalination process powered by a microgrid. Desalination is critically important for many countries demanding potable water beyond that available in nature. The desalination process requires a stable power supply system. As the stable power supply system, microgrid, which is a distributed small capacity power system integrating renewable energy with energy storage, has become important. In this paper, small capacity desalination plant powered by a microgrid is implemented and its features are described. The desalination plant is operated by electricity provided from either renewable energy resource such as solar cell or power grid. Overall control of the desalination plant is carried out by a programmable logic controller and status of water production is monitored by energy management system. The implemented desalination plant consumes 5 kW and produces 1 m3/h of fresh water.

This paper describes the effects of weir construction on water quality in the Yeongsan (YS) River. In general, weirs affect aquatic environments of rivers and streams by interrupting natural water flow. To identify changes in water quality before and after weir construction, analysis of variance and autocorrelation tests were conducted on data from four monitoring stations. Seasonal variations in suspended solids (SS), biochemical oxygen demand (BOD5), chemical oxygen demand (COD), total nitrogen (TN), total phosphorus (TP), and pH were analyzed using data from six years of monitoring. No significant changes in mean BOD5 or COD followed the construction of weirs. However, mean TN and TP were changed significantly during and after construction. Moreover, SS and pH changed significantly during construction, and TN and TP concentrations were slightly improved after weir construction. However, continuous monitoring and analysis of water quality changes in each weir are required to prevent environmenta...

This study introduces a schematic methodology for smart water grids (SWGs) for use in water management platforms, which integrates information and communication technology (ICT) into a single water management scheme. SWG technology is seen as a promising solution for resolving recent critical global water problems. To ensure the security of water quantity, safety of water quality, and ICT-based water management solutions, SWG technology should integrate five prime research areas: (1) platform configuration in both water and ICT networks, (2) guarantee water resources including both natural and manufactured water, (3) intelligent control of water flow using bi-directional communication in water infrastructure, (4) better management scheme dealing with risk-minimization for assets in the water infrastructure, and (5) energy efficiency in operating and maintaining water infrastructure. Two platforms (i.e. water and ICT platforms) are introduced as examples of well-designed platforms for the managemen...

In this study, unlike the previous researches, the pretreatment equipment composed of a 40- μm disk filter and a hollow fiber ultra-filtration (UF) membrane was constructed. The performances of the pretreatment facilities were analyzed on the basis of 5-week-long continuous experiments using sea water. The results confirmed that the newly constructed pretreatment equipment could be used for the pretreatment of sea water reverse osmosis as evidenced by silt density index15 values below two for a long period and measured turbidities of about 0.4 NTU. The membrane fouling could be removed by using chemical enhanced backwash. Trans-membrane pressure and the permeability could be returned to the initial conditions. It reveals that UF membrane performances of the pretreatment were dependent on the sea water conditions and operating conditions.

Nonpoint source (NPS) pollution is widely recognized as a major source affecting the water quality deterioration in rivers, lakes, and marine environments. Many studies about the relations between NPS pollutants and solid matters from drainage area have been carried out in the area of stormwater management. This study collected stormwater and soil samples from a drainage area in Korea; the particle size distributions (PSDs) were then analyzed during four storm events. The results indicate that the PSDs of fine and medium silt in the stormwater are related to the soil component of the drainage area. In addition, solid matter was strongly related to NPS pollutant discharges such as total nitrogen and total phosphorus during stormwater runoff. Therefore, to design an NPS management facility, the PSD from the drainage area should be considered. It is expected that this study can be applied to the designs of settling ponds used to remove particles from stormwater runoff.

Nonpoint source pollutions discharged with stormwater runoff during rainfall events degrade public waterbodies. Because combined sewer overflows (CSOs) especially affect public waterbodies, necessary measures must be taken for CSOs. Therefore, this study treated CSOs using the ultra-rapid coagulation (URC) process. More than 50% of the study site was comprised of an industrial area, followed by forest, farmland and residential areas at 21.3, 2.6, and 23.5%, respectively. The 30,000 ton capacity URC process was used to treat CSOs generated from the catchment. Monitoring was conducted over 8 rainfall events, and the samples were analyzed for pollutant parameters such as total suspended solids (TSS), biochemical oxygen demand (BOD), chemical oxygen demand (CODcr), total nitrogen (TN), total phosphorus (TP), and heavy metals. At the beginning of the rainfall, the first flash effect was observed, but was not observed 20 min later. The concentration of TSS and BOD increased as the rainfall intensity be...

This study evaluated ecological health, using various biomarkers and bioindicators, of pale chub (Zacco platypus) as a sentinel species, in Daejeon Stream, South Korea, during April–May 2011. The biomarkers and bioindicators were compared among three sites of control: Reference (Cz), transition (Tz), and the urban zones (Uz); and the 7-Ethoxyresorufin-O-deethylase (EROD) activity, DNA damage, acetylcholinesterase (AChE) activity, and vitellogenin (VTG) concentrations were more significantly increased in the Uz than in the Cz. Also, physiological markers such as condition factor, liver somatic index, visceral somatic index, and gonad somatic index were significantly increased in the Uz than in the Cz. For the health assessments, three categorized parameters of blood chemistry, molecular biomarkers, and physiological bioindicators were standardized and calculated as a star-plot, representing values of Integrated Health Response (IHR). Values of IHR had more significant (P

Finding a suitable osmostically active solute is the most important problem in forward osmosis (FO). Even though there are a number of osmotically active compounds that exist, the major problem occurs during the separation of product water from the solute. Osmotically active macromolecules (polyethylene glycol [PEG] and humic acid [HA]) were investigated in this research as possible draw solutes for FO. Cellulose triacetate FO membranes (Hydration Technology Innovations, LLC) and several ultrafiltration and nanofiltration membranes were used in osmosis and filtration steps of the system, respectively. Molecular weights (MW) of PEG were selected as 2 k, 10 k, and 20 kDa for 400 and 600 g/L concentrations. HA solutions were prepared in concentrations ranging from 200 to 800 g/L. Increased MW resulted in higher water permeation when PEGs were used. The relationship between the reflection coefficient and the viscosity was investigated for PEG/water separation by membrane filtration. The combined effe...

The fouling behavior of seawater reverse osmosis membranes has yet to be definitively investigated due to the complexity of seawater compositions. In this study, a time-series image analysis (TSIA) was performed to investigate the fouling mechanism using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The fouling experiments were conducted with synthetic seawater (SS) and SS mixed with humic acid substances (SHA). The effect of operational time was investigated for 2, 4, 6, 8, 12, and 20 h. According to the TSIA results, different fouling characteristics between SS and SHA experiments were observed. In the SS case, the fouling mechanism is the interaction between inorganic particles and the membrane surface as well as interaction between inorganic particles and the deposited foulants. Then, increased accumulation of deposited foulants was observed with respect to the operational time. However, in the presence of humic acid, the fouling mechanism was significantly influenced ...

The development and exploitation of sustainable and environment-friendly energy resources are required in order to resolve global energy shortages. Recently, salinity gradient power (SGP) has been considered a feasible candidate, with high potential to become a substitute for the current use of fossil fuels due to benefits such as less periodicity, abundance and no emission of carbon dioxide. In this paper, one SGP, pressure-retarded osmosis (PRO) system, was reviewed in terms of its mechanism, limitations and available applications. In the PRO system, water permeates through a semipermeable membrane from the feed solution to the draw solution, and energy is generated by depressurizing the permeated flow through a hydro turbine. Models for understanding its mechanism and for improving of its performance were reviewed. In addition, applications of sea water reverse osmosis (SWRO), wastewater treatment (WWT) and PRO hybrid process were introduced in order to develop new water-energy nexus processes...

A lab-scale vortex separator, based on a swirling motion to remove settleable particles, was used to remove suspended solids in urban stormwater runoff. However, the treatment is limited to the removal of large settleable particles. The synthesized stormwater runoff was made with tap water and the addition of road sediment. The vortex separator has internal components designed to enhance vortex separation by minimizing the turbulence, increasing the efficiency, and preventing captured pollutants from washout. As the flow continues to spiral down around the inlet baffle, a low energy vortex motion directs settleable particles into the protected sediment storage zone. Advanced vortex separation provided an extendable and stabilized flow path while protecting the captured pollutants for a wide range of flow rates. The range of the inflow rate was 30–115 l/m, and the size of the influent particles varied from 75 to 200 μm. Overall removal efficiencies of 51.8% for SS, 26.6% for COD, 70.5% for TP, and...

A four-year monitoring study was conducted to determine the diffuse pollutant unit loads for the six representative transportation landuses (i.e., highway, parking lot, bridge, service area and toll gate) in urban areas in Korea. Pollutant event mean concentrations (EMCs) were calculated from 123 storm events at eleven sites and the average annual rainfall and runoff coefficients were determined to estimate the unit loads using the National Institute of Environmental Research (NIER) method. Apparent differences in the unit load values existed among landuses as explained by the high variability of EMCs for different rainfall events. The study has found that runoff from bridges and highways contained the highest loadings of TSS and COD while service areas are the primary sources of nutrients and metals. The results of this study could be used by the Ministry of Environment (MOE) to separate the unit loads of transportation landuses from the urban area category in the current unit load system. The v...

Scale formation of soluble salts is one of the major factors limiting the performance of reverse osmosis (RO) membranes for desalination. However, it is difficult to predict membrane fouling due to scale formation in a complicated feed water containing dissolved organics such as humic substances. This study aims at prediction of the complicated fouling phenomenon by scale formation in the presence of dissolved organic matters. Experimental studies with model solutions were conducted in a small batch filtration device. Humic acid and calcium sulfate were used as model dissolved organic matters and scale-forming salts. A genetic programming technique was applied to predict the effect of dissolved organic matters on scale formation.

Seawater reverse osmosis (SWRO) desalination is considered one of the most promising technologies for supplying freshwater to the regions suffering from water scarcity. Although a considerable amount of research has been conducted in attempts to improve SWRO desalination technology, reducing the cost of producing freshwater is still required. In Korea, this effort is already been being carried out by the Seawater Engineering & Architecture of High Efficiency Reverse Osmosis (SeaHERO) project. Core Technology 2 (CT2), one of the most important sub-projects out of four CTs under SeaHERO, pursues two main goals: optimization of processes for low energy consumption/high efficiency and localization of core parts/equipments of the SWRO plant. Four unit technologies (UTs) are then incorporated into CT2 and each UT has its own technical target; UT1 focuses on the development of SWRO desalination system integration and optimization technology in terms of energy saving; UT2 and 3 work to develop high performance RO...

Forward osmosis (FO) is a membrane-based desalination technique using an osmotic pressure gradient as a driving force. FO enables lower energy consumption to produce water than reverse osmosis (RO) because it does not require high transmembrane pressure. However, FO needs to be combined with other processes such as RO or evaporation because the draw salts in the FO products should be removed. This paper focused on theoretical investigation of combined systems with FO and RO for seawater desalination. A theoretical model to predict the performance of the combined systems was developed based on the solution—diffusion model and the modified film theory. The effect of internal concentration polarization on FO efficiency was also considered in the model. A pilot-scale system of FO and RO was assumed for model calculations. Results showed that the combinations of FO with seawater reverse osmosis (SWRO) have potential for desalination with high recovery (up to 80%). It was also found that FO may be incorporated ...

In the present study, the feasibility of a tri-hybrid desalination system for the production of electricity, energy for heating and cooling and water was studied. The tri-hybrid desalination system is a combination of a cogeneration and a desalination system. The system is composed of a generator driven by a gas engine, a gas boiler, a turbo-refrigerator, an absorption refrigerator for cogeneration, and an RO and an MED for the desalination system. The excess heat was calculated based on the electrical, heating and cooling load data and assumed that would be used for the production of water. The quantitative analysis of the product water and the energy consumption rate was compared on a month-by-month basis, and the feasibility of the tri-hybrid desalination system is explained.

The model of salt transport through the membrane in multi-component system was developed with the irreversible thermodynamics theory considering the effect of the interaction between the salt ions. With the proposed transport model, the model for spiral-wound module was built based on the mass conservation law and concentration polarization derived by film theory. Through the parameter estimation, the frictional coefficients related to permeability of water and each ion was determined and then phenomenological analysis was conducted. The simulation results show that the salt rejection is increasing as the applied pressure and feed flow rate increasing. Also, the predictions by present model are in good agreement with the experimental data in the literature.

To date, over 80 papers on transport modeling and natural organic matter (NOM) relating to seawater reverse osmosis (SWRO), have been reviewed. As a result of such focus, NOM, one of the main foulants related to reverse osmosis (RO) membranes, has been shown to possess intrinsic chemical complexities and ambiguities, necessitating further investigation. Consequently, since such NOM fouling and transport mechanisms associated with SWRO are not fully understood, a summation of previous studies has been included in the paper in question to systematize information, not only as to RO membrane transport modeling, but NOM fouling characteristics, as well. Accordingly, RO transport models in the review are classified into three categories: diffusion-based, pore, and irreversible thermodynamic models. In addition, specific features, unique assumptions, and applications for each model are examined. The paper consists of the following components towards meaningful understanding of NOM fouling model development durin...

A seawater reverse osmosis (SWRO) desalination process has become an alternative technology to solve water shortage problem in the world. Although SWRO is an advanced and useful technology for humanity, there is still unsettled cost effective issue. Therefore, the estimation of operation and maintenance (O&M) costs should be significantly considered before a new construction of SWRO desalination plant. The objective of this feasibility study is to estimate total annual profits (TAP) according to O&M for a new construction of SWRO desalination plant at 9 candidate sites along the shoreline in Korea. The cost estimation model was developed and validated with Fujairah SWRO plant operation data in 2005. As a result, TAPs for the 9 candidate sites were estimated and compared with that of Fujairah SWRO plant. The result reflects that the cost estimation model in this study is able to propose a reasonable range of TAP for a new construction project of SWRO desalination plant in Korea.

The successful operation of a seawater reverse osmosis desalination plant depends greatly on the performance of the pretreatment step. The start-up of a pretreatment filtration process usually begins with a dynamic part called ripening, during which the filter media increases its adsorption ability and improves the removal of foulants from the seawater. In that period (typically lasting 30–60 min, depending on the system's conditions) the effluent often does not meet the quality requirements of the RO membranes and must often be disposed of. An observation and analysis of the ripening phenomena was performed using lab scale acrylic filter columns containing granular activated carbon. The seawater originated from the Yellow Sea in Korea and an inline coagulation was performed prior to filtration using an optimal dose of FeCl3 based on a jar test. The turbidity, total suspended solids concentration and dissolved organic carbon were measured before and after filtration with the goal of assessing the filtrati...

Recovery and salt rejection rate, which are directly related to the membrane properties and operating conditions (i.e., feed flow rate, pressure, temperature, and TDS concentration), are two main indicators for evaluating the performance of a reverse osmosis (RO) membrane process. A simple and rapid test with minimum data is inevitably requested to diagnose membrane performance at a certain operating conditions, because experiments at all operating conditions are inefficient and consumable work in the view of cost as well as man-hour. In this study, permeate flow rate and TDS concentration of three kinds of commercial RO membranes were carefully examined under various operating conditions [i.e., feed pressure (45–65 kgf/cm2) and temperature (5–30°C)]. Based on the experimental data, membrane resistance models including temperature and pressure correction factors were developed for the rapid diagnosis of SWRO membrane performances. As a result, the models developed in this study have good agreements betwee...

Reverse osmosis (RO) membranes have high rejection for most of solutes in seawater except for boron. Therefore, boron rejection should be considered in the design and operation of the RO process for seawater desalination. In this paper, we investigated boron rejection and its relation to salt rejection using an irreversible thermodynamic model. Permeability constants for commercially-available RO membranes were obtained using theoretical model and the simulation data from membrane performance test program provided by membrane manufacturers. The effect of pH and concentration of the feed water on the boron rejection was also theoretically investigated under various operating conditions. The model calculations revealed that the rejection of boron follows a different mechanism from those of other ionic solutes and could not be readily correlated with ion rejections. To overcome the limit of mechanistic models, we explored an alternative approach for predicting boron permeability from membrane properties and ion permeability. It appears that this alternative approach can aid to achieve a better understanding of boron rejection by seawater RO membranes.

Desalination offers one of the reasonable alternatives as a solution to water scarcity. Among the desalination technologies, seawater reverse osmosis (SWRO) process becomes increasingly attractive for freshwater supply with comparatively low energy consumption and cost-effective operation. In this study, a benchmark of operating Fujairah SWRO desalination plant in the United Arab Emirates is applied to assess the relative performance of a new and large plant construction in other sites. A process model was developed to simulate the performance of SWRO desalination process and to estimate its operating cost. The developed model was validated using one-year SWRO operation data obtained from Fujairah SWRO desalination plant. Temperature and salinity data were collected from World Ocean Atlas 2005, and then applied to the model to estimate the operating cost under the site-specific conditions of 9 different countries. The results of this study present that the performance of the SWRO desalination process was significantly influenced by feed water concentration (i.e., mainly salinity) and temperature, and that the total operating cost is significantly dependent of the local electricity costs. As a conclusion, World Ocean Atlas data and the benchmark provide a method of comparing the performance of various SWRO desalination systems among different countries. Furthermore the methodology is applicable to simulate the process model with site-specific water quality data and to estimate the operating cost before a new construction of SWRO desalination plant at a target area elsewhere.

At the time being there are several technological designs of membrane-based seawater reverse osmosis (SWRO) pretreatment systems on the desalination market. The abundance of different membrane materials and configurations (pressurized/submerged/inside-out/outside-in etc.) combined with site specific conditions make the unbiased assessment of their general performance a difficult task. In this paper we suggest a data mining method based on the principal component analysis (PCA) to serve as a more systematically logical regression tool on currently available literature data. PCA is a multivariate statistical method that uses a linear transformation for dimension reduction and pattern recognition. The results show how this method can be used effectively in the case of SWRO membrane based pretreatment for both literature data reconciliation and reconstruction, as well as for future data prediction.